Alkene Epoxidations Mediated by Mn-Salen Macrocyclic Catalysts
Three new chiral Mn macrocycle catalysts containing 20 or 40 atoms in the macrocycle were synthetized and tested in the enantioselective epoxidation of cis-β-ethyl-styrene and 1,2-dihydronathalene. The effect of the presence of a binaphtol (BINOL) compound in the catalyst backbone has been evaluated...
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| Format: | Article |
| Language: | English |
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MDPI AG
2021-04-01
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| Series: | Catalysts |
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| Online Access: | https://www.mdpi.com/2073-4344/11/4/465 |
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| author | Andrea Pappalardo Francesco P. Ballistreri Rosa Maria Toscano Maria Assunta Chiacchio Laura Legnani Giovanni Grazioso Lucia Veltri Giuseppe Trusso Sfrazzetto |
| author_facet | Andrea Pappalardo Francesco P. Ballistreri Rosa Maria Toscano Maria Assunta Chiacchio Laura Legnani Giovanni Grazioso Lucia Veltri Giuseppe Trusso Sfrazzetto |
| author_sort | Andrea Pappalardo |
| collection | DOAJ |
| description | Three new chiral Mn macrocycle catalysts containing 20 or 40 atoms in the macrocycle were synthetized and tested in the enantioselective epoxidation of cis-β-ethyl-styrene and 1,2-dihydronathalene. The effect of the presence of a binaphtol (BINOL) compound in the catalyst backbone has been evaluated, including by Density Functional Theory (DFT) calculations. |
| first_indexed | 2024-03-10T12:40:07Z |
| format | Article |
| id | doaj.art-ee1cef81bf674d0c94a7f447492b0641 |
| institution | Directory Open Access Journal |
| issn | 2073-4344 |
| language | English |
| last_indexed | 2024-03-10T12:40:07Z |
| publishDate | 2021-04-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Catalysts |
| spelling | doaj.art-ee1cef81bf674d0c94a7f447492b06412023-11-21T13:57:23ZengMDPI AGCatalysts2073-43442021-04-0111446510.3390/catal11040465Alkene Epoxidations Mediated by Mn-Salen Macrocyclic CatalystsAndrea Pappalardo0Francesco P. Ballistreri1Rosa Maria Toscano2Maria Assunta Chiacchio3Laura Legnani4Giovanni Grazioso5Lucia Veltri6Giuseppe Trusso Sfrazzetto7Department of Chemical Sciences, University of Catania, 95125 Catania, ItalyDepartment of Chemical Sciences, University of Catania, 95125 Catania, ItalyDepartment of Chemical Sciences, University of Catania, 95125 Catania, ItalyDepartment of Drug Sciences, University of Catania, Viale A. Doria 6, 95125 Catania, ItalyDepartment of Drug Sciences, University of Catania, Viale A. Doria 6, 95125 Catania, ItalyDipartimento di Scienze Farmaceutiche, Università degli Studi di Milano, Via L. Mangiagalli 25, 20133 Milan, ItalyLaboratory of Industrial and Synthetic Organic Chemistry (LISOC), Department of Chemistry and Chemical Technologies, University of Calabria, Via P. Bucci 12/C, 87036 Arcavacata di Rende, ItalyDepartment of Chemical Sciences, University of Catania, 95125 Catania, ItalyThree new chiral Mn macrocycle catalysts containing 20 or 40 atoms in the macrocycle were synthetized and tested in the enantioselective epoxidation of cis-β-ethyl-styrene and 1,2-dihydronathalene. The effect of the presence of a binaphtol (BINOL) compound in the catalyst backbone has been evaluated, including by Density Functional Theory (DFT) calculations.https://www.mdpi.com/2073-4344/11/4/465enantioselectiveepoxidationMn catalystalkeneDFT |
| spellingShingle | Andrea Pappalardo Francesco P. Ballistreri Rosa Maria Toscano Maria Assunta Chiacchio Laura Legnani Giovanni Grazioso Lucia Veltri Giuseppe Trusso Sfrazzetto Alkene Epoxidations Mediated by Mn-Salen Macrocyclic Catalysts Catalysts enantioselective epoxidation Mn catalyst alkene DFT |
| title | Alkene Epoxidations Mediated by Mn-Salen Macrocyclic Catalysts |
| title_full | Alkene Epoxidations Mediated by Mn-Salen Macrocyclic Catalysts |
| title_fullStr | Alkene Epoxidations Mediated by Mn-Salen Macrocyclic Catalysts |
| title_full_unstemmed | Alkene Epoxidations Mediated by Mn-Salen Macrocyclic Catalysts |
| title_short | Alkene Epoxidations Mediated by Mn-Salen Macrocyclic Catalysts |
| title_sort | alkene epoxidations mediated by mn salen macrocyclic catalysts |
| topic | enantioselective epoxidation Mn catalyst alkene DFT |
| url | https://www.mdpi.com/2073-4344/11/4/465 |
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