Mechanistic Modeling of the Variability of Methane Emissions from an Artificial Reservoir

The mechanistic model LAKE2.3 was tested for its capability to predict of methane (CH<sub>4</sub>) emissions from reservoirs. Estimates of CH<sub>4</sub> emissions from the Mozhaysk reservoir (Moscow region) provided by the model showed good agreement with instrumental in sit...

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Main Authors: Victor Lomov, Victor Stepanenko, Maria Grechushnikova, Irina Repina
Format: Article
Language:English
Published: MDPI AG 2023-12-01
Series:Water
Subjects:
Online Access:https://www.mdpi.com/2073-4441/16/1/76
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author Victor Lomov
Victor Stepanenko
Maria Grechushnikova
Irina Repina
author_facet Victor Lomov
Victor Stepanenko
Maria Grechushnikova
Irina Repina
author_sort Victor Lomov
collection DOAJ
description The mechanistic model LAKE2.3 was tested for its capability to predict of methane (CH<sub>4</sub>) emissions from reservoirs. Estimates of CH<sub>4</sub> emissions from the Mozhaysk reservoir (Moscow region) provided by the model showed good agreement with instrumental in situ observations for several parameters of the water ecosystem. The average CH<sub>4</sub> flux calculated by the model is 37.7 mgC-CH<sub>4</sub> m<sup>−2</sup> day<sup>−1</sup>, while according to observations, it is 34.4 mgC-CH<sub>4</sub> m<sup>−2</sup> day<sup>−1</sup>. Ebullition makes the largest contribution to the emissions from reservoirs (up to 95%) due to low methane solubility in water and the high oxidation rate of diffusive methane flux. During the heating period, an increase in methane emission is observed both in the model and empirical data, with a maximum before the onset of the autumn overturn. An effective parameter for calibrating the diffusive methane flux in the model is the potential rate of methane oxidation. For ebullition flux, it is the parameter q10 (an empirical parameter determining the relationship between methane generation and temperature) because methane production in bottom sediments is the most important. The results of this research can be used to develop mechanistic models and provide a necessary step toward regional and global simulations of lacustrine methane emission using LAKE2.3.
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spelling doaj.art-eeeadb4a20ac4e5e8c2ce43ae16f03a12024-01-10T15:11:34ZengMDPI AGWater2073-44412023-12-011617610.3390/w16010076Mechanistic Modeling of the Variability of Methane Emissions from an Artificial ReservoirVictor Lomov0Victor Stepanenko1Maria Grechushnikova2Irina Repina3Laboratory of Supercomputer Modeling of the Earth System Processes, Research Computing Center, Moscow State University, 119991 Moscow, RussiaLaboratory of Supercomputer Modeling of the Earth System Processes, Research Computing Center, Moscow State University, 119991 Moscow, RussiaHydrology Department, Faculty of Geography, Moscow State University, 119991 Moscow, RussiaLaboratory of Supercomputer Modeling of the Earth System Processes, Research Computing Center, Moscow State University, 119991 Moscow, RussiaThe mechanistic model LAKE2.3 was tested for its capability to predict of methane (CH<sub>4</sub>) emissions from reservoirs. Estimates of CH<sub>4</sub> emissions from the Mozhaysk reservoir (Moscow region) provided by the model showed good agreement with instrumental in situ observations for several parameters of the water ecosystem. The average CH<sub>4</sub> flux calculated by the model is 37.7 mgC-CH<sub>4</sub> m<sup>−2</sup> day<sup>−1</sup>, while according to observations, it is 34.4 mgC-CH<sub>4</sub> m<sup>−2</sup> day<sup>−1</sup>. Ebullition makes the largest contribution to the emissions from reservoirs (up to 95%) due to low methane solubility in water and the high oxidation rate of diffusive methane flux. During the heating period, an increase in methane emission is observed both in the model and empirical data, with a maximum before the onset of the autumn overturn. An effective parameter for calibrating the diffusive methane flux in the model is the potential rate of methane oxidation. For ebullition flux, it is the parameter q10 (an empirical parameter determining the relationship between methane generation and temperature) because methane production in bottom sediments is the most important. The results of this research can be used to develop mechanistic models and provide a necessary step toward regional and global simulations of lacustrine methane emission using LAKE2.3.https://www.mdpi.com/2073-4441/16/1/76artificial reservoirmethane emissionthermodynamical modelingwater ecosystem
spellingShingle Victor Lomov
Victor Stepanenko
Maria Grechushnikova
Irina Repina
Mechanistic Modeling of the Variability of Methane Emissions from an Artificial Reservoir
Water
artificial reservoir
methane emission
thermodynamical modeling
water ecosystem
title Mechanistic Modeling of the Variability of Methane Emissions from an Artificial Reservoir
title_full Mechanistic Modeling of the Variability of Methane Emissions from an Artificial Reservoir
title_fullStr Mechanistic Modeling of the Variability of Methane Emissions from an Artificial Reservoir
title_full_unstemmed Mechanistic Modeling of the Variability of Methane Emissions from an Artificial Reservoir
title_short Mechanistic Modeling of the Variability of Methane Emissions from an Artificial Reservoir
title_sort mechanistic modeling of the variability of methane emissions from an artificial reservoir
topic artificial reservoir
methane emission
thermodynamical modeling
water ecosystem
url https://www.mdpi.com/2073-4441/16/1/76
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AT victorstepanenko mechanisticmodelingofthevariabilityofmethaneemissionsfromanartificialreservoir
AT mariagrechushnikova mechanisticmodelingofthevariabilityofmethaneemissionsfromanartificialreservoir
AT irinarepina mechanisticmodelingofthevariabilityofmethaneemissionsfromanartificialreservoir