Modification of Polyhedral Oligomeric Silsesquioxanes (POSS) Molecules by Ruthenium Catalyzed Cross Metathesis
The scope of ruthenium (Ru)-catalyzed cross metathesis (CM) of allyl-decorated polyhedral oligomeric silsesquioxanes (POSS) was explored. A variety of different commercial and non-commercial ruthenium complexes were tested to determine that the nitro-activated Ru catalyst is optimal for this transfo...
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| Format: | Article |
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MDPI AG
2018-07-01
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| Series: | Molecules |
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| Online Access: | http://www.mdpi.com/1420-3049/23/7/1722 |
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| author | Justyna Czaban-Jóźwiak Łukasz Woźniak Artur Ulikowski Katarzyna Kwiecińska Adam A. Rajkiewicz Karol Grela |
| author_facet | Justyna Czaban-Jóźwiak Łukasz Woźniak Artur Ulikowski Katarzyna Kwiecińska Adam A. Rajkiewicz Karol Grela |
| author_sort | Justyna Czaban-Jóźwiak |
| collection | DOAJ |
| description | The scope of ruthenium (Ru)-catalyzed cross metathesis (CM) of allyl-decorated polyhedral oligomeric silsesquioxanes (POSS) was explored. A variety of different commercial and non-commercial ruthenium complexes were tested to determine that the nitro-activated Ru catalyst is optimal for this transformation. The reported transformation was used to prepare selected hybrid steroid-POSS compounds. |
| first_indexed | 2024-12-21T23:30:21Z |
| format | Article |
| id | doaj.art-eddc8945bf1147bd8b488645286bbb64 |
| institution | Directory Open Access Journal |
| issn | 1420-3049 |
| language | English |
| last_indexed | 2024-12-21T23:30:21Z |
| publishDate | 2018-07-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Molecules |
| spelling | doaj.art-eddc8945bf1147bd8b488645286bbb642022-12-21T18:46:30ZengMDPI AGMolecules1420-30492018-07-01237172210.3390/molecules23071722molecules23071722Modification of Polyhedral Oligomeric Silsesquioxanes (POSS) Molecules by Ruthenium Catalyzed Cross MetathesisJustyna Czaban-Jóźwiak0Łukasz Woźniak1Artur Ulikowski2Katarzyna Kwiecińska3Adam A. Rajkiewicz4Karol Grela5Institute of Organic Chemistry, Polish Academy of Sciences, Kasprzaka 44/52, PO Box 58, 01-224 Warsaw, PolandInstitute of Organic Chemistry, Polish Academy of Sciences, Kasprzaka 44/52, PO Box 58, 01-224 Warsaw, PolandInstitute of Organic Chemistry, Polish Academy of Sciences, Kasprzaka 44/52, PO Box 58, 01-224 Warsaw, PolandInstitute of Organic Chemistry, Polish Academy of Sciences, Kasprzaka 44/52, PO Box 58, 01-224 Warsaw, PolandInstitute of Organic Chemistry, Polish Academy of Sciences, Kasprzaka 44/52, PO Box 58, 01-224 Warsaw, PolandInstitute of Organic Chemistry, Polish Academy of Sciences, Kasprzaka 44/52, PO Box 58, 01-224 Warsaw, PolandThe scope of ruthenium (Ru)-catalyzed cross metathesis (CM) of allyl-decorated polyhedral oligomeric silsesquioxanes (POSS) was explored. A variety of different commercial and non-commercial ruthenium complexes were tested to determine that the nitro-activated Ru catalyst is optimal for this transformation. The reported transformation was used to prepare selected hybrid steroid-POSS compounds.http://www.mdpi.com/1420-3049/23/7/1722cross metathesiscross metathesis (CM)steroidPOSSpolyhedral oligomeric silsesquioxanesruthenium complexes |
| spellingShingle | Justyna Czaban-Jóźwiak Łukasz Woźniak Artur Ulikowski Katarzyna Kwiecińska Adam A. Rajkiewicz Karol Grela Modification of Polyhedral Oligomeric Silsesquioxanes (POSS) Molecules by Ruthenium Catalyzed Cross Metathesis Molecules cross metathesis cross metathesis (CM) steroid POSS polyhedral oligomeric silsesquioxanes ruthenium complexes |
| title | Modification of Polyhedral Oligomeric Silsesquioxanes (POSS) Molecules by Ruthenium Catalyzed Cross Metathesis |
| title_full | Modification of Polyhedral Oligomeric Silsesquioxanes (POSS) Molecules by Ruthenium Catalyzed Cross Metathesis |
| title_fullStr | Modification of Polyhedral Oligomeric Silsesquioxanes (POSS) Molecules by Ruthenium Catalyzed Cross Metathesis |
| title_full_unstemmed | Modification of Polyhedral Oligomeric Silsesquioxanes (POSS) Molecules by Ruthenium Catalyzed Cross Metathesis |
| title_short | Modification of Polyhedral Oligomeric Silsesquioxanes (POSS) Molecules by Ruthenium Catalyzed Cross Metathesis |
| title_sort | modification of polyhedral oligomeric silsesquioxanes poss molecules by ruthenium catalyzed cross metathesis |
| topic | cross metathesis cross metathesis (CM) steroid POSS polyhedral oligomeric silsesquioxanes ruthenium complexes |
| url | http://www.mdpi.com/1420-3049/23/7/1722 |
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