New particle formation during <font face='Symbol' >a</font>- and <font face='Symbol' >b</font>-pinene oxidation by O<sub>3</sub>, OH and NO<sub>3</sub>, and the influence of water vapour: particle size distribution studies
New particle formation during the oxidation of <font face='Symbol' >a</font>- and <font face='Symbol' >b</font>-pinene (C<sub>10</sub>H<sub>16</sub>) by ozone, OH and NO<sub>3</sub> was studied by measuring the...
| Main Authors: | , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
Copernicus Publications
2002-01-01
|
| Series: | Atmospheric Chemistry and Physics |
| Online Access: | http://www.atmos-chem-phys.net/2/183/2002/acp-2-183-2002.pdf |
| _version_ | 1828921909464530944 |
|---|---|
| author | B. Bonn G. K. Moorgat |
| author_facet | B. Bonn G. K. Moorgat |
| author_sort | B. Bonn |
| collection | DOAJ |
| description | New particle formation during the oxidation of <font face='Symbol' >a</font>- and <font face='Symbol' >b</font>-pinene (C<sub>10</sub>H<sub>16</sub>) by ozone, OH and NO<sub>3</sub> was studied by measuring the particle size distributions with a scanning mobility particle sizer (TSI 3936). The results indicate a drastically higher nucleation potential of the ozonolysis than in the reaction with either OH or NO<sub>3</sub>. On the contrary, the contribution of the individual oxidation reactions to form new aerosol volume was found to depend on the location of the carbon double bond to be oxidised: for the <i>endocyclic</i> <font face='Symbol' >a</font>-pinene reactions the ozonolysis contributed mostly to the aerosol volume yield, whereas for the <i>exocyclic</i> <font face='Symbol' >b</font>-pinene reactions the oxidation by O<sub>3</sub>, OH and NO<sub>3</sub> yielded a similar aerosol volume.<br> <br> In a second part of this study the influence of water vapour on the nucleation in all three possible oxidation routes was examined. The observations revealed only an effect of water vapour during the ozonolysis reactions. |
| first_indexed | 2024-12-13T22:11:26Z |
| format | Article |
| id | doaj.art-ee5d656d22f94cf68b8805c14940b7e0 |
| institution | Directory Open Access Journal |
| issn | 1680-7316 1680-7324 |
| language | English |
| last_indexed | 2024-12-13T22:11:26Z |
| publishDate | 2002-01-01 |
| publisher | Copernicus Publications |
| record_format | Article |
| series | Atmospheric Chemistry and Physics |
| spelling | doaj.art-ee5d656d22f94cf68b8805c14940b7e02022-12-21T23:29:42ZengCopernicus PublicationsAtmospheric Chemistry and Physics1680-73161680-73242002-01-0123183196New particle formation during <font face='Symbol' >a</font>- and <font face='Symbol' >b</font>-pinene oxidation by O<sub>3</sub>, OH and NO<sub>3</sub>, and the influence of water vapour: particle size distribution studiesB. BonnG. K. MoorgatNew particle formation during the oxidation of <font face='Symbol' >a</font>- and <font face='Symbol' >b</font>-pinene (C<sub>10</sub>H<sub>16</sub>) by ozone, OH and NO<sub>3</sub> was studied by measuring the particle size distributions with a scanning mobility particle sizer (TSI 3936). The results indicate a drastically higher nucleation potential of the ozonolysis than in the reaction with either OH or NO<sub>3</sub>. On the contrary, the contribution of the individual oxidation reactions to form new aerosol volume was found to depend on the location of the carbon double bond to be oxidised: for the <i>endocyclic</i> <font face='Symbol' >a</font>-pinene reactions the ozonolysis contributed mostly to the aerosol volume yield, whereas for the <i>exocyclic</i> <font face='Symbol' >b</font>-pinene reactions the oxidation by O<sub>3</sub>, OH and NO<sub>3</sub> yielded a similar aerosol volume.<br> <br> In a second part of this study the influence of water vapour on the nucleation in all three possible oxidation routes was examined. The observations revealed only an effect of water vapour during the ozonolysis reactions.http://www.atmos-chem-phys.net/2/183/2002/acp-2-183-2002.pdf |
| spellingShingle | B. Bonn G. K. Moorgat New particle formation during <font face='Symbol' >a</font>- and <font face='Symbol' >b</font>-pinene oxidation by O<sub>3</sub>, OH and NO<sub>3</sub>, and the influence of water vapour: particle size distribution studies Atmospheric Chemistry and Physics |
| title | New particle formation during <font face='Symbol' >a</font>- and <font face='Symbol' >b</font>-pinene oxidation by O<sub>3</sub>, OH and NO<sub>3</sub>, and the influence of water vapour: particle size distribution studies |
| title_full | New particle formation during <font face='Symbol' >a</font>- and <font face='Symbol' >b</font>-pinene oxidation by O<sub>3</sub>, OH and NO<sub>3</sub>, and the influence of water vapour: particle size distribution studies |
| title_fullStr | New particle formation during <font face='Symbol' >a</font>- and <font face='Symbol' >b</font>-pinene oxidation by O<sub>3</sub>, OH and NO<sub>3</sub>, and the influence of water vapour: particle size distribution studies |
| title_full_unstemmed | New particle formation during <font face='Symbol' >a</font>- and <font face='Symbol' >b</font>-pinene oxidation by O<sub>3</sub>, OH and NO<sub>3</sub>, and the influence of water vapour: particle size distribution studies |
| title_short | New particle formation during <font face='Symbol' >a</font>- and <font face='Symbol' >b</font>-pinene oxidation by O<sub>3</sub>, OH and NO<sub>3</sub>, and the influence of water vapour: particle size distribution studies |
| title_sort | new particle formation during font face symbol a font and font face symbol b font pinene oxidation by o sub 3 sub oh and no sub 3 sub and the influence of water vapour particle size distribution studies |
| url | http://www.atmos-chem-phys.net/2/183/2002/acp-2-183-2002.pdf |
| work_keys_str_mv | AT bbonn newparticleformationduringfontfacesymbolafontandfontfacesymbolbfontpineneoxidationbyosub3subohandnosub3subandtheinfluenceofwatervapourparticlesizedistributionstudies AT gkmoorgat newparticleformationduringfontfacesymbolafontandfontfacesymbolbfontpineneoxidationbyosub3subohandnosub3subandtheinfluenceofwatervapourparticlesizedistributionstudies |