Hydride-based antiperovskites with soft anionic sublattices as fast alkali ionic conductors
Oxide-based lithium/sodium-rich antiperovskites are regarded as promising solid electrolytes. Here, authors report a series of antiperovskites with a soft lattice containing hydride (H–) and chalcogenide (S2–, Se2–, Te2–) anions, enabling the fast Li+ /Na+ transport assisted by rotational phonon mod...
| Main Authors: | , , , , , , , , , , , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
Nature Portfolio
2021-01-01
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| Series: | Nature Communications |
| Online Access: | https://doi.org/10.1038/s41467-020-20370-2 |
| _version_ | 1830176906223288320 |
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| author | Shenghan Gao Thibault Broux Susumu Fujii Cédric Tassel Kentaro Yamamoto Yao Xiao Itaru Oikawa Hitoshi Takamura Hiroki Ubukata Yuki Watanabe Kotaro Fujii Masatomo Yashima Akihide Kuwabara Yoshiharu Uchimoto Hiroshi Kageyama |
| author_facet | Shenghan Gao Thibault Broux Susumu Fujii Cédric Tassel Kentaro Yamamoto Yao Xiao Itaru Oikawa Hitoshi Takamura Hiroki Ubukata Yuki Watanabe Kotaro Fujii Masatomo Yashima Akihide Kuwabara Yoshiharu Uchimoto Hiroshi Kageyama |
| author_sort | Shenghan Gao |
| collection | DOAJ |
| description | Oxide-based lithium/sodium-rich antiperovskites are regarded as promising solid electrolytes. Here, authors report a series of antiperovskites with a soft lattice containing hydride (H–) and chalcogenide (S2–, Se2–, Te2–) anions, enabling the fast Li+ /Na+ transport assisted by rotational phonon modes. |
| first_indexed | 2024-12-17T19:16:06Z |
| format | Article |
| id | doaj.art-ee1934e208b14e8a8e8bae43d8fe400c |
| institution | Directory Open Access Journal |
| issn | 2041-1723 |
| language | English |
| last_indexed | 2024-12-17T19:16:06Z |
| publishDate | 2021-01-01 |
| publisher | Nature Portfolio |
| record_format | Article |
| series | Nature Communications |
| spelling | doaj.art-ee1934e208b14e8a8e8bae43d8fe400c2022-12-21T21:35:46ZengNature PortfolioNature Communications2041-17232021-01-0112111010.1038/s41467-020-20370-2Hydride-based antiperovskites with soft anionic sublattices as fast alkali ionic conductorsShenghan Gao0Thibault Broux1Susumu Fujii2Cédric Tassel3Kentaro Yamamoto4Yao Xiao5Itaru Oikawa6Hitoshi Takamura7Hiroki Ubukata8Yuki Watanabe9Kotaro Fujii10Masatomo Yashima11Akihide Kuwabara12Yoshiharu Uchimoto13Hiroshi Kageyama14Department of Energy and Hydrocarbon Chemistry, Graduate School of Engineering, Kyoto UniversityDepartment of Energy and Hydrocarbon Chemistry, Graduate School of Engineering, Kyoto UniversityNanostructures Research Laboratory, Japan Fine Ceramics CenterDepartment of Energy and Hydrocarbon Chemistry, Graduate School of Engineering, Kyoto UniversityGraduate School of Human and Environmental Studies, Kyoto UniversityGraduate School of Human and Environmental Studies, Kyoto UniversityDepartment of Materials Science, Graduate School of Engineering, Tohoku UniversityDepartment of Materials Science, Graduate School of Engineering, Tohoku UniversityDepartment of Energy and Hydrocarbon Chemistry, Graduate School of Engineering, Kyoto UniversityDepartment of Energy and Hydrocarbon Chemistry, Graduate School of Engineering, Kyoto UniversityDepartment of Chemistry, School of Science, Tokyo Institute of TechnologyDepartment of Chemistry, School of Science, Tokyo Institute of TechnologyNanostructures Research Laboratory, Japan Fine Ceramics CenterGraduate School of Human and Environmental Studies, Kyoto UniversityDepartment of Energy and Hydrocarbon Chemistry, Graduate School of Engineering, Kyoto UniversityOxide-based lithium/sodium-rich antiperovskites are regarded as promising solid electrolytes. Here, authors report a series of antiperovskites with a soft lattice containing hydride (H–) and chalcogenide (S2–, Se2–, Te2–) anions, enabling the fast Li+ /Na+ transport assisted by rotational phonon modes.https://doi.org/10.1038/s41467-020-20370-2 |
| spellingShingle | Shenghan Gao Thibault Broux Susumu Fujii Cédric Tassel Kentaro Yamamoto Yao Xiao Itaru Oikawa Hitoshi Takamura Hiroki Ubukata Yuki Watanabe Kotaro Fujii Masatomo Yashima Akihide Kuwabara Yoshiharu Uchimoto Hiroshi Kageyama Hydride-based antiperovskites with soft anionic sublattices as fast alkali ionic conductors Nature Communications |
| title | Hydride-based antiperovskites with soft anionic sublattices as fast alkali ionic conductors |
| title_full | Hydride-based antiperovskites with soft anionic sublattices as fast alkali ionic conductors |
| title_fullStr | Hydride-based antiperovskites with soft anionic sublattices as fast alkali ionic conductors |
| title_full_unstemmed | Hydride-based antiperovskites with soft anionic sublattices as fast alkali ionic conductors |
| title_short | Hydride-based antiperovskites with soft anionic sublattices as fast alkali ionic conductors |
| title_sort | hydride based antiperovskites with soft anionic sublattices as fast alkali ionic conductors |
| url | https://doi.org/10.1038/s41467-020-20370-2 |
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