catena-Poly[[[[bis(pyridin-2-yl-κN)amine]zinc(II)]-μ2-(2E,4E)-hexa-2,4-dienedioato-κ4O1,O1′:O6,O6′] monohydrate]
In the title compound, {[Zn(C6H4O4)(C10H9N3)]·H2O}n, the di(pyridin-2-yl)amine (dpa) ligands chelate the ZnII ions, forming [Zn(dpa)]2+ units which are connected by two independent bridging muconate [(2E,4E)-hexa-2,4-dienedioate] ligands to form chains. A crystallographic inversion centre is located...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2016-04-01
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| Series: | IUCrData |
| Subjects: | |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S2414314616006362 |
| _version_ | 1819260082935824384 |
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| author | Do Nam Lee Youngmee Kim |
| author_facet | Do Nam Lee Youngmee Kim |
| author_sort | Do Nam Lee |
| collection | DOAJ |
| description | In the title compound, {[Zn(C6H4O4)(C10H9N3)]·H2O}n, the di(pyridin-2-yl)amine (dpa) ligands chelate the ZnII ions, forming [Zn(dpa)]2+ units which are connected by two independent bridging muconate [(2E,4E)-hexa-2,4-dienedioate] ligands to form chains. A crystallographic inversion centre is located at the mid-point of the central C—C bond of each muconate ligand. The carboxylate groups of the muconate ligands bridge the ZnII ions in asymmetric chelating modes. The ZnII ion is coordinated by four O atoms of two chelating carboxylate groups and two pyridyl N atoms in a distorted octahedral coordination environment. In the crystal, N—H...O and O—H...O hydrogen bonds connect chains and solvent water molecules, forming a two-dimensional network parallel to (101). |
| first_indexed | 2024-12-23T19:20:15Z |
| format | Article |
| id | doaj.art-efa8a6f9fce3496da14575c57a1ee65c |
| institution | Directory Open Access Journal |
| issn | 2414-3146 |
| language | English |
| last_indexed | 2024-12-23T19:20:15Z |
| publishDate | 2016-04-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | IUCrData |
| spelling | doaj.art-efa8a6f9fce3496da14575c57a1ee65c2022-12-21T17:34:11ZengInternational Union of CrystallographyIUCrData2414-31462016-04-0114x16063610.1107/S2414314616006362lh4006catena-Poly[[[[bis(pyridin-2-yl-κN)amine]zinc(II)]-μ2-(2E,4E)-hexa-2,4-dienedioato-κ4O1,O1′:O6,O6′] monohydrate]Do Nam Lee0Youngmee Kim1Division of General Education (Chemistry), Kwangwoon University, Seoul 01897, Republic of KoreaDepartment of Chemistry and Nano Science, Ewha Womans University, Seoul 03760, Republic of KoreaIn the title compound, {[Zn(C6H4O4)(C10H9N3)]·H2O}n, the di(pyridin-2-yl)amine (dpa) ligands chelate the ZnII ions, forming [Zn(dpa)]2+ units which are connected by two independent bridging muconate [(2E,4E)-hexa-2,4-dienedioate] ligands to form chains. A crystallographic inversion centre is located at the mid-point of the central C—C bond of each muconate ligand. The carboxylate groups of the muconate ligands bridge the ZnII ions in asymmetric chelating modes. The ZnII ion is coordinated by four O atoms of two chelating carboxylate groups and two pyridyl N atoms in a distorted octahedral coordination environment. In the crystal, N—H...O and O—H...O hydrogen bonds connect chains and solvent water molecules, forming a two-dimensional network parallel to (101).http://scripts.iucr.org/cgi-bin/paper?S2414314616006362crystal structureZn–MOFmuconatedi(pyridin-2-yl)aminehydrogen bonds |
| spellingShingle | Do Nam Lee Youngmee Kim catena-Poly[[[[bis(pyridin-2-yl-κN)amine]zinc(II)]-μ2-(2E,4E)-hexa-2,4-dienedioato-κ4O1,O1′:O6,O6′] monohydrate] IUCrData crystal structure Zn–MOF muconate di(pyridin-2-yl)amine hydrogen bonds |
| title | catena-Poly[[[[bis(pyridin-2-yl-κN)amine]zinc(II)]-μ2-(2E,4E)-hexa-2,4-dienedioato-κ4O1,O1′:O6,O6′] monohydrate] |
| title_full | catena-Poly[[[[bis(pyridin-2-yl-κN)amine]zinc(II)]-μ2-(2E,4E)-hexa-2,4-dienedioato-κ4O1,O1′:O6,O6′] monohydrate] |
| title_fullStr | catena-Poly[[[[bis(pyridin-2-yl-κN)amine]zinc(II)]-μ2-(2E,4E)-hexa-2,4-dienedioato-κ4O1,O1′:O6,O6′] monohydrate] |
| title_full_unstemmed | catena-Poly[[[[bis(pyridin-2-yl-κN)amine]zinc(II)]-μ2-(2E,4E)-hexa-2,4-dienedioato-κ4O1,O1′:O6,O6′] monohydrate] |
| title_short | catena-Poly[[[[bis(pyridin-2-yl-κN)amine]zinc(II)]-μ2-(2E,4E)-hexa-2,4-dienedioato-κ4O1,O1′:O6,O6′] monohydrate] |
| title_sort | catena poly bis pyridin 2 yl κn amine zinc ii μ2 2e 4e hexa 2 4 dienedioato κ4o1 o1 o6 o6 monohydrate |
| topic | crystal structure Zn–MOF muconate di(pyridin-2-yl)amine hydrogen bonds |
| url | http://scripts.iucr.org/cgi-bin/paper?S2414314616006362 |
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