Bis(isopropyltriphenylphosphonium) di-μ-iodido-bis[iodidocopper(I)]

The title compound, (C21H22P)2[Cu2I4], prepared from reaction between copper powder, iodine and isopropyl triphenylphosphonium iodide in hydroxyacetone (acetol), shows an already known Cu2I42− anion with a planar conformation [Cu—I range = 2.5108 (3)&amp...

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Main Authors: Ehsan Jalilian, Sven Lidin
Format: Article
Language:English
Published: International Union of Crystallography 2010-04-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536810010196
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author Ehsan Jalilian
Sven Lidin
author_facet Ehsan Jalilian
Sven Lidin
author_sort Ehsan Jalilian
collection DOAJ
description The title compound, (C21H22P)2[Cu2I4], prepared from reaction between copper powder, iodine and isopropyl triphenylphosphonium iodide in hydroxyacetone (acetol), shows an already known Cu2I42− anion with a planar conformation [Cu—I range = 2.5108 (3)–2.5844 (3) Å and I—Cu—I range = 110.821 (10)–125.401 (10)°].
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spelling doaj.art-ef0de2ad37464cf88fcb8f29d7b00a642022-12-22T00:04:13ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-04-01664m432m43310.1107/S1600536810010196Bis(isopropyltriphenylphosphonium) di-μ-iodido-bis[iodidocopper(I)]Ehsan JalilianSven LidinThe title compound, (C21H22P)2[Cu2I4], prepared from reaction between copper powder, iodine and isopropyl triphenylphosphonium iodide in hydroxyacetone (acetol), shows an already known Cu2I42− anion with a planar conformation [Cu—I range = 2.5108 (3)–2.5844 (3) Å and I—Cu—I range = 110.821 (10)–125.401 (10)°].http://scripts.iucr.org/cgi-bin/paper?S1600536810010196
spellingShingle Ehsan Jalilian
Sven Lidin
Bis(isopropyltriphenylphosphonium) di-μ-iodido-bis[iodidocopper(I)]
Acta Crystallographica Section E
title Bis(isopropyltriphenylphosphonium) di-μ-iodido-bis[iodidocopper(I)]
title_full Bis(isopropyltriphenylphosphonium) di-μ-iodido-bis[iodidocopper(I)]
title_fullStr Bis(isopropyltriphenylphosphonium) di-μ-iodido-bis[iodidocopper(I)]
title_full_unstemmed Bis(isopropyltriphenylphosphonium) di-μ-iodido-bis[iodidocopper(I)]
title_short Bis(isopropyltriphenylphosphonium) di-μ-iodido-bis[iodidocopper(I)]
title_sort bis isopropyltriphenylphosphonium di amp 956 iodido bis iodidocopper i
url http://scripts.iucr.org/cgi-bin/paper?S1600536810010196
work_keys_str_mv AT ehsanjalilian bisisopropyltriphenylphosphoniumdiamp956iodidobisiodidocopperi
AT svenlidin bisisopropyltriphenylphosphoniumdiamp956iodidobisiodidocopperi