Recycle of gold mine tailings slurry into MCM-41 mesoporous silica with high specific surface area

In this study, MCM-41 was prepared from the gold mine tailings slurry as an alternative silica source. The effects of the reaction time, temperature, and pH adjustments on the synthesis of MCM-41 were investigated. The optimum condition for the synthesis process of pure and highly ordered MCM-41 fro...

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Bibliographic Details
Main Authors: Acaroglu Degitz Ilayda, Sari Yilmaz Muge, Piskin Sabriye
Format: Article
Language:English
Published: Association of the Chemical Engineers of Serbia 2017-01-01
Series:Chemical Industry and Chemical Engineering Quarterly
Subjects:
Online Access:http://www.doiserbia.nb.rs/img/doi/1451-9372/2017/1451-93721700012A.pdf
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Summary:In this study, MCM-41 was prepared from the gold mine tailings slurry as an alternative silica source. The effects of the reaction time, temperature, and pH adjustments on the synthesis of MCM-41 were investigated. The optimum condition for the synthesis process of pure and highly ordered MCM-41 from tailings slurry was found to be at 30°C for 60 min with a pH of 11. In addition, MCM-41 was synthesized from a pure silica source, in order to compare the structural properties of the obtained sample from that of the slurry produced at optimum conditions. The samples synthesized from tailings slurry had a high surface area of 983 m2/g and a pore volume of 0.74 cm3/g. The structural properties of the samples produced from the slurry were closely related with those that were synthesized from a pure silica source. Results indicate that the tailings slurry has the potential to be used as a cheap, alternative silica source which can be used for the synthesis of a pure and ordered mesoporous silica MCM-41.
ISSN:1451-9372
2217-7434