7-Bromo-1-(4-chlorophenylsulfanyl)-2-phenylnaphtho[2,1-b]furan
In the title compound, C24H14BrClOS, the S-bound 4-chlorophenyl ring is nearly perpendicular to the plane of the naphthofuran fragment [dihedral angle = 83.34 (3)°] and the phenyl ring in the 2-position is rotated out of the naphthofuran plane by a dihedral angle of 15.23&...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2010-01-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536809052945 |
| _version_ | 1818283602665799680 |
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| author | Hong Dae Choi Pil Ja Seo Byung Ki Kim Byeng Wha Son Uk Lee |
| author_facet | Hong Dae Choi Pil Ja Seo Byung Ki Kim Byeng Wha Son Uk Lee |
| author_sort | Hong Dae Choi |
| collection | DOAJ |
| description | In the title compound, C24H14BrClOS, the S-bound 4-chlorophenyl ring is nearly perpendicular to the plane of the naphthofuran fragment [dihedral angle = 83.34 (3)°] and the phenyl ring in the 2-position is rotated out of the naphthofuran plane by a dihedral angle of 15.23 (5)°. The crystal structure is stabilized by aromatic π–π interactions between the furan and the central benzene rings of the neighbouring naphthofuran fragments, and between the outer benzene rings of the neighbouring naphthofuran fragments; the centroid–centroid distances within the stack are 3.879 (2) and 3.857 (2) Å. In addition, intermolecular C—Cl...π interactions [3.505 (2) Å] between the Cl atom and the 2-phenyl ring are present. |
| first_indexed | 2024-12-13T00:39:31Z |
| format | Article |
| id | doaj.art-ee7fae3acc5e47fe859870302ce75bd3 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-13T00:39:31Z |
| publishDate | 2010-01-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-ee7fae3acc5e47fe859870302ce75bd32022-12-22T00:05:09ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-01-01661o173o17310.1107/S16005368090529457-Bromo-1-(4-chlorophenylsulfanyl)-2-phenylnaphtho[2,1-b]furanHong Dae ChoiPil Ja SeoByung Ki KimByeng Wha SonUk LeeIn the title compound, C24H14BrClOS, the S-bound 4-chlorophenyl ring is nearly perpendicular to the plane of the naphthofuran fragment [dihedral angle = 83.34 (3)°] and the phenyl ring in the 2-position is rotated out of the naphthofuran plane by a dihedral angle of 15.23 (5)°. The crystal structure is stabilized by aromatic π–π interactions between the furan and the central benzene rings of the neighbouring naphthofuran fragments, and between the outer benzene rings of the neighbouring naphthofuran fragments; the centroid–centroid distances within the stack are 3.879 (2) and 3.857 (2) Å. In addition, intermolecular C—Cl...π interactions [3.505 (2) Å] between the Cl atom and the 2-phenyl ring are present.http://scripts.iucr.org/cgi-bin/paper?S1600536809052945 |
| spellingShingle | Hong Dae Choi Pil Ja Seo Byung Ki Kim Byeng Wha Son Uk Lee 7-Bromo-1-(4-chlorophenylsulfanyl)-2-phenylnaphtho[2,1-b]furan Acta Crystallographica Section E |
| title | 7-Bromo-1-(4-chlorophenylsulfanyl)-2-phenylnaphtho[2,1-b]furan |
| title_full | 7-Bromo-1-(4-chlorophenylsulfanyl)-2-phenylnaphtho[2,1-b]furan |
| title_fullStr | 7-Bromo-1-(4-chlorophenylsulfanyl)-2-phenylnaphtho[2,1-b]furan |
| title_full_unstemmed | 7-Bromo-1-(4-chlorophenylsulfanyl)-2-phenylnaphtho[2,1-b]furan |
| title_short | 7-Bromo-1-(4-chlorophenylsulfanyl)-2-phenylnaphtho[2,1-b]furan |
| title_sort | 7 bromo 1 4 chlorophenylsulfanyl 2 phenylnaphtho 2 1 b furan |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536809052945 |
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