Potassium zinc borate, KZnB3O6
The title compound, KZnB3O6 contains a remarkable [B6O12]6− group (overline{1} symmetry) formed by two rings linked by edge-sharing BO4 tetrahedra, a feature that has only been observed previously under high pressure conditions. These borate groups are connected through distorted ZnO4...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2010-05-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536810015175 |
| _version_ | 1818285264154394624 |
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| author | Yang Wu Ji-Yong Yao Jian-Xiu Zhang Pei-Zhen Fu Yi-Cheng Wu |
| author_facet | Yang Wu Ji-Yong Yao Jian-Xiu Zhang Pei-Zhen Fu Yi-Cheng Wu |
| author_sort | Yang Wu |
| collection | DOAJ |
| description | The title compound, KZnB3O6 contains a remarkable [B6O12]6− group (overline{1} symmetry) formed by two rings linked by edge-sharing BO4 tetrahedra, a feature that has only been observed previously under high pressure conditions. These borate groups are connected through distorted ZnO4 tetrahedra in edge-shared pairs (overline{1} symmetry), forming a three-dimensional network whose cavities are filled by K+ cations. |
| first_indexed | 2024-12-13T01:05:56Z |
| format | Article |
| id | doaj.art-eebf5f987054416c93de0f7212fd5114 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-13T01:05:56Z |
| publishDate | 2010-05-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-eebf5f987054416c93de0f7212fd51142022-12-22T00:04:34ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-05-01665i45i4510.1107/S1600536810015175Potassium zinc borate, KZnB3O6Yang WuJi-Yong YaoJian-Xiu ZhangPei-Zhen FuYi-Cheng WuThe title compound, KZnB3O6 contains a remarkable [B6O12]6− group (overline{1} symmetry) formed by two rings linked by edge-sharing BO4 tetrahedra, a feature that has only been observed previously under high pressure conditions. These borate groups are connected through distorted ZnO4 tetrahedra in edge-shared pairs (overline{1} symmetry), forming a three-dimensional network whose cavities are filled by K+ cations.http://scripts.iucr.org/cgi-bin/paper?S1600536810015175 |
| spellingShingle | Yang Wu Ji-Yong Yao Jian-Xiu Zhang Pei-Zhen Fu Yi-Cheng Wu Potassium zinc borate, KZnB3O6 Acta Crystallographica Section E |
| title | Potassium zinc borate, KZnB3O6 |
| title_full | Potassium zinc borate, KZnB3O6 |
| title_fullStr | Potassium zinc borate, KZnB3O6 |
| title_full_unstemmed | Potassium zinc borate, KZnB3O6 |
| title_short | Potassium zinc borate, KZnB3O6 |
| title_sort | potassium zinc borate kznb3o6 |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536810015175 |
| work_keys_str_mv | AT yangwu potassiumzincboratekznb3o6 AT jiyongyao potassiumzincboratekznb3o6 AT jianxiuzhang potassiumzincboratekznb3o6 AT peizhenfu potassiumzincboratekznb3o6 AT yichengwu potassiumzincboratekznb3o6 |