Morphological growth criterion for faceted to non-faceted transition in pure materials

A criterion to explain the morphological growth transition from faceted to non-faceted (f-nf) morphology in the case of directional solidification is presented for pure materials. The criterion is based on the number of atomic layers at the solid–liquid interface and allows a foreknowledge of the so...

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Main Author: Yaw Delali Bensah
Format: Article
Language:English
Published: Elsevier 2023-05-01
Series:Results in Physics
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S2211379723002115
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author Yaw Delali Bensah
author_facet Yaw Delali Bensah
author_sort Yaw Delali Bensah
collection DOAJ
description A criterion to explain the morphological growth transition from faceted to non-faceted (f-nf) morphology in the case of directional solidification is presented for pure materials. The criterion is based on the number of atomic layers at the solid–liquid interface and allows a foreknowledge of the solidification growth velocity at which f-nf transition becomes significant. The basis for the transition criterion hinges on the Cahn theory of interface structure and the theory of liquid–solid transition by the maximum entropy production rate (MEPR) principle. The criterion is tested with a number of pure materials and compared with experimental measurements for salol. The criterion fits quite well with available experimental data.
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spelling doaj.art-ed315660827c4e0db3cc012db65ae4ac2023-04-06T06:10:53ZengElsevierResults in Physics2211-37972023-05-0148106418Morphological growth criterion for faceted to non-faceted transition in pure materialsYaw Delali Bensah0Department of Materials Science and Engineering, School of Engineering Sciences, University of Ghana, PMB, Accra, GhanaA criterion to explain the morphological growth transition from faceted to non-faceted (f-nf) morphology in the case of directional solidification is presented for pure materials. The criterion is based on the number of atomic layers at the solid–liquid interface and allows a foreknowledge of the solidification growth velocity at which f-nf transition becomes significant. The basis for the transition criterion hinges on the Cahn theory of interface structure and the theory of liquid–solid transition by the maximum entropy production rate (MEPR) principle. The criterion is tested with a number of pure materials and compared with experimental measurements for salol. The criterion fits quite well with available experimental data.http://www.sciencedirect.com/science/article/pii/S2211379723002115Maximum entropy generation rate densitySolidificationFacetedNon-facetedMorphological transition
spellingShingle Yaw Delali Bensah
Morphological growth criterion for faceted to non-faceted transition in pure materials
Results in Physics
Maximum entropy generation rate density
Solidification
Faceted
Non-faceted
Morphological transition
title Morphological growth criterion for faceted to non-faceted transition in pure materials
title_full Morphological growth criterion for faceted to non-faceted transition in pure materials
title_fullStr Morphological growth criterion for faceted to non-faceted transition in pure materials
title_full_unstemmed Morphological growth criterion for faceted to non-faceted transition in pure materials
title_short Morphological growth criterion for faceted to non-faceted transition in pure materials
title_sort morphological growth criterion for faceted to non faceted transition in pure materials
topic Maximum entropy generation rate density
Solidification
Faceted
Non-faceted
Morphological transition
url http://www.sciencedirect.com/science/article/pii/S2211379723002115
work_keys_str_mv AT yawdelalibensah morphologicalgrowthcriterionforfacetedtononfacetedtransitioninpurematerials