Holey Graphene for Electrochemical Energy Storage
Summary: Graphene and its hybrids have been considered promising candidates for electrochemical energy storage because of their fascinating physicochemical properties. However, they suffer from unsatisfactory areal or volumetric energy density and relatively poor rate performance. These drawbacks ar...
Main Authors: | , , , , |
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Format: | Article |
Language: | English |
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Elsevier
2020-10-01
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Series: | Cell Reports Physical Science |
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Online Access: | http://www.sciencedirect.com/science/article/pii/S2666386420302307 |
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author | Tao Liu Liuyang Zhang Bei Cheng Xianluo Hu Jiaguo Yu |
author_facet | Tao Liu Liuyang Zhang Bei Cheng Xianluo Hu Jiaguo Yu |
author_sort | Tao Liu |
collection | DOAJ |
description | Summary: Graphene and its hybrids have been considered promising candidates for electrochemical energy storage because of their fascinating physicochemical properties. However, they suffer from unsatisfactory areal or volumetric energy density and relatively poor rate performance. These drawbacks are due to limited accessible surface area and poor ion diffusion capacity arising from the agglomeration and restacking of graphene nanosheets during electrode assembly. To solve the above issues, perforation on the graphene planes is adopted, which bestows the graphene-based nanomaterials with porous architectures. In particular, in-plane holes are capable of accelerating ion transport across the graphene sheets and ultimately accessing the inner electrode surface. Here, a comprehensive review of holey graphene-based nanomaterials is presented, which summarizes recent progress from their rational design and controlled synthesis to their applications in electrochemical energy storage. Finally, perspectives on the future directions of their large-scale synthesis and advanced assembly protocols as electrodes are proposed and discussed. |
first_indexed | 2024-12-14T00:46:48Z |
format | Article |
id | doaj.art-ee730c27b0ac484896db2e5a9026b42b |
institution | Directory Open Access Journal |
issn | 2666-3864 |
language | English |
last_indexed | 2024-12-14T00:46:48Z |
publishDate | 2020-10-01 |
publisher | Elsevier |
record_format | Article |
series | Cell Reports Physical Science |
spelling | doaj.art-ee730c27b0ac484896db2e5a9026b42b2022-12-21T23:24:05ZengElsevierCell Reports Physical Science2666-38642020-10-01110100215Holey Graphene for Electrochemical Energy StorageTao Liu0Liuyang Zhang1Bei Cheng2Xianluo Hu3Jiaguo Yu4State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Luoshi Road 122, Wuhan 430070, P.R. China; Foshan Xianhu Laboratory of the Advanced Energy Science and Technology Guangdong Laboratory, Xianhu Hydrogen Valley, Foshan 528200, P.R. ChinaState Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Luoshi Road 122, Wuhan 430070, P.R. China; Corresponding authorState Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Luoshi Road 122, Wuhan 430070, P.R. ChinaState Key Laboratory of Materials Processing and Die & Mould Technology, School of Materials Science and Engineering, Huazhong University of Science and Technology, Wuhan 430074, P.R. ChinaState Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Luoshi Road 122, Wuhan 430070, P.R. China; Foshan Xianhu Laboratory of the Advanced Energy Science and Technology Guangdong Laboratory, Xianhu Hydrogen Valley, Foshan 528200, P.R. China; Corresponding authorSummary: Graphene and its hybrids have been considered promising candidates for electrochemical energy storage because of their fascinating physicochemical properties. However, they suffer from unsatisfactory areal or volumetric energy density and relatively poor rate performance. These drawbacks are due to limited accessible surface area and poor ion diffusion capacity arising from the agglomeration and restacking of graphene nanosheets during electrode assembly. To solve the above issues, perforation on the graphene planes is adopted, which bestows the graphene-based nanomaterials with porous architectures. In particular, in-plane holes are capable of accelerating ion transport across the graphene sheets and ultimately accessing the inner electrode surface. Here, a comprehensive review of holey graphene-based nanomaterials is presented, which summarizes recent progress from their rational design and controlled synthesis to their applications in electrochemical energy storage. Finally, perspectives on the future directions of their large-scale synthesis and advanced assembly protocols as electrodes are proposed and discussed.http://www.sciencedirect.com/science/article/pii/S2666386420302307holey graphenesupercapacitorlithium-ion batterysodium-ion batterylithium-sulfur battery |
spellingShingle | Tao Liu Liuyang Zhang Bei Cheng Xianluo Hu Jiaguo Yu Holey Graphene for Electrochemical Energy Storage Cell Reports Physical Science holey graphene supercapacitor lithium-ion battery sodium-ion battery lithium-sulfur battery |
title | Holey Graphene for Electrochemical Energy Storage |
title_full | Holey Graphene for Electrochemical Energy Storage |
title_fullStr | Holey Graphene for Electrochemical Energy Storage |
title_full_unstemmed | Holey Graphene for Electrochemical Energy Storage |
title_short | Holey Graphene for Electrochemical Energy Storage |
title_sort | holey graphene for electrochemical energy storage |
topic | holey graphene supercapacitor lithium-ion battery sodium-ion battery lithium-sulfur battery |
url | http://www.sciencedirect.com/science/article/pii/S2666386420302307 |
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