N1-[(1H-Imidazol-2-yl)methylidene]-N4-phenylbenzene-1,4-diamine
The title compound, C16H14N4, is non-planar with dihedral angles between the planes of the imidazole and phenylenediamine rings of 30.66 (4)° and between the planes of the phenylenediamine and N-phenyl rings of 56.63 (7)°. In the crystal, molecules are connected by N—H...N hydrogen bonds, generating...
| Main Authors: | , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2014-07-01
|
| Series: | Acta Crystallographica Section E |
| Subjects: | |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536814014238 |
| _version_ | 1828750988555583488 |
|---|---|
| author | Md. Serajul Haque Faizi Ashraf Mashrai M. Shahid Musheer Ahmad |
| author_facet | Md. Serajul Haque Faizi Ashraf Mashrai M. Shahid Musheer Ahmad |
| author_sort | Md. Serajul Haque Faizi |
| collection | DOAJ |
| description | The title compound, C16H14N4, is non-planar with dihedral angles between the planes of the imidazole and phenylenediamine rings of 30.66 (4)° and between the planes of the phenylenediamine and N-phenyl rings of 56.63 (7)°. In the crystal, molecules are connected by N—H...N hydrogen bonds, generating a chain extending along the b-axis direction. The crystal structure is also stabilized by C—H...π interactions between N-phenyl and imidazole rings and slipped π–π stacking interactions between imidazole rings [centroid–centroid distance = 3.516 (4) Å] giving an overall two-dimensional layered structure lying parallel to (010). |
| first_indexed | 2024-12-10T20:46:41Z |
| format | Article |
| id | doaj.art-eee62e2b675d4f018b2439477f665d3f |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-10T20:46:41Z |
| publishDate | 2014-07-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-eee62e2b675d4f018b2439477f665d3f2022-12-22T01:34:12ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682014-07-01707o806o80610.1107/S1600536814014238gg2140N1-[(1H-Imidazol-2-yl)methylidene]-N4-phenylbenzene-1,4-diamineMd. Serajul Haque Faizi0Ashraf Mashrai1M. Shahid2Musheer Ahmad3Department of Chemistry, Indian Institute of Technology Kanpur, Kanpur, UP 208 016, IndiaDepartment of Chemistry, Aligarh Muslim University, Aligarh 202 002, IndiaDepartment of Chemistry, Aligarh Muslim University, Aligarh 202 002, IndiaDepartment of Chemistry, Indian Institute of Technology Kanpur, Kanpur, UP 208 016, IndiaThe title compound, C16H14N4, is non-planar with dihedral angles between the planes of the imidazole and phenylenediamine rings of 30.66 (4)° and between the planes of the phenylenediamine and N-phenyl rings of 56.63 (7)°. In the crystal, molecules are connected by N—H...N hydrogen bonds, generating a chain extending along the b-axis direction. The crystal structure is also stabilized by C—H...π interactions between N-phenyl and imidazole rings and slipped π–π stacking interactions between imidazole rings [centroid–centroid distance = 3.516 (4) Å] giving an overall two-dimensional layered structure lying parallel to (010).http://scripts.iucr.org/cgi-bin/paper?S1600536814014238crystal structure |
| spellingShingle | Md. Serajul Haque Faizi Ashraf Mashrai M. Shahid Musheer Ahmad N1-[(1H-Imidazol-2-yl)methylidene]-N4-phenylbenzene-1,4-diamine Acta Crystallographica Section E crystal structure |
| title | N1-[(1H-Imidazol-2-yl)methylidene]-N4-phenylbenzene-1,4-diamine |
| title_full | N1-[(1H-Imidazol-2-yl)methylidene]-N4-phenylbenzene-1,4-diamine |
| title_fullStr | N1-[(1H-Imidazol-2-yl)methylidene]-N4-phenylbenzene-1,4-diamine |
| title_full_unstemmed | N1-[(1H-Imidazol-2-yl)methylidene]-N4-phenylbenzene-1,4-diamine |
| title_short | N1-[(1H-Imidazol-2-yl)methylidene]-N4-phenylbenzene-1,4-diamine |
| title_sort | n1 1h imidazol 2 yl methylidene n4 phenylbenzene 1 4 diamine |
| topic | crystal structure |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536814014238 |
| work_keys_str_mv | AT mdserajulhaquefaizi n11himidazol2ylmethylidenen4phenylbenzene14diamine AT ashrafmashrai n11himidazol2ylmethylidenen4phenylbenzene14diamine AT mshahid n11himidazol2ylmethylidenen4phenylbenzene14diamine AT musheerahmad n11himidazol2ylmethylidenen4phenylbenzene14diamine |