Cyclodextrin Effect on Intramolecular Catalysis
HPCD inhibits the hydrolysis reaction of monoamides and monoesters of phthalic and maleic acid at pH 2. The magnitude of inhibition depends on the leaving group. For some of the substrates, the reaction in the cavity is more than 100 times slower than that in solution.
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
MDPI AG
2000-03-01
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| Series: | Molecules |
| Subjects: | |
| Online Access: | http://www.mdpi.com/1420-3049/5/3/405/ |
| _version_ | 1818540083229229056 |
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| author | A. M. Granados G. O. Andres R. Hoyos de Rossi |
| author_facet | A. M. Granados G. O. Andres R. Hoyos de Rossi |
| author_sort | A. M. Granados |
| collection | DOAJ |
| description | HPCD inhibits the hydrolysis reaction of monoamides and monoesters of phthalic and maleic acid at pH 2. The magnitude of inhibition depends on the leaving group. For some of the substrates, the reaction in the cavity is more than 100 times slower than that in solution. |
| first_indexed | 2024-12-11T21:50:41Z |
| format | Article |
| id | doaj.art-ee4e059c6f81458ea51c8f67430719fa |
| institution | Directory Open Access Journal |
| issn | 1420-3049 |
| language | English |
| last_indexed | 2024-12-11T21:50:41Z |
| publishDate | 2000-03-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Molecules |
| spelling | doaj.art-ee4e059c6f81458ea51c8f67430719fa2022-12-22T00:49:29ZengMDPI AGMolecules1420-30492000-03-015340540610.3390/50300405Cyclodextrin Effect on Intramolecular CatalysisA. M. GranadosG. O. AndresR. Hoyos de RossiHPCD inhibits the hydrolysis reaction of monoamides and monoesters of phthalic and maleic acid at pH 2. The magnitude of inhibition depends on the leaving group. For some of the substrates, the reaction in the cavity is more than 100 times slower than that in solution.http://www.mdpi.com/1420-3049/5/3/405/n/a |
| spellingShingle | A. M. Granados G. O. Andres R. Hoyos de Rossi Cyclodextrin Effect on Intramolecular Catalysis Molecules n/a |
| title | Cyclodextrin Effect on Intramolecular Catalysis |
| title_full | Cyclodextrin Effect on Intramolecular Catalysis |
| title_fullStr | Cyclodextrin Effect on Intramolecular Catalysis |
| title_full_unstemmed | Cyclodextrin Effect on Intramolecular Catalysis |
| title_short | Cyclodextrin Effect on Intramolecular Catalysis |
| title_sort | cyclodextrin effect on intramolecular catalysis |
| topic | n/a |
| url | http://www.mdpi.com/1420-3049/5/3/405/ |
| work_keys_str_mv | AT amgranados cyclodextrineffectonintramolecularcatalysis AT goandres cyclodextrineffectonintramolecularcatalysis AT rhoyosderossi cyclodextrineffectonintramolecularcatalysis |