Search for near room-temperature superconductivity in B-doped Q-carbon

We present 1D, 2D and 3D structures of boron-doped Q-carbon with a higher superconducting transition temperature than the current value of 55 K in 25 at% B-doped amorphous Q-carbon. The higher transition temperature is predicted for 1D and 2D crystalline structures with increasing density of states...

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Main Authors: J. Narayan, R. Sachan, A. Bhaumik
Format: Article
Language:English
Published: Taylor & Francis Group 2019-04-01
Series:Materials Research Letters
Subjects:
Online Access:http://dx.doi.org/10.1080/21663831.2019.1569566
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author J. Narayan
R. Sachan
A. Bhaumik
author_facet J. Narayan
R. Sachan
A. Bhaumik
author_sort J. Narayan
collection DOAJ
description We present 1D, 2D and 3D structures of boron-doped Q-carbon with a higher superconducting transition temperature than the current value of 55 K in 25 at% B-doped amorphous Q-carbon. The higher transition temperature is predicted for 1D and 2D crystalline structures with increasing density of states near the Fermi level through dopant trapping in substitutional sites. We have synthesized 50at% B-doped Q-carbon where diamond tetrahedra are arranged randomly and packed with over 80% efficiency to generate an amorphous structure. Detailed EELS measurements show higher density of states near the Fermi level above 90 K and preliminary transport data show signature of Tc above 100 K.
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spelling doaj.art-eee92517aee048f3ace9522b484974c62022-12-22T01:33:39ZengTaylor & Francis GroupMaterials Research Letters2166-38312019-04-017416417210.1080/21663831.2019.15695661569566Search for near room-temperature superconductivity in B-doped Q-carbonJ. Narayan0R. Sachan1A. Bhaumik2North Carolina State UniversityNorth Carolina State UniversityNorth Carolina State UniversityWe present 1D, 2D and 3D structures of boron-doped Q-carbon with a higher superconducting transition temperature than the current value of 55 K in 25 at% B-doped amorphous Q-carbon. The higher transition temperature is predicted for 1D and 2D crystalline structures with increasing density of states near the Fermi level through dopant trapping in substitutional sites. We have synthesized 50at% B-doped Q-carbon where diamond tetrahedra are arranged randomly and packed with over 80% efficiency to generate an amorphous structure. Detailed EELS measurements show higher density of states near the Fermi level above 90 K and preliminary transport data show signature of Tc above 100 K.http://dx.doi.org/10.1080/21663831.2019.1569566High-temperature superconductorsQ-carbonBCS superconductivityCryo-EELS
spellingShingle J. Narayan
R. Sachan
A. Bhaumik
Search for near room-temperature superconductivity in B-doped Q-carbon
Materials Research Letters
High-temperature superconductors
Q-carbon
BCS superconductivity
Cryo-EELS
title Search for near room-temperature superconductivity in B-doped Q-carbon
title_full Search for near room-temperature superconductivity in B-doped Q-carbon
title_fullStr Search for near room-temperature superconductivity in B-doped Q-carbon
title_full_unstemmed Search for near room-temperature superconductivity in B-doped Q-carbon
title_short Search for near room-temperature superconductivity in B-doped Q-carbon
title_sort search for near room temperature superconductivity in b doped q carbon
topic High-temperature superconductors
Q-carbon
BCS superconductivity
Cryo-EELS
url http://dx.doi.org/10.1080/21663831.2019.1569566
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AT rsachan searchfornearroomtemperaturesuperconductivityinbdopedqcarbon
AT abhaumik searchfornearroomtemperaturesuperconductivityinbdopedqcarbon