Analyzing Near-Surface Regions of Hydrophobic and Long-Term Weathered Natural Stones at Microscopic Scale

The visual appearance of building structures is an important attribute which reflects the character and identity of a region. Due to the influence of weathering, the surfaces of building stones alter, leading to aesthetic changes of the material surface such as discoloration or darkening. In this st...

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Main Authors: Franziska Braun, Jeanette Orlowsky, Stefan Brüggerhoff
Format: Article
Language:English
Published: MDPI AG 2020-06-01
Series:Heritage
Subjects:
Online Access:https://www.mdpi.com/2571-9408/3/2/27
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author Franziska Braun
Jeanette Orlowsky
Stefan Brüggerhoff
author_facet Franziska Braun
Jeanette Orlowsky
Stefan Brüggerhoff
author_sort Franziska Braun
collection DOAJ
description The visual appearance of building structures is an important attribute which reflects the character and identity of a region. Due to the influence of weathering, the surfaces of building stones alter, leading to aesthetic changes of the material surface such as discoloration or darkening. In this study, near-surface regions of weathered Baumberger (BST), Schleeriether (SST), and Obernkirchener Sandstones (OKS) have been analyzed at the microscopic scale in order to investigate the intensity and the extent of visual as well as structural changes and how both can be affected due to the presence of surface treatments with hydrophobing agents. It could be detected that aesthetic changes appeared already after 2 years of outdoor exposure, with the slightest variations on BST surfaces, followed by SST and OKS. The use of hydrophobing agents leads to a reduction in surface darkening in the short term. After long-term weathering, no significant changes are visible, as similar values in total color difference (ΔE*) were measured. Biogenic growth and the formation of black weathering crusts are the main reasons for color alterations in the case of the examined stones. The surface damages occur especially on calcareous (BST) followed by clayey (SST) and quartzitic (OKS) stone surfaces.
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spelling doaj.art-ed4998dc63854a1fbadd0254fc7ec4bf2023-11-20T03:40:45ZengMDPI AGHeritage2571-94082020-06-013245747310.3390/heritage3020027Analyzing Near-Surface Regions of Hydrophobic and Long-Term Weathered Natural Stones at Microscopic ScaleFranziska Braun0Jeanette Orlowsky1Stefan Brüggerhoff2Department of Building Materials, Technische Universität Dortmund, August-Schmidt-Str. 8, 44227 Dortmund, GermanyDepartment of Building Materials, Technische Universität Dortmund, August-Schmidt-Str. 8, 44227 Dortmund, GermanyDeutsches Bergbau-Museum Bochum, Am Bergbaumuseum 28, 44791 Bochum, GermanyThe visual appearance of building structures is an important attribute which reflects the character and identity of a region. Due to the influence of weathering, the surfaces of building stones alter, leading to aesthetic changes of the material surface such as discoloration or darkening. In this study, near-surface regions of weathered Baumberger (BST), Schleeriether (SST), and Obernkirchener Sandstones (OKS) have been analyzed at the microscopic scale in order to investigate the intensity and the extent of visual as well as structural changes and how both can be affected due to the presence of surface treatments with hydrophobing agents. It could be detected that aesthetic changes appeared already after 2 years of outdoor exposure, with the slightest variations on BST surfaces, followed by SST and OKS. The use of hydrophobing agents leads to a reduction in surface darkening in the short term. After long-term weathering, no significant changes are visible, as similar values in total color difference (ΔE*) were measured. Biogenic growth and the formation of black weathering crusts are the main reasons for color alterations in the case of the examined stones. The surface damages occur especially on calcareous (BST) followed by clayey (SST) and quartzitic (OKS) stone surfaces.https://www.mdpi.com/2571-9408/3/2/27natural stonehydrophobic agentslong-term weatheringdurabilityweathering damagescolor alterations
spellingShingle Franziska Braun
Jeanette Orlowsky
Stefan Brüggerhoff
Analyzing Near-Surface Regions of Hydrophobic and Long-Term Weathered Natural Stones at Microscopic Scale
Heritage
natural stone
hydrophobic agents
long-term weathering
durability
weathering damages
color alterations
title Analyzing Near-Surface Regions of Hydrophobic and Long-Term Weathered Natural Stones at Microscopic Scale
title_full Analyzing Near-Surface Regions of Hydrophobic and Long-Term Weathered Natural Stones at Microscopic Scale
title_fullStr Analyzing Near-Surface Regions of Hydrophobic and Long-Term Weathered Natural Stones at Microscopic Scale
title_full_unstemmed Analyzing Near-Surface Regions of Hydrophobic and Long-Term Weathered Natural Stones at Microscopic Scale
title_short Analyzing Near-Surface Regions of Hydrophobic and Long-Term Weathered Natural Stones at Microscopic Scale
title_sort analyzing near surface regions of hydrophobic and long term weathered natural stones at microscopic scale
topic natural stone
hydrophobic agents
long-term weathering
durability
weathering damages
color alterations
url https://www.mdpi.com/2571-9408/3/2/27
work_keys_str_mv AT franziskabraun analyzingnearsurfaceregionsofhydrophobicandlongtermweatherednaturalstonesatmicroscopicscale
AT jeanetteorlowsky analyzingnearsurfaceregionsofhydrophobicandlongtermweatherednaturalstonesatmicroscopicscale
AT stefanbruggerhoff analyzingnearsurfaceregionsofhydrophobicandlongtermweatherednaturalstonesatmicroscopicscale