Alkene Epoxidations Mediated by Mn-Salen Macrocyclic Catalysts

Alkene Epoxidations Mediated by Mn-Salen Macrocyclic Catalysts

Three new chiral Mn macrocycle catalysts containing 20 or 40 atoms in the macrocycle were synthetized and tested in the enantioselective epoxidation of cis-β-ethyl-styrene and 1,2-dihydronathalene. The effect of the presence of a binaphtol (BINOL) compound in the catalyst backbone has been evaluated...

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Bibliographic Details
Main Authors:	Andrea Pappalardo, Francesco P. Ballistreri, Rosa Maria Toscano, Maria Assunta Chiacchio, Laura Legnani, Giovanni Grazioso, Lucia Veltri, Giuseppe Trusso Sfrazzetto
Format:	Article
Language:	English
Published:	MDPI AG 2021-04-01
Series:	Catalysts
Subjects:	enantioselective epoxidation Mn catalyst alkene DFT
Online Access:	https://www.mdpi.com/2073-4344/11/4/465

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