Gallium Nanoparticles by Surface Wet Disaggregation and Abrasion

Nanoparticles of zerovalent Gallium have been produced by surface disaggregation carried out by means of mechanical abrasion in aqueous phase where capping agents have been dissolved. The particles have been characterized in diameter by dynamic light scattering. At a constant grinding force acting o...

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Main Authors: Andrea P. Reverberi, Marco Salerno, Marco Vocciante, Marco Trofa, Bruno Fabiano
Format: Article
Language:English
Published: AIDIC Servizi S.r.l. 2021-06-01
Series:Chemical Engineering Transactions
Online Access:https://www.cetjournal.it/index.php/cet/article/view/11558
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author Andrea P. Reverberi
Marco Salerno
Marco Vocciante
Marco Trofa
Bruno Fabiano
author_facet Andrea P. Reverberi
Marco Salerno
Marco Vocciante
Marco Trofa
Bruno Fabiano
author_sort Andrea P. Reverberi
collection DOAJ
description Nanoparticles of zerovalent Gallium have been produced by surface disaggregation carried out by means of mechanical abrasion in aqueous phase where capping agents have been dissolved. The particles have been characterized in diameter by dynamic light scattering. At a constant grinding force acting on metal surface, it has been observed that the dimension of the as-produced particles is correlated with the physico-chemical properties of the capping agents. Green and eco-friendly stabilizers like glucose and urea showed a higher efficiency than standard capping agents. Such technique proves that metal particles can be obtained without resorting to complex processes relying upon expensive and energy-wasting mechanical apparatuses based on autogenous and non-autogenous disaggregation. The present method, owing to the absence of toxic or noxious reagents usually employed in standard wet chemical etching processes, may represent a cost-effective and environmentally friendly technique for the synthesis of soft metal particles dispersions with application in theranostics and for heat transfer technologies in mechanical and electronic engineering.
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spelling doaj.art-edc8754951e34b658bc9d4f55b9ebd6b2022-12-21T18:57:37ZengAIDIC Servizi S.r.l.Chemical Engineering Transactions2283-92162021-06-018610.3303/CET2186132Gallium Nanoparticles by Surface Wet Disaggregation and AbrasionAndrea P. ReverberiMarco SalernoMarco VoccianteMarco TrofaBruno FabianoNanoparticles of zerovalent Gallium have been produced by surface disaggregation carried out by means of mechanical abrasion in aqueous phase where capping agents have been dissolved. The particles have been characterized in diameter by dynamic light scattering. At a constant grinding force acting on metal surface, it has been observed that the dimension of the as-produced particles is correlated with the physico-chemical properties of the capping agents. Green and eco-friendly stabilizers like glucose and urea showed a higher efficiency than standard capping agents. Such technique proves that metal particles can be obtained without resorting to complex processes relying upon expensive and energy-wasting mechanical apparatuses based on autogenous and non-autogenous disaggregation. The present method, owing to the absence of toxic or noxious reagents usually employed in standard wet chemical etching processes, may represent a cost-effective and environmentally friendly technique for the synthesis of soft metal particles dispersions with application in theranostics and for heat transfer technologies in mechanical and electronic engineering.https://www.cetjournal.it/index.php/cet/article/view/11558
spellingShingle Andrea P. Reverberi
Marco Salerno
Marco Vocciante
Marco Trofa
Bruno Fabiano
Gallium Nanoparticles by Surface Wet Disaggregation and Abrasion
Chemical Engineering Transactions
title Gallium Nanoparticles by Surface Wet Disaggregation and Abrasion
title_full Gallium Nanoparticles by Surface Wet Disaggregation and Abrasion
title_fullStr Gallium Nanoparticles by Surface Wet Disaggregation and Abrasion
title_full_unstemmed Gallium Nanoparticles by Surface Wet Disaggregation and Abrasion
title_short Gallium Nanoparticles by Surface Wet Disaggregation and Abrasion
title_sort gallium nanoparticles by surface wet disaggregation and abrasion
url https://www.cetjournal.it/index.php/cet/article/view/11558
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AT marcovocciante galliumnanoparticlesbysurfacewetdisaggregationandabrasion
AT marcotrofa galliumnanoparticlesbysurfacewetdisaggregationandabrasion
AT brunofabiano galliumnanoparticlesbysurfacewetdisaggregationandabrasion