NEW TRANS-1,2- CYCLOHEXYLDIAMINO-NN,N’N’ (CH2CO2)(CH2CO2H)3 ANION CONTAINING ADDUCTS AND DERIVATIVES: SYNTHESIS AND INFRARED STUDY
Five Cyclohexyldiamino-NN, N’N’(CH2CO2)(CH2CO2H)3 anion containing adducts and derivatives with tin, antimony and mercury halides have been synthesized and characterized by infrared spectroscopy. The suggested structures are discrete, the anion behaving as a monodentate or a monochelating ligand: t...
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Formato: | Artigo |
Idioma: | English |
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Alma Mater Publishing House "Vasile Alecsandri" University of Bacau
2017-12-01
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Colecção: | Journal of Engineering Studies and Research |
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Acesso em linha: | https://www.jesr.ub.ro/1/article/view/72 |
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author | GORGUI AWA SECK ABOUBACRY SENE LIBASSE DIOP |
author_facet | GORGUI AWA SECK ABOUBACRY SENE LIBASSE DIOP |
author_sort | GORGUI AWA SECK |
collection | DOAJ |
description |
Five Cyclohexyldiamino-NN, N’N’(CH2CO2)(CH2CO2H)3 anion containing adducts and derivatives with tin, antimony and mercury halides have been synthesized and characterized by infrared spectroscopy. The suggested structures are discrete, the anion behaving as a monodentate or a monochelating ligand: the environments around the metallic centres are trigonal bipyramidal or octahedral.The carboxylic groups and the cation, when involved in extra OH---O, OH----Cl or NH---Cl or O hydrogen bonds may lead to supramolecular architectures.
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first_indexed | 2024-03-07T21:45:55Z |
format | Article |
id | doaj.art-edf9abed1f5a4f53a2630537264dfda8 |
institution | Directory Open Access Journal |
issn | 2068-7559 2344-4932 |
language | English |
last_indexed | 2025-02-18T18:28:43Z |
publishDate | 2017-12-01 |
publisher | Alma Mater Publishing House "Vasile Alecsandri" University of Bacau |
record_format | Article |
series | Journal of Engineering Studies and Research |
spelling | doaj.art-edf9abed1f5a4f53a2630537264dfda82024-10-22T03:26:22ZengAlma Mater Publishing House "Vasile Alecsandri" University of BacauJournal of Engineering Studies and Research2068-75592344-49322017-12-0123410.29081/jesr.v23i4.72NEW TRANS-1,2- CYCLOHEXYLDIAMINO-NN,N’N’ (CH2CO2)(CH2CO2H)3 ANION CONTAINING ADDUCTS AND DERIVATIVES: SYNTHESIS AND INFRARED STUDYGORGUI AWA SECK0 ABOUBACRY SENE1LIBASSE DIOP2Université Cheikh Anta Diop, Faculté des Sciences et Techniques- Département de Chimie, Laboratoire de Chimie Minérale et Analytique, DAKAR, Senegal Université Cheikh Anta Diop, Faculté des Sciences et Techniques- Département de Chimie, Laboratoire de Chimie Minérale et Analytique, DAKAR, Senegal Université Cheikh Anta Diop, Faculté des Sciences et Techniques- Département de Chimie, Laboratoire de Chimie Minérale et Analytique, DAKAR, Senegal Five Cyclohexyldiamino-NN, N’N’(CH2CO2)(CH2CO2H)3 anion containing adducts and derivatives with tin, antimony and mercury halides have been synthesized and characterized by infrared spectroscopy. The suggested structures are discrete, the anion behaving as a monodentate or a monochelating ligand: the environments around the metallic centres are trigonal bipyramidal or octahedral.The carboxylic groups and the cation, when involved in extra OH---O, OH----Cl or NH---Cl or O hydrogen bonds may lead to supramolecular architectures. https://www.jesr.ub.ro/1/article/view/72monodentate or monochelating ligandsupramolecular architecturestrigonal bipyramidal or octahedral environments |
spellingShingle | GORGUI AWA SECK ABOUBACRY SENE LIBASSE DIOP NEW TRANS-1,2- CYCLOHEXYLDIAMINO-NN,N’N’ (CH2CO2)(CH2CO2H)3 ANION CONTAINING ADDUCTS AND DERIVATIVES: SYNTHESIS AND INFRARED STUDY Journal of Engineering Studies and Research monodentate or monochelating ligand supramolecular architectures trigonal bipyramidal or octahedral environments |
title | NEW TRANS-1,2- CYCLOHEXYLDIAMINO-NN,N’N’ (CH2CO2)(CH2CO2H)3 ANION CONTAINING ADDUCTS AND DERIVATIVES: SYNTHESIS AND INFRARED STUDY |
title_full | NEW TRANS-1,2- CYCLOHEXYLDIAMINO-NN,N’N’ (CH2CO2)(CH2CO2H)3 ANION CONTAINING ADDUCTS AND DERIVATIVES: SYNTHESIS AND INFRARED STUDY |
title_fullStr | NEW TRANS-1,2- CYCLOHEXYLDIAMINO-NN,N’N’ (CH2CO2)(CH2CO2H)3 ANION CONTAINING ADDUCTS AND DERIVATIVES: SYNTHESIS AND INFRARED STUDY |
title_full_unstemmed | NEW TRANS-1,2- CYCLOHEXYLDIAMINO-NN,N’N’ (CH2CO2)(CH2CO2H)3 ANION CONTAINING ADDUCTS AND DERIVATIVES: SYNTHESIS AND INFRARED STUDY |
title_short | NEW TRANS-1,2- CYCLOHEXYLDIAMINO-NN,N’N’ (CH2CO2)(CH2CO2H)3 ANION CONTAINING ADDUCTS AND DERIVATIVES: SYNTHESIS AND INFRARED STUDY |
title_sort | new trans 1 2 cyclohexyldiamino nn n n ch2co2 ch2co2h 3 anion containing adducts and derivatives synthesis and infrared study |
topic | monodentate or monochelating ligand supramolecular architectures trigonal bipyramidal or octahedral environments |
url | https://www.jesr.ub.ro/1/article/view/72 |
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