Effective Production of Sorbitol and Mannitol from Sugars Catalyzed by Ni Nanoparticles Supported on Aluminium Hydroxide
Effective production of hexitols (sorbitol and mannitol) was achieved from sugars by means of nickel nanoparticles supported on aluminium hydroxide (NiNPs/AlOH) catalyst. NiNPs/AlOH catalyst was prepared by a simple and benign environmentally procedure using less amount of sodium hydroxide. ICP-AES...
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| Format: | Article |
| Language: | English |
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Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS)
2013-06-01
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| Series: | Bulletin of Chemical Reaction Engineering & Catalysis |
| Subjects: | |
| Online Access: | https://journal.bcrec.id/index.php/bcrec/article/view/19514 |
| _version_ | 1797677788310798336 |
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| author | Rodiansono Rodiansono Shogo Shimazu |
| author_facet | Rodiansono Rodiansono Shogo Shimazu |
| author_sort | Rodiansono Rodiansono |
| collection | DOAJ |
| description | Effective production of hexitols (sorbitol and mannitol) was achieved from sugars by means of nickel nanoparticles supported on aluminium hydroxide (NiNPs/AlOH) catalyst. NiNPs/AlOH catalyst was prepared by a simple and benign environmentally procedure using less amount of sodium hydroxide. ICP-AES and XRD analyses confirmed that the NiNPs/AlOH catalysts comprised a large amount of remained aluminium hydroxide (i.e. bayerite and gibbsite). The presence of aluminium hydroxide caused a high dispersion Ni metal species. The average Ni crystallite sizes that derived from the Scherrer`s equation for former R-Ni and NiNPs/AlOH were 8.6 nm and 4.1 nm, respectively. The catalyst exhibited high activity and selectivity both hydrogenolysis of disaccharides (sucrose and cellobiose) and monosaccharides (glucose, fructose, and xylose) at 403 K for 24 h. The NiNPs/AlOH catalyst was found to be reusable for at least five consecutive runs without any significant loss of activity and selectivity. © 2013 by Authors, Published by BCREC Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0) |
| first_indexed | 2024-03-11T22:50:15Z |
| format | Article |
| id | doaj.art-eedaa7011bfa480c80c50be4f97ec436 |
| institution | Directory Open Access Journal |
| issn | 1978-2993 |
| language | English |
| last_indexed | 2024-03-11T22:50:15Z |
| publishDate | 2013-06-01 |
| publisher | Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS) |
| record_format | Article |
| series | Bulletin of Chemical Reaction Engineering & Catalysis |
| spelling | doaj.art-eedaa7011bfa480c80c50be4f97ec4362023-09-22T03:58:34ZengMasyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS)Bulletin of Chemical Reaction Engineering & Catalysis1978-29932013-06-0181404610.9767/bcrec.8.1.4290.40-468188Effective Production of Sorbitol and Mannitol from Sugars Catalyzed by Ni Nanoparticles Supported on Aluminium HydroxideRodiansono Rodiansono0Shogo Shimazu1Department of Chemistry, Lambung Mangkurat University, Jl. A. Yani Km 36.0, Banjarbaru, South Kalimantan, IndonesiaGraduate School of Engineering, Chiba University, 1-33 Yayoi, Inage, Chiba 263-8522, JapanEffective production of hexitols (sorbitol and mannitol) was achieved from sugars by means of nickel nanoparticles supported on aluminium hydroxide (NiNPs/AlOH) catalyst. NiNPs/AlOH catalyst was prepared by a simple and benign environmentally procedure using less amount of sodium hydroxide. ICP-AES and XRD analyses confirmed that the NiNPs/AlOH catalysts comprised a large amount of remained aluminium hydroxide (i.e. bayerite and gibbsite). The presence of aluminium hydroxide caused a high dispersion Ni metal species. The average Ni crystallite sizes that derived from the Scherrer`s equation for former R-Ni and NiNPs/AlOH were 8.6 nm and 4.1 nm, respectively. The catalyst exhibited high activity and selectivity both hydrogenolysis of disaccharides (sucrose and cellobiose) and monosaccharides (glucose, fructose, and xylose) at 403 K for 24 h. The NiNPs/AlOH catalyst was found to be reusable for at least five consecutive runs without any significant loss of activity and selectivity. © 2013 by Authors, Published by BCREC Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0)https://journal.bcrec.id/index.php/bcrec/article/view/19514supported-nickel nanoparticleshydrogenationsugarsorbitolmannitol |
| spellingShingle | Rodiansono Rodiansono Shogo Shimazu Effective Production of Sorbitol and Mannitol from Sugars Catalyzed by Ni Nanoparticles Supported on Aluminium Hydroxide Bulletin of Chemical Reaction Engineering & Catalysis supported-nickel nanoparticles hydrogenation sugar sorbitol mannitol |
| title | Effective Production of Sorbitol and Mannitol from Sugars Catalyzed by Ni Nanoparticles Supported on Aluminium Hydroxide |
| title_full | Effective Production of Sorbitol and Mannitol from Sugars Catalyzed by Ni Nanoparticles Supported on Aluminium Hydroxide |
| title_fullStr | Effective Production of Sorbitol and Mannitol from Sugars Catalyzed by Ni Nanoparticles Supported on Aluminium Hydroxide |
| title_full_unstemmed | Effective Production of Sorbitol and Mannitol from Sugars Catalyzed by Ni Nanoparticles Supported on Aluminium Hydroxide |
| title_short | Effective Production of Sorbitol and Mannitol from Sugars Catalyzed by Ni Nanoparticles Supported on Aluminium Hydroxide |
| title_sort | effective production of sorbitol and mannitol from sugars catalyzed by ni nanoparticles supported on aluminium hydroxide |
| topic | supported-nickel nanoparticles hydrogenation sugar sorbitol mannitol |
| url | https://journal.bcrec.id/index.php/bcrec/article/view/19514 |
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