Deep desulphurization of gas oil and model compounds by anatase nanocomposite sandwich type polyoxometalate as a novel, reusable and green nano mercaptan scavenger
Oxidative desulphurization of gas oil and model compounds that exist in gas oil with hydrogen peroxide/acetic acid using nanoparticle (Bu4N)7H3[P2W18Cd4(Br)2O68]-TiO2 ((Bu4N)7H3[P2W18Cd4]-TiO2) as a nano scavenger has been studied. This sandwich-type nanoparticle was shown be able to scavenge hy...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
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Serbian Chemical Society
2013-01-01
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| Series: | Journal of the Serbian Chemical Society |
| Subjects: | |
| Online Access: | http://www.doiserbia.nb.rs/img/doi/0352-5139/2013/0352-51391200034S.pdf |
| _version_ | 1818156793464881152 |
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| author | Shojaei Fallah Abdollah Rezvani Ali Mohamad Zonoz Farokhzad Mohamadi |
| author_facet | Shojaei Fallah Abdollah Rezvani Ali Mohamad Zonoz Farokhzad Mohamadi |
| author_sort | Shojaei Fallah Abdollah |
| collection | DOAJ |
| description | Oxidative desulphurization of gas oil and model compounds that exist in gas oil with hydrogen peroxide/acetic acid using nanoparticle (Bu4N)7H3[P2W18Cd4(Br)2O68]-TiO2 ((Bu4N)7H3[P2W18Cd4]-TiO2) as a nano scavenger has been studied. This sandwich-type nanoparticle was shown be able to scavenge hydrogen sulfide and mercaptans with high yield. The addition of acetic acid enhanced the conversion. This system provides an efficient, convenient and practical method for scavenging of sulphur compound. The (Bu4N)7H3[P2W18Cd4]-TiO2 nanoparticle was very active catalyst system for the model compound oxidation, while other polyoxometalate systems were much less active. |
| first_indexed | 2024-12-11T15:03:57Z |
| format | Article |
| id | doaj.art-ef510689e06e4eb096078cace1d1c2a8 |
| institution | Directory Open Access Journal |
| issn | 0352-5139 |
| language | English |
| last_indexed | 2024-12-11T15:03:57Z |
| publishDate | 2013-01-01 |
| publisher | Serbian Chemical Society |
| record_format | Article |
| series | Journal of the Serbian Chemical Society |
| spelling | doaj.art-ef510689e06e4eb096078cace1d1c2a82022-12-22T01:01:02ZengSerbian Chemical SocietyJournal of the Serbian Chemical Society0352-51392013-01-0178112913610.2298/JSC120112034SDeep desulphurization of gas oil and model compounds by anatase nanocomposite sandwich type polyoxometalate as a novel, reusable and green nano mercaptan scavengerShojaei Fallah AbdollahRezvani Ali MohamadZonoz Farokhzad MohamadiOxidative desulphurization of gas oil and model compounds that exist in gas oil with hydrogen peroxide/acetic acid using nanoparticle (Bu4N)7H3[P2W18Cd4(Br)2O68]-TiO2 ((Bu4N)7H3[P2W18Cd4]-TiO2) as a nano scavenger has been studied. This sandwich-type nanoparticle was shown be able to scavenge hydrogen sulfide and mercaptans with high yield. The addition of acetic acid enhanced the conversion. This system provides an efficient, convenient and practical method for scavenging of sulphur compound. The (Bu4N)7H3[P2W18Cd4]-TiO2 nanoparticle was very active catalyst system for the model compound oxidation, while other polyoxometalate systems were much less active.http://www.doiserbia.nb.rs/img/doi/0352-5139/2013/0352-51391200034S.pdfpolyoxometalesdesulphurizationanatasescavengermercaptans |
| spellingShingle | Shojaei Fallah Abdollah Rezvani Ali Mohamad Zonoz Farokhzad Mohamadi Deep desulphurization of gas oil and model compounds by anatase nanocomposite sandwich type polyoxometalate as a novel, reusable and green nano mercaptan scavenger Journal of the Serbian Chemical Society polyoxometales desulphurization anatase scavenger mercaptans |
| title | Deep desulphurization of gas oil and model compounds by anatase nanocomposite sandwich type polyoxometalate as a novel, reusable and green nano mercaptan scavenger |
| title_full | Deep desulphurization of gas oil and model compounds by anatase nanocomposite sandwich type polyoxometalate as a novel, reusable and green nano mercaptan scavenger |
| title_fullStr | Deep desulphurization of gas oil and model compounds by anatase nanocomposite sandwich type polyoxometalate as a novel, reusable and green nano mercaptan scavenger |
| title_full_unstemmed | Deep desulphurization of gas oil and model compounds by anatase nanocomposite sandwich type polyoxometalate as a novel, reusable and green nano mercaptan scavenger |
| title_short | Deep desulphurization of gas oil and model compounds by anatase nanocomposite sandwich type polyoxometalate as a novel, reusable and green nano mercaptan scavenger |
| title_sort | deep desulphurization of gas oil and model compounds by anatase nanocomposite sandwich type polyoxometalate as a novel reusable and green nano mercaptan scavenger |
| topic | polyoxometales desulphurization anatase scavenger mercaptans |
| url | http://www.doiserbia.nb.rs/img/doi/0352-5139/2013/0352-51391200034S.pdf |
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