Bis(N′-benzoylpyridine-4-carbohydrazide)(1,10-phenanthroline)copper(II) dinitrate
In the title complex, [Cu(C13H11N3O2)2(C12H8N2)](NO3)2, the CuII atom (site symmetry 2) is coordinated by four N atoms from one 1,10-phenanthroline and two hydrazine ligands, respectively. The hydrazine ligands coordinate to the CuIIatom by a pyridine N atom. These four atoms form a slightly distort...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2010-11-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536810038985 |
| _version_ | 1819105663668715520 |
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| author | Xiu-Qing Zhang Chun-Ying Li He-Dong Bian Qing Yu Hong Liang |
| author_facet | Xiu-Qing Zhang Chun-Ying Li He-Dong Bian Qing Yu Hong Liang |
| author_sort | Xiu-Qing Zhang |
| collection | DOAJ |
| description | In the title complex, [Cu(C13H11N3O2)2(C12H8N2)](NO3)2, the CuII atom (site symmetry 2) is coordinated by four N atoms from one 1,10-phenanthroline and two hydrazine ligands, respectively. The hydrazine ligands coordinate to the CuIIatom by a pyridine N atom. These four atoms form a slightly distorted square-planar N4 donor set. In the packing, two additional Cu...O interactions occur [Cu...O = 2.462 (2) Å], resulting in a typical Jahn–Teller-distorted octahedral environment around the Cu atom. N—H...O hydrogen bonds result in a three-dimensional network. The O atoms of the anion are disordered over two positions in a 0.68 (2):0.32 (2) ratio. |
| first_indexed | 2024-12-22T02:25:50Z |
| format | Article |
| id | doaj.art-eda4ac3e0c1d4374a220ac7c879464fd |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-22T02:25:50Z |
| publishDate | 2010-11-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-eda4ac3e0c1d4374a220ac7c879464fd2022-12-21T18:42:01ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-11-016611m1360m136010.1107/S1600536810038985Bis(N′-benzoylpyridine-4-carbohydrazide)(1,10-phenanthroline)copper(II) dinitrateXiu-Qing ZhangChun-Ying LiHe-Dong BianQing YuHong LiangIn the title complex, [Cu(C13H11N3O2)2(C12H8N2)](NO3)2, the CuII atom (site symmetry 2) is coordinated by four N atoms from one 1,10-phenanthroline and two hydrazine ligands, respectively. The hydrazine ligands coordinate to the CuIIatom by a pyridine N atom. These four atoms form a slightly distorted square-planar N4 donor set. In the packing, two additional Cu...O interactions occur [Cu...O = 2.462 (2) Å], resulting in a typical Jahn–Teller-distorted octahedral environment around the Cu atom. N—H...O hydrogen bonds result in a three-dimensional network. The O atoms of the anion are disordered over two positions in a 0.68 (2):0.32 (2) ratio.http://scripts.iucr.org/cgi-bin/paper?S1600536810038985 |
| spellingShingle | Xiu-Qing Zhang Chun-Ying Li He-Dong Bian Qing Yu Hong Liang Bis(N′-benzoylpyridine-4-carbohydrazide)(1,10-phenanthroline)copper(II) dinitrate Acta Crystallographica Section E |
| title | Bis(N′-benzoylpyridine-4-carbohydrazide)(1,10-phenanthroline)copper(II) dinitrate |
| title_full | Bis(N′-benzoylpyridine-4-carbohydrazide)(1,10-phenanthroline)copper(II) dinitrate |
| title_fullStr | Bis(N′-benzoylpyridine-4-carbohydrazide)(1,10-phenanthroline)copper(II) dinitrate |
| title_full_unstemmed | Bis(N′-benzoylpyridine-4-carbohydrazide)(1,10-phenanthroline)copper(II) dinitrate |
| title_short | Bis(N′-benzoylpyridine-4-carbohydrazide)(1,10-phenanthroline)copper(II) dinitrate |
| title_sort | bis n amp 8242 benzoylpyridine 4 carbohydrazide 1 10 phenanthroline copper ii dinitrate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536810038985 |
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