Thermal Annealing Effect on Surface-Enhanced Raman Scattering of Gold Films Deposited on Liquid Substrates
We prepare metal films with various thicknesses on liquid substrates by thermal evaporation and investigate the annealing effect on these films. Gold films deposited on a silicone oil surface consist of a large number of branched aggregates, which contains plenty of gold nanoparticles. This characte...
Main Authors: | , , , , , , , , |
---|---|
Format: | Article |
Language: | English |
Published: |
MDPI AG
2023-02-01
|
Series: | Molecules |
Subjects: | |
Online Access: | https://www.mdpi.com/1420-3049/28/3/1472 |
_version_ | 1797623726610579456 |
---|---|
author | Ziran Ye Haixia Huang Fengyun Xu Ping Lu Yiben Chen Jiawei Shen Gaoxiang Ye Fan Gao Bo Yan |
author_facet | Ziran Ye Haixia Huang Fengyun Xu Ping Lu Yiben Chen Jiawei Shen Gaoxiang Ye Fan Gao Bo Yan |
author_sort | Ziran Ye |
collection | DOAJ |
description | We prepare metal films with various thicknesses on liquid substrates by thermal evaporation and investigate the annealing effect on these films. Gold films deposited on a silicone oil surface consist of a large number of branched aggregates, which contains plenty of gold nanoparticles. This characteristic morphology is mainly attributed to the isotropic and free-sustained liquid substrate. Thermal annealing results in the reintegration of nanoparticles; thus, the surface morphology and microstructure of gold films change significantly. The dependence of annealing conditions on the surface-enhanced Raman scattering performance of gold films is studied, in which gold films show favorable Raman activity when annealed at certain annealing temperature and the experimental results are verified by simulation analysis. The study on the optimal annealing temperature of surface-enhanced Raman scattering substrate will pave the way for the potential application of films deposited on liquid surfaces in microfluidics and enhanced Raman detection. |
first_indexed | 2024-03-11T09:32:54Z |
format | Article |
id | doaj.art-ed7c918ee6f94d44a00f5d3f88c0dabd |
institution | Directory Open Access Journal |
issn | 1420-3049 |
language | English |
last_indexed | 2024-03-11T09:32:54Z |
publishDate | 2023-02-01 |
publisher | MDPI AG |
record_format | Article |
series | Molecules |
spelling | doaj.art-ed7c918ee6f94d44a00f5d3f88c0dabd2023-11-16T17:33:05ZengMDPI AGMolecules1420-30492023-02-01283147210.3390/molecules28031472Thermal Annealing Effect on Surface-Enhanced Raman Scattering of Gold Films Deposited on Liquid SubstratesZiran Ye0Haixia Huang1Fengyun Xu2Ping Lu3Yiben Chen4Jiawei Shen5Gaoxiang Ye6Fan Gao7Bo Yan8Department of Applied Physics, College of Science, Zhejiang University of Technology, Hangzhou 310058, ChinaDepartment of Applied Physics, College of Science, Zhejiang University of Technology, Hangzhou 310058, ChinaDepartment of Applied Physics, College of Science, Zhejiang University of Technology, Hangzhou 310058, ChinaDepartment of Applied Physics, College of Science, Zhejiang University of Technology, Hangzhou 310058, ChinaDepartment of Applied Physics, College of Science, Zhejiang University of Technology, Hangzhou 310058, ChinaDepartment of Physics, Zhejiang University, Hangzhou 310015, ChinaDepartment of Physics, Zhejiang University, Hangzhou 310015, ChinaDepartment of Applied Physics, College of Science, Zhejiang University of Technology, Hangzhou 310058, ChinaDepartment of Applied Physics, College of Science, Zhejiang University of Technology, Hangzhou 310058, ChinaWe prepare metal films with various thicknesses on liquid substrates by thermal evaporation and investigate the annealing effect on these films. Gold films deposited on a silicone oil surface consist of a large number of branched aggregates, which contains plenty of gold nanoparticles. This characteristic morphology is mainly attributed to the isotropic and free-sustained liquid substrate. Thermal annealing results in the reintegration of nanoparticles; thus, the surface morphology and microstructure of gold films change significantly. The dependence of annealing conditions on the surface-enhanced Raman scattering performance of gold films is studied, in which gold films show favorable Raman activity when annealed at certain annealing temperature and the experimental results are verified by simulation analysis. The study on the optimal annealing temperature of surface-enhanced Raman scattering substrate will pave the way for the potential application of films deposited on liquid surfaces in microfluidics and enhanced Raman detection.https://www.mdpi.com/1420-3049/28/3/1472thin filmsannealingSERSnanoparticlesliquid substrates |
spellingShingle | Ziran Ye Haixia Huang Fengyun Xu Ping Lu Yiben Chen Jiawei Shen Gaoxiang Ye Fan Gao Bo Yan Thermal Annealing Effect on Surface-Enhanced Raman Scattering of Gold Films Deposited on Liquid Substrates Molecules thin films annealing SERS nanoparticles liquid substrates |
title | Thermal Annealing Effect on Surface-Enhanced Raman Scattering of Gold Films Deposited on Liquid Substrates |
title_full | Thermal Annealing Effect on Surface-Enhanced Raman Scattering of Gold Films Deposited on Liquid Substrates |
title_fullStr | Thermal Annealing Effect on Surface-Enhanced Raman Scattering of Gold Films Deposited on Liquid Substrates |
title_full_unstemmed | Thermal Annealing Effect on Surface-Enhanced Raman Scattering of Gold Films Deposited on Liquid Substrates |
title_short | Thermal Annealing Effect on Surface-Enhanced Raman Scattering of Gold Films Deposited on Liquid Substrates |
title_sort | thermal annealing effect on surface enhanced raman scattering of gold films deposited on liquid substrates |
topic | thin films annealing SERS nanoparticles liquid substrates |
url | https://www.mdpi.com/1420-3049/28/3/1472 |
work_keys_str_mv | AT ziranye thermalannealingeffectonsurfaceenhancedramanscatteringofgoldfilmsdepositedonliquidsubstrates AT haixiahuang thermalannealingeffectonsurfaceenhancedramanscatteringofgoldfilmsdepositedonliquidsubstrates AT fengyunxu thermalannealingeffectonsurfaceenhancedramanscatteringofgoldfilmsdepositedonliquidsubstrates AT pinglu thermalannealingeffectonsurfaceenhancedramanscatteringofgoldfilmsdepositedonliquidsubstrates AT yibenchen thermalannealingeffectonsurfaceenhancedramanscatteringofgoldfilmsdepositedonliquidsubstrates AT jiaweishen thermalannealingeffectonsurfaceenhancedramanscatteringofgoldfilmsdepositedonliquidsubstrates AT gaoxiangye thermalannealingeffectonsurfaceenhancedramanscatteringofgoldfilmsdepositedonliquidsubstrates AT fangao thermalannealingeffectonsurfaceenhancedramanscatteringofgoldfilmsdepositedonliquidsubstrates AT boyan thermalannealingeffectonsurfaceenhancedramanscatteringofgoldfilmsdepositedonliquidsubstrates |