NEW TRANS-1,2- CYCLOHEXYLDIAMINO-NN,N’N’ (CH2CO2)(CH2CO2H)3 ANION CONTAINING ADDUCTS AND DERIVATIVES: SYNTHESIS AND INFRARED STUDY

Five Cyclohexyldiamino-NN, N’N’(CH2CO2)(CH2CO2H)3 anion containing adducts and derivatives with tin, antimony and mercury halides have been synthesized and characterized by infrared spectroscopy. The suggested structures are discrete, the anion behaving as a monodentate or a monochelating ligand: t...

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Main Authors: GORGUI AWA SECK, ABOUBACRY SENE, LIBASSE DIOP
Formato: Artigo
Idioma:English
Publicado em: Alma Mater Publishing House "Vasile Alecsandri" University of Bacau 2017-12-01
Colecção:Journal of Engineering Studies and Research
Assuntos:
Acesso em linha:https://www.jesr.ub.ro/1/article/view/72
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author GORGUI AWA SECK
ABOUBACRY SENE
LIBASSE DIOP
author_facet GORGUI AWA SECK
ABOUBACRY SENE
LIBASSE DIOP
author_sort GORGUI AWA SECK
collection DOAJ
description Five Cyclohexyldiamino-NN, N’N’(CH2CO2)(CH2CO2H)3 anion containing adducts and derivatives with tin, antimony and mercury halides have been synthesized and characterized by infrared spectroscopy. The suggested structures are discrete, the anion behaving as a monodentate or a monochelating ligand: the environments around the metallic centres are trigonal bipyramidal or octahedral.The carboxylic groups and the cation, when involved in extra OH---O, OH----Cl or NH---Cl or O hydrogen bonds may lead to supramolecular architectures.
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spelling doaj.art-edf9abed1f5a4f53a2630537264dfda82024-10-22T03:26:22ZengAlma Mater Publishing House "Vasile Alecsandri" University of BacauJournal of Engineering Studies and Research2068-75592344-49322017-12-0123410.29081/jesr.v23i4.72NEW TRANS-1,2- CYCLOHEXYLDIAMINO-NN,N’N’ (CH2CO2)(CH2CO2H)3 ANION CONTAINING ADDUCTS AND DERIVATIVES: SYNTHESIS AND INFRARED STUDYGORGUI AWA SECK0 ABOUBACRY SENE1LIBASSE DIOP2Université Cheikh Anta Diop, Faculté des Sciences et Techniques- Département de Chimie, Laboratoire de Chimie Minérale et Analytique, DAKAR, Senegal Université Cheikh Anta Diop, Faculté des Sciences et Techniques- Département de Chimie, Laboratoire de Chimie Minérale et Analytique, DAKAR, Senegal Université Cheikh Anta Diop, Faculté des Sciences et Techniques- Département de Chimie, Laboratoire de Chimie Minérale et Analytique, DAKAR, Senegal Five Cyclohexyldiamino-NN, N’N’(CH2CO2)(CH2CO2H)3 anion containing adducts and derivatives with tin, antimony and mercury halides have been synthesized and characterized by infrared spectroscopy. The suggested structures are discrete, the anion behaving as a monodentate or a monochelating ligand: the environments around the metallic centres are trigonal bipyramidal or octahedral.The carboxylic groups and the cation, when involved in extra OH---O, OH----Cl or NH---Cl or O hydrogen bonds may lead to supramolecular architectures. https://www.jesr.ub.ro/1/article/view/72monodentate or monochelating ligandsupramolecular architecturestrigonal bipyramidal or octahedral environments
spellingShingle GORGUI AWA SECK
ABOUBACRY SENE
LIBASSE DIOP
NEW TRANS-1,2- CYCLOHEXYLDIAMINO-NN,N’N’ (CH2CO2)(CH2CO2H)3 ANION CONTAINING ADDUCTS AND DERIVATIVES: SYNTHESIS AND INFRARED STUDY
Journal of Engineering Studies and Research
monodentate or monochelating ligand
supramolecular architectures
trigonal bipyramidal or octahedral environments
title NEW TRANS-1,2- CYCLOHEXYLDIAMINO-NN,N’N’ (CH2CO2)(CH2CO2H)3 ANION CONTAINING ADDUCTS AND DERIVATIVES: SYNTHESIS AND INFRARED STUDY
title_full NEW TRANS-1,2- CYCLOHEXYLDIAMINO-NN,N’N’ (CH2CO2)(CH2CO2H)3 ANION CONTAINING ADDUCTS AND DERIVATIVES: SYNTHESIS AND INFRARED STUDY
title_fullStr NEW TRANS-1,2- CYCLOHEXYLDIAMINO-NN,N’N’ (CH2CO2)(CH2CO2H)3 ANION CONTAINING ADDUCTS AND DERIVATIVES: SYNTHESIS AND INFRARED STUDY
title_full_unstemmed NEW TRANS-1,2- CYCLOHEXYLDIAMINO-NN,N’N’ (CH2CO2)(CH2CO2H)3 ANION CONTAINING ADDUCTS AND DERIVATIVES: SYNTHESIS AND INFRARED STUDY
title_short NEW TRANS-1,2- CYCLOHEXYLDIAMINO-NN,N’N’ (CH2CO2)(CH2CO2H)3 ANION CONTAINING ADDUCTS AND DERIVATIVES: SYNTHESIS AND INFRARED STUDY
title_sort new trans 1 2 cyclohexyldiamino nn n n ch2co2 ch2co2h 3 anion containing adducts and derivatives synthesis and infrared study
topic monodentate or monochelating ligand
supramolecular architectures
trigonal bipyramidal or octahedral environments
url https://www.jesr.ub.ro/1/article/view/72
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AT aboubacrysene newtrans12cyclohexyldiaminonnnnch2co2ch2co2h3anioncontainingadductsandderivativessynthesisandinfraredstudy
AT libassediop newtrans12cyclohexyldiaminonnnnch2co2ch2co2h3anioncontainingadductsandderivativessynthesisandinfraredstudy