Morphological growth criterion for faceted to non-faceted transition in pure materials
A criterion to explain the morphological growth transition from faceted to non-faceted (f-nf) morphology in the case of directional solidification is presented for pure materials. The criterion is based on the number of atomic layers at the solid–liquid interface and allows a foreknowledge of the so...
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Format: | Article |
Language: | English |
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Elsevier
2023-05-01
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Series: | Results in Physics |
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Online Access: | http://www.sciencedirect.com/science/article/pii/S2211379723002115 |
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author | Yaw Delali Bensah |
author_facet | Yaw Delali Bensah |
author_sort | Yaw Delali Bensah |
collection | DOAJ |
description | A criterion to explain the morphological growth transition from faceted to non-faceted (f-nf) morphology in the case of directional solidification is presented for pure materials. The criterion is based on the number of atomic layers at the solid–liquid interface and allows a foreknowledge of the solidification growth velocity at which f-nf transition becomes significant. The basis for the transition criterion hinges on the Cahn theory of interface structure and the theory of liquid–solid transition by the maximum entropy production rate (MEPR) principle. The criterion is tested with a number of pure materials and compared with experimental measurements for salol. The criterion fits quite well with available experimental data. |
first_indexed | 2024-04-09T19:15:11Z |
format | Article |
id | doaj.art-ed315660827c4e0db3cc012db65ae4ac |
institution | Directory Open Access Journal |
issn | 2211-3797 |
language | English |
last_indexed | 2024-04-09T19:15:11Z |
publishDate | 2023-05-01 |
publisher | Elsevier |
record_format | Article |
series | Results in Physics |
spelling | doaj.art-ed315660827c4e0db3cc012db65ae4ac2023-04-06T06:10:53ZengElsevierResults in Physics2211-37972023-05-0148106418Morphological growth criterion for faceted to non-faceted transition in pure materialsYaw Delali Bensah0Department of Materials Science and Engineering, School of Engineering Sciences, University of Ghana, PMB, Accra, GhanaA criterion to explain the morphological growth transition from faceted to non-faceted (f-nf) morphology in the case of directional solidification is presented for pure materials. The criterion is based on the number of atomic layers at the solid–liquid interface and allows a foreknowledge of the solidification growth velocity at which f-nf transition becomes significant. The basis for the transition criterion hinges on the Cahn theory of interface structure and the theory of liquid–solid transition by the maximum entropy production rate (MEPR) principle. The criterion is tested with a number of pure materials and compared with experimental measurements for salol. The criterion fits quite well with available experimental data.http://www.sciencedirect.com/science/article/pii/S2211379723002115Maximum entropy generation rate densitySolidificationFacetedNon-facetedMorphological transition |
spellingShingle | Yaw Delali Bensah Morphological growth criterion for faceted to non-faceted transition in pure materials Results in Physics Maximum entropy generation rate density Solidification Faceted Non-faceted Morphological transition |
title | Morphological growth criterion for faceted to non-faceted transition in pure materials |
title_full | Morphological growth criterion for faceted to non-faceted transition in pure materials |
title_fullStr | Morphological growth criterion for faceted to non-faceted transition in pure materials |
title_full_unstemmed | Morphological growth criterion for faceted to non-faceted transition in pure materials |
title_short | Morphological growth criterion for faceted to non-faceted transition in pure materials |
title_sort | morphological growth criterion for faceted to non faceted transition in pure materials |
topic | Maximum entropy generation rate density Solidification Faceted Non-faceted Morphological transition |
url | http://www.sciencedirect.com/science/article/pii/S2211379723002115 |
work_keys_str_mv | AT yawdelalibensah morphologicalgrowthcriterionforfacetedtononfacetedtransitioninpurematerials |