Synthesis and X-ray Structural Studies of a Substituted 2,3,4,5-Tetrahydro-1H-3-benzazonine and a 1,2,3,5-Tetrahydro-4,3-benzoxazonine

Synthesis and X-ray Structural Studies of a Substituted 2,3,4,5-Tetrahydro-1H-3-benzazonine and a 1,2,3,5-Tetrahydro-4,3-benzoxazonine

Using a common 1-(1-phenylethenyl)-1,2,3,4-tetrahydroisoquinoline precursor to the required ylide or N-oxide intermediate, the Stevens [2,3] and analogous Meisenheimer [2,3] sigmatropic rearrangements have been applied to afford concise syntheses of phenyl -substituted representatives of each of the...

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Bibliographic Details
Main Authors: Timothy S. Bailey, John B. Bremner, Brian W. Skelton, Allan H. White
Format: Article
Language:English
Published: MDPI AG 2014-12-01
Series:Molecules
Subjects:
large rings
X-ray crystal structures
benzazonine
benzoxazonine
Online Access:http://www.mdpi.com/1420-3049/20/1/487

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