catena-Poly[[bis(nitrato-κ2O,O′)copper(II)]-μ-2,2′-(ethane-1,2-diyldithio)di-1,3,4-thiadiazole-κ2N4:N4′]
In the title compound, [Cu(NO3)2(C6H6N4S4)]n, the CuII atom, occupying a crystallographic inversion centre, is six-coordinated by two N atoms of two 2,2′-[1,2-ethanediylbis(thio)]bis[1,3,4-thiadiazole] ligands in trans positions, and four O atoms from two symmetry-related opposite nitrate...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2009-01-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536808041202 |
| _version_ | 1828882102556295168 |
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| author | Hua-Ming Huang Feng-Yang Ju Jian-Ge Wang Jian-Hua Qin |
| author_facet | Hua-Ming Huang Feng-Yang Ju Jian-Ge Wang Jian-Hua Qin |
| author_sort | Hua-Ming Huang |
| collection | DOAJ |
| description | In the title compound, [Cu(NO3)2(C6H6N4S4)]n, the CuII atom, occupying a crystallographic inversion centre, is six-coordinated by two N atoms of two 2,2′-[1,2-ethanediylbis(thio)]bis[1,3,4-thiadiazole] ligands in trans positions, and four O atoms from two symmetry-related opposite nitrate anions, which are asymmetrically bonded, resulting in a strong distorted octahedral geometry of the central atom. The ethane group is equally disordered over two sites via another inversion centre. The bridging bidentate 2,2′-[1,2-ethanediylbis(thio)]bis[1,3,4-thiadiazole] ligands link the CuII centres into a one-dimensional chain. The chains are interconnected via intermolecular S...O interactions [3.044 (4) and 3.084 (5) Å] and weak C—H...O hydrogen bonds, generating a three-dimensional supramolecular structure. |
| first_indexed | 2024-12-13T10:21:34Z |
| format | Article |
| id | doaj.art-ee426c04b2734fa78b5e4772eca3f6e5 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-13T10:21:34Z |
| publishDate | 2009-01-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-ee426c04b2734fa78b5e4772eca3f6e52022-12-21T23:51:11ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-01-01651m80m8110.1107/S1600536808041202catena-Poly[[bis(nitrato-κ2O,O′)copper(II)]-μ-2,2′-(ethane-1,2-diyldithio)di-1,3,4-thiadiazole-κ2N4:N4′]Hua-Ming HuangFeng-Yang JuJian-Ge WangJian-Hua QinIn the title compound, [Cu(NO3)2(C6H6N4S4)]n, the CuII atom, occupying a crystallographic inversion centre, is six-coordinated by two N atoms of two 2,2′-[1,2-ethanediylbis(thio)]bis[1,3,4-thiadiazole] ligands in trans positions, and four O atoms from two symmetry-related opposite nitrate anions, which are asymmetrically bonded, resulting in a strong distorted octahedral geometry of the central atom. The ethane group is equally disordered over two sites via another inversion centre. The bridging bidentate 2,2′-[1,2-ethanediylbis(thio)]bis[1,3,4-thiadiazole] ligands link the CuII centres into a one-dimensional chain. The chains are interconnected via intermolecular S...O interactions [3.044 (4) and 3.084 (5) Å] and weak C—H...O hydrogen bonds, generating a three-dimensional supramolecular structure.http://scripts.iucr.org/cgi-bin/paper?S1600536808041202 |
| spellingShingle | Hua-Ming Huang Feng-Yang Ju Jian-Ge Wang Jian-Hua Qin catena-Poly[[bis(nitrato-κ2O,O′)copper(II)]-μ-2,2′-(ethane-1,2-diyldithio)di-1,3,4-thiadiazole-κ2N4:N4′] Acta Crystallographica Section E |
| title | catena-Poly[[bis(nitrato-κ2O,O′)copper(II)]-μ-2,2′-(ethane-1,2-diyldithio)di-1,3,4-thiadiazole-κ2N4:N4′] |
| title_full | catena-Poly[[bis(nitrato-κ2O,O′)copper(II)]-μ-2,2′-(ethane-1,2-diyldithio)di-1,3,4-thiadiazole-κ2N4:N4′] |
| title_fullStr | catena-Poly[[bis(nitrato-κ2O,O′)copper(II)]-μ-2,2′-(ethane-1,2-diyldithio)di-1,3,4-thiadiazole-κ2N4:N4′] |
| title_full_unstemmed | catena-Poly[[bis(nitrato-κ2O,O′)copper(II)]-μ-2,2′-(ethane-1,2-diyldithio)di-1,3,4-thiadiazole-κ2N4:N4′] |
| title_short | catena-Poly[[bis(nitrato-κ2O,O′)copper(II)]-μ-2,2′-(ethane-1,2-diyldithio)di-1,3,4-thiadiazole-κ2N4:N4′] |
| title_sort | catena poly bis nitrato 954 2o o 8242 copper ii 956 2 2 8242 ethane 1 2 diyldithio di 1 3 4 thiadiazole 954 2n4 n4 8242 |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536808041202 |
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