A solar-heated Janus sponge with excellent floating stability for efficient cleanup of heavy oil

The inefficient cleanup of viscous heavy oil is thought as a worldwide problem because of its poorer fluidity at room temperature. Herein, we make full use of the photothermal performance to harvest solar energy and convert heat into heavy oil, thus reducing significantly oil viscosity and realizing...

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Main Authors: Jin Yang, Peng Xu, Yilin Yao, Yong Li, Bing Shi, Xiaohua Jia, Haojie Song
Format: Article
Language:English
Published: Elsevier 2020-10-01
Series:Materials & Design
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S026412752030513X
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author Jin Yang
Peng Xu
Yilin Yao
Yong Li
Bing Shi
Xiaohua Jia
Haojie Song
author_facet Jin Yang
Peng Xu
Yilin Yao
Yong Li
Bing Shi
Xiaohua Jia
Haojie Song
author_sort Jin Yang
collection DOAJ
description The inefficient cleanup of viscous heavy oil is thought as a worldwide problem because of its poorer fluidity at room temperature. Herein, we make full use of the photothermal performance to harvest solar energy and convert heat into heavy oil, thus reducing significantly oil viscosity and realizing rapid oil remediation. Specially, the polydopamine as photothermal components, titanium dioxide and perfluorodecyltrichlorosilane as superhydrophobic/superoleophilic source are introduced into the melamine-formaldehyde sponge by deposition method. To be applicable in the marine environments with winds and waves, the bottom side of this sponge subjected to UV irradiation is transferrable from superhydrophobicity to superhydrophilicity. The Janus sponge can keep the balance of movement and never overturned under the action of wind force, thereby enabling this sponge to absorb consecutively spilled heavy oil from marine system. With one simulated solar irradiation, the top and bottom of Janus sponge are heated to a suitable temperature of 90.7 and 70.2 °C, respectively. Relied on these advantages, the Janus sponge can effectively reduce the viscosity of spilled heavy oil and enhance its fluidity, which allow for quick heavy oil absorption up to nearly 12 times of own weight. Meanwhile, it can be also compressed for recycled uses.
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spelling doaj.art-ef8d7435164b48daaff038c50271554f2022-12-21T19:52:25ZengElsevierMaterials & Design0264-12752020-10-01195108979A solar-heated Janus sponge with excellent floating stability for efficient cleanup of heavy oilJin Yang0Peng Xu1Yilin Yao2Yong Li3Bing Shi4Xiaohua Jia5Haojie Song6School of Materials Science & Engineering, Shaanxi Key Laboratory of Green Preparation and Functionalization for Inorganic Materials, Shaanxi University of Science & Technology, Xi’ an, Shaanxi, 710021, PR China; Corresponding authors.Institute for Advanced Materials, School of Materials Science and Engineering, Jiangsu University, Zhenjiang, 212013, PR ChinaSchool of Materials Science & Engineering, Shaanxi Key Laboratory of Green Preparation and Functionalization for Inorganic Materials, Shaanxi University of Science & Technology, Xi’ an, Shaanxi, 710021, PR ChinaSchool of Materials Science & Engineering, Shaanxi Key Laboratory of Green Preparation and Functionalization for Inorganic Materials, Shaanxi University of Science & Technology, Xi’ an, Shaanxi, 710021, PR ChinaInstitute for Advanced Materials, School of Materials Science and Engineering, Jiangsu University, Zhenjiang, 212013, PR ChinaSchool of Materials Science & Engineering, Shaanxi Key Laboratory of Green Preparation and Functionalization for Inorganic Materials, Shaanxi University of Science & Technology, Xi’ an, Shaanxi, 710021, PR ChinaSchool of Materials Science & Engineering, Shaanxi Key Laboratory of Green Preparation and Functionalization for Inorganic Materials, Shaanxi University of Science & Technology, Xi’ an, Shaanxi, 710021, PR China; Corresponding authors.The inefficient cleanup of viscous heavy oil is thought as a worldwide problem because of its poorer fluidity at room temperature. Herein, we make full use of the photothermal performance to harvest solar energy and convert heat into heavy oil, thus reducing significantly oil viscosity and realizing rapid oil remediation. Specially, the polydopamine as photothermal components, titanium dioxide and perfluorodecyltrichlorosilane as superhydrophobic/superoleophilic source are introduced into the melamine-formaldehyde sponge by deposition method. To be applicable in the marine environments with winds and waves, the bottom side of this sponge subjected to UV irradiation is transferrable from superhydrophobicity to superhydrophilicity. The Janus sponge can keep the balance of movement and never overturned under the action of wind force, thereby enabling this sponge to absorb consecutively spilled heavy oil from marine system. With one simulated solar irradiation, the top and bottom of Janus sponge are heated to a suitable temperature of 90.7 and 70.2 °C, respectively. Relied on these advantages, the Janus sponge can effectively reduce the viscosity of spilled heavy oil and enhance its fluidity, which allow for quick heavy oil absorption up to nearly 12 times of own weight. Meanwhile, it can be also compressed for recycled uses.http://www.sciencedirect.com/science/article/pii/S026412752030513XPhotothermalOil remediationSuperhydrophobicityJanus spongeWinds and waves
spellingShingle Jin Yang
Peng Xu
Yilin Yao
Yong Li
Bing Shi
Xiaohua Jia
Haojie Song
A solar-heated Janus sponge with excellent floating stability for efficient cleanup of heavy oil
Materials & Design
Photothermal
Oil remediation
Superhydrophobicity
Janus sponge
Winds and waves
title A solar-heated Janus sponge with excellent floating stability for efficient cleanup of heavy oil
title_full A solar-heated Janus sponge with excellent floating stability for efficient cleanup of heavy oil
title_fullStr A solar-heated Janus sponge with excellent floating stability for efficient cleanup of heavy oil
title_full_unstemmed A solar-heated Janus sponge with excellent floating stability for efficient cleanup of heavy oil
title_short A solar-heated Janus sponge with excellent floating stability for efficient cleanup of heavy oil
title_sort solar heated janus sponge with excellent floating stability for efficient cleanup of heavy oil
topic Photothermal
Oil remediation
Superhydrophobicity
Janus sponge
Winds and waves
url http://www.sciencedirect.com/science/article/pii/S026412752030513X
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