On-the-Fly Formation of Polymer Film at Water Surface

The self-propulsion of bodies floating in water is of great interest for developing new robotic and intelligent systems at different scales, and whenever possible, Marangoni propulsion is an attractive candidate for the locomotion of untethered micro-robots. Significant cases have been shown using l...

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Main Authors: Veronica Vespini, Sara Coppola, Pietro Ferraro
Format: Article
Language:English
Published: MDPI AG 2022-08-01
Series:Polymers
Subjects:
Online Access:https://www.mdpi.com/2073-4360/14/15/3228
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author Veronica Vespini
Sara Coppola
Pietro Ferraro
author_facet Veronica Vespini
Sara Coppola
Pietro Ferraro
author_sort Veronica Vespini
collection DOAJ
description The self-propulsion of bodies floating in water is of great interest for developing new robotic and intelligent systems at different scales, and whenever possible, Marangoni propulsion is an attractive candidate for the locomotion of untethered micro-robots. Significant cases have been shown using liquid and solid surfactants that allow an effective propulsion for bodies floating on water to be achieved. Here, we show for the first time a strategy for activating a twofold functionality where the self-propulsion of a floating body is combined with the formation of a polymer thin film at the water surface. In fact, we demonstrate that by using polymer droplets with an appropriate concentration of solvent and delivering such drops at specific locations onto freely floating objects, it is possible to form “on-the-fly” thin polymer films at the free water surface. By exploiting self-propulsion, a polymer thin film can be formed that could cover quite extensive areas with different shapes depending on the motion of the floating object. This intriguing twice-functionality activated though a single phenomenon, i.e., film formation and related locomotion, could be used in perspective to perform complex operations at water surfaces, such as dynamic liquid packaging, cleaning, and moving away floating particles, monolayer films, or macro-sized objects, as discussed in the text.
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spelling doaj.art-ed79e41acf9942bd8139a96b7a402b832023-12-01T23:07:44ZengMDPI AGPolymers2073-43602022-08-011415322810.3390/polym14153228On-the-Fly Formation of Polymer Film at Water SurfaceVeronica Vespini0Sara Coppola1Pietro Ferraro2Institute of Applied Sciences and Intelligent Systems “E. Caianiello”, National Research Council (CNR-ISASI), Via Campi Flegrei 34, 80078 Pozzuoli, NA, ItalyInstitute of Applied Sciences and Intelligent Systems “E. Caianiello”, National Research Council (CNR-ISASI), Via Campi Flegrei 34, 80078 Pozzuoli, NA, ItalyInstitute of Applied Sciences and Intelligent Systems “E. Caianiello”, National Research Council (CNR-ISASI), Via Campi Flegrei 34, 80078 Pozzuoli, NA, ItalyThe self-propulsion of bodies floating in water is of great interest for developing new robotic and intelligent systems at different scales, and whenever possible, Marangoni propulsion is an attractive candidate for the locomotion of untethered micro-robots. Significant cases have been shown using liquid and solid surfactants that allow an effective propulsion for bodies floating on water to be achieved. Here, we show for the first time a strategy for activating a twofold functionality where the self-propulsion of a floating body is combined with the formation of a polymer thin film at the water surface. In fact, we demonstrate that by using polymer droplets with an appropriate concentration of solvent and delivering such drops at specific locations onto freely floating objects, it is possible to form “on-the-fly” thin polymer films at the free water surface. By exploiting self-propulsion, a polymer thin film can be formed that could cover quite extensive areas with different shapes depending on the motion of the floating object. This intriguing twice-functionality activated though a single phenomenon, i.e., film formation and related locomotion, could be used in perspective to perform complex operations at water surfaces, such as dynamic liquid packaging, cleaning, and moving away floating particles, monolayer films, or macro-sized objects, as discussed in the text.https://www.mdpi.com/2073-4360/14/15/3228filminterfaceliquid packagingMarangoni propulsionpolymerspreading
spellingShingle Veronica Vespini
Sara Coppola
Pietro Ferraro
On-the-Fly Formation of Polymer Film at Water Surface
Polymers
film
interface
liquid packaging
Marangoni propulsion
polymer
spreading
title On-the-Fly Formation of Polymer Film at Water Surface
title_full On-the-Fly Formation of Polymer Film at Water Surface
title_fullStr On-the-Fly Formation of Polymer Film at Water Surface
title_full_unstemmed On-the-Fly Formation of Polymer Film at Water Surface
title_short On-the-Fly Formation of Polymer Film at Water Surface
title_sort on the fly formation of polymer film at water surface
topic film
interface
liquid packaging
Marangoni propulsion
polymer
spreading
url https://www.mdpi.com/2073-4360/14/15/3228
work_keys_str_mv AT veronicavespini ontheflyformationofpolymerfilmatwatersurface
AT saracoppola ontheflyformationofpolymerfilmatwatersurface
AT pietroferraro ontheflyformationofpolymerfilmatwatersurface