Synthesis and structure of [2-((L)-menthoxycarbonyl)ethyl]diphenyltin halides
Two [2-((L)-menthoxycarbonyl)ethyl]diphenyltin halides, (L)-MenOCOCH2CH2SnXPh2 (X=Cl, 1; I, 2), have been synthesized and characterized by means of elemental analysis, FT-IR, NMR (1H, 13C, and 119Sn) spectroscopy, and X-ray single crystal diffraction. The tin atoms in 1 and 2 are both five-coordinat...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
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De Gruyter
2015-08-01
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| Series: | Main Group Metal Chemistry |
| Subjects: | |
| Online Access: | https://doi.org/10.1515/mgmc-2015-0020 |
| _version_ | 1818676734349803520 |
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| author | Liu Qingtao Shi Xiaowen Zhang Changfa Tian Laijin |
| author_facet | Liu Qingtao Shi Xiaowen Zhang Changfa Tian Laijin |
| author_sort | Liu Qingtao |
| collection | DOAJ |
| description | Two [2-((L)-menthoxycarbonyl)ethyl]diphenyltin halides, (L)-MenOCOCH2CH2SnXPh2 (X=Cl, 1; I, 2), have been synthesized and characterized by means of elemental analysis, FT-IR, NMR (1H, 13C, and 119Sn) spectroscopy, and X-ray single crystal diffraction. The tin atoms in 1 and 2 are both five-coordinated and possess the [C3SnOX] (X=Cl and I) trigonal bipyramidal environment with the trigonal plane defined by the three carbon atoms and the axial positions occupied by the halogen atom and internal carbonyl oxygen. There is a five-membered chelate ring in 1 and 2 with the Sn-O distance being 2.4781(16) and 2.512(2) Å, respectively. |
| first_indexed | 2024-12-17T08:48:11Z |
| format | Article |
| id | doaj.art-ef2ff531527b42ec8ce0f3eda82f4741 |
| institution | Directory Open Access Journal |
| issn | 0792-1241 2191-0219 |
| language | English |
| last_indexed | 2024-12-17T08:48:11Z |
| publishDate | 2015-08-01 |
| publisher | De Gruyter |
| record_format | Article |
| series | Main Group Metal Chemistry |
| spelling | doaj.art-ef2ff531527b42ec8ce0f3eda82f47412022-12-21T21:56:09ZengDe GruyterMain Group Metal Chemistry0792-12412191-02192015-08-01383-4939710.1515/mgmc-2015-0020Synthesis and structure of [2-((L)-menthoxycarbonyl)ethyl]diphenyltin halidesLiu Qingtao0Shi Xiaowen1Zhang Changfa2Tian Laijin3Key Laboratory of Natural Products and Pharmaceutical Intermediates, Qufu Normal University, Qufu 273165, ChinaKey Laboratory of Natural Products and Pharmaceutical Intermediates, Qufu Normal University, Qufu 273165, ChinaDepartment of Resources and Environmental, Shandong Water Polytechnic, Rizhao 276826, ChinaKey Laboratory of Natural Products and Pharmaceutical Intermediates, Qufu Normal University, Qufu 273165, ChinaTwo [2-((L)-menthoxycarbonyl)ethyl]diphenyltin halides, (L)-MenOCOCH2CH2SnXPh2 (X=Cl, 1; I, 2), have been synthesized and characterized by means of elemental analysis, FT-IR, NMR (1H, 13C, and 119Sn) spectroscopy, and X-ray single crystal diffraction. The tin atoms in 1 and 2 are both five-coordinated and possess the [C3SnOX] (X=Cl and I) trigonal bipyramidal environment with the trigonal plane defined by the three carbon atoms and the axial positions occupied by the halogen atom and internal carbonyl oxygen. There is a five-membered chelate ring in 1 and 2 with the Sn-O distance being 2.4781(16) and 2.512(2) Å, respectively.https://doi.org/10.1515/mgmc-2015-0020intramolecular coordination2-((l)-menthoxycarbonyl)ethyltinorganotinx-ray crystal structure |
| spellingShingle | Liu Qingtao Shi Xiaowen Zhang Changfa Tian Laijin Synthesis and structure of [2-((L)-menthoxycarbonyl)ethyl]diphenyltin halides Main Group Metal Chemistry intramolecular coordination 2-((l)-menthoxycarbonyl)ethyltin organotin x-ray crystal structure |
| title | Synthesis and structure of [2-((L)-menthoxycarbonyl)ethyl]diphenyltin halides |
| title_full | Synthesis and structure of [2-((L)-menthoxycarbonyl)ethyl]diphenyltin halides |
| title_fullStr | Synthesis and structure of [2-((L)-menthoxycarbonyl)ethyl]diphenyltin halides |
| title_full_unstemmed | Synthesis and structure of [2-((L)-menthoxycarbonyl)ethyl]diphenyltin halides |
| title_short | Synthesis and structure of [2-((L)-menthoxycarbonyl)ethyl]diphenyltin halides |
| title_sort | synthesis and structure of 2 l menthoxycarbonyl ethyl diphenyltin halides |
| topic | intramolecular coordination 2-((l)-menthoxycarbonyl)ethyltin organotin x-ray crystal structure |
| url | https://doi.org/10.1515/mgmc-2015-0020 |
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