Thermodynamic investigation on the aqueous mixtures of choline chloride/propylene glycol deep eutectic solvent at T = (293.15 to 313.15) K
Abstract This work focuses on physicochemical features of the choline chloride/propylene glycol deep eutectic solvent (DES) + water mixtures by determining their density values in mono- and mixed- states over various temperatures in the range of 293.15–318.15 K. The density data obtained from measur...
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| Format: | Article |
| Language: | English |
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BMC
2024-03-01
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| Series: | BMC Chemistry |
| Subjects: | |
| Online Access: | https://doi.org/10.1186/s13065-024-01153-y |
| _version_ | 1797259606824583168 |
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| author | Aynaz Zarghampour Parisa Jafari Elaheh Rahimpour Abolghasem Jouyban |
| author_facet | Aynaz Zarghampour Parisa Jafari Elaheh Rahimpour Abolghasem Jouyban |
| author_sort | Aynaz Zarghampour |
| collection | DOAJ |
| description | Abstract This work focuses on physicochemical features of the choline chloride/propylene glycol deep eutectic solvent (DES) + water mixtures by determining their density values in mono- and mixed- states over various temperatures in the range of 293.15–318.15 K. The density data obtained from measurements were utilized for the computation of various quantities such as excess molar volumes, molar volume, apparent molar volume, limiting apparent molar expansibility, and isobaric thermal expansion coefficient. Furthermore, the experimental densities were fitted to some mathematical equations such as Jouyban-Acree, Jouyban-Acreevan’t Hoff, modified Jouyban-Acree-van’t Hoff, Redlich–Kister and Emmerling. Studies of this nature can provide useful insights into solute–solvent interactions in aqueous solutions of DES, especially about to their novel application in drug solubilization. |
| first_indexed | 2024-04-24T23:12:06Z |
| format | Article |
| id | doaj.art-ed25b04627764735b33a169296acdd31 |
| institution | Directory Open Access Journal |
| issn | 2661-801X |
| language | English |
| last_indexed | 2024-04-24T23:12:06Z |
| publishDate | 2024-03-01 |
| publisher | BMC |
| record_format | Article |
| series | BMC Chemistry |
| spelling | doaj.art-ed25b04627764735b33a169296acdd312024-03-17T12:13:13ZengBMCBMC Chemistry2661-801X2024-03-0118111010.1186/s13065-024-01153-yThermodynamic investigation on the aqueous mixtures of choline chloride/propylene glycol deep eutectic solvent at T = (293.15 to 313.15) KAynaz Zarghampour0Parisa Jafari1Elaheh Rahimpour2Abolghasem Jouyban3Pharmaceutical Analysis Research Center and Faculty of Pharmacy, Tabriz University of Medical SciencesPharmaceutical Analysis Research Center and Faculty of Pharmacy, Tabriz University of Medical SciencesPharmaceutical Analysis Research Center and Faculty of Pharmacy, Tabriz University of Medical SciencesPharmaceutical Analysis Research Center and Faculty of Pharmacy, Tabriz University of Medical SciencesAbstract This work focuses on physicochemical features of the choline chloride/propylene glycol deep eutectic solvent (DES) + water mixtures by determining their density values in mono- and mixed- states over various temperatures in the range of 293.15–318.15 K. The density data obtained from measurements were utilized for the computation of various quantities such as excess molar volumes, molar volume, apparent molar volume, limiting apparent molar expansibility, and isobaric thermal expansion coefficient. Furthermore, the experimental densities were fitted to some mathematical equations such as Jouyban-Acree, Jouyban-Acreevan’t Hoff, modified Jouyban-Acree-van’t Hoff, Redlich–Kister and Emmerling. Studies of this nature can provide useful insights into solute–solvent interactions in aqueous solutions of DES, especially about to their novel application in drug solubilization.https://doi.org/10.1186/s13065-024-01153-yDensityDeep eutectic solventSolute–solvent interactionsExcess molar volumesPhysicochemical properties |
| spellingShingle | Aynaz Zarghampour Parisa Jafari Elaheh Rahimpour Abolghasem Jouyban Thermodynamic investigation on the aqueous mixtures of choline chloride/propylene glycol deep eutectic solvent at T = (293.15 to 313.15) K BMC Chemistry Density Deep eutectic solvent Solute–solvent interactions Excess molar volumes Physicochemical properties |
| title | Thermodynamic investigation on the aqueous mixtures of choline chloride/propylene glycol deep eutectic solvent at T = (293.15 to 313.15) K |
| title_full | Thermodynamic investigation on the aqueous mixtures of choline chloride/propylene glycol deep eutectic solvent at T = (293.15 to 313.15) K |
| title_fullStr | Thermodynamic investigation on the aqueous mixtures of choline chloride/propylene glycol deep eutectic solvent at T = (293.15 to 313.15) K |
| title_full_unstemmed | Thermodynamic investigation on the aqueous mixtures of choline chloride/propylene glycol deep eutectic solvent at T = (293.15 to 313.15) K |
| title_short | Thermodynamic investigation on the aqueous mixtures of choline chloride/propylene glycol deep eutectic solvent at T = (293.15 to 313.15) K |
| title_sort | thermodynamic investigation on the aqueous mixtures of choline chloride propylene glycol deep eutectic solvent at t 293 15 to 313 15 k |
| topic | Density Deep eutectic solvent Solute–solvent interactions Excess molar volumes Physicochemical properties |
| url | https://doi.org/10.1186/s13065-024-01153-y |
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