Performance evaluation of portable dual-spot micro-aethalometers for source identification of black carbon aerosols: application to wildfire smoke and traffic emissions in the Pacific Northwest
<p>Black carbon (BC) is a component of particulate matter, emitted from the incomplete combustion of carbonaceous fuels. The presence of BC in the atmosphere can disrupt the atmospheric radiation budget, and exposure to BC can adversely affect human health. Multi-wavelength light-absorption-ba...
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| Format: | Article |
| Language: | English |
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Copernicus Publications
2023-05-01
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| Series: | Atmospheric Measurement Techniques |
| Online Access: | https://amt.copernicus.org/articles/16/2333/2023/amt-16-2333-2023.pdf |
| _version_ | 1797833010553290752 |
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| author | M. Chakraborty A. Giang A. Giang N. Zimmerman |
| author_facet | M. Chakraborty A. Giang A. Giang N. Zimmerman |
| author_sort | M. Chakraborty |
| collection | DOAJ |
| description | <p>Black carbon (BC) is a component of particulate matter, emitted from the incomplete combustion of carbonaceous fuels. The presence of BC in the atmosphere can disrupt the atmospheric radiation budget, and exposure to BC can adversely affect human health. Multi-wavelength light-absorption-based dual-spot aethalometers can be used to quantify the source and characteristics of BC from traffic or biomass-burning-based sources. However, aethalometer measurements are affected by artifacts such as aerosol loading and light scattering; hence, they often need correction to reduce measurement uncertainty. This work assesses the performance of the recently developed portable aethalometer (MA300, AethLabs). Due to their portability and ease of usage, MA300s can be suitable for mobile and personal exposure monitoring. Here, we evaluate BC concentration and source apportionment accuracy of three MA300 units relative to a widely used aethalometer, the AE33 (Magee Scientific). Synchronous field measurements were performed at a major traffic intersection during regular and wildfire-smoke-affected days in Vancouver, Canada. We find that MA300-reported BC mass concentrations were strongly correlated (Slope range between 0.73 and 1.01, with <span class="inline-formula"><i>R</i><sup>2</sup></span> <span class="inline-formula">=</span> 0.9) compared to the reference instrument, yet there is visible instrumental variability in the normalized concentrations (5 %) across three units. The mean absolute error of MA300-reported BC concentrations ranged between 0.44–0.98 <span class="inline-formula">µ</span>g m<span class="inline-formula"><sup>−3</sup></span>, with the highest deviations observed in wildfire-smoke-affected polluted days. From the aerosol light absorption measurement perspective, MA300s tend to underestimate the absorption coefficients (<span class="inline-formula"><i>b</i><sub>abs</sub></span>) across the five wavelengths. UV channel light absorption results were subjected to the highest amount of noise and were found to be consistently underestimating in all the MA300 units, leading to systematic bias in source apportionment analysis. Absorption Ångström exponent values from the MA300 units were able to capture the variability of aerosol sources within a day, with a mean value of 1.15 during clean days and 1.46 during wildfire-smoke-affected days. We investigated the application of the latest non-linear aethalometer correction protocols in the MA300 and found that flow fluctuations enhanced noise across all channels, compared to onboard instrument correction. We also identify that the UV (<span class="inline-formula"><i>λ</i></span> <span class="inline-formula">=</span> 370 nm) channel absorption measurements are most sensitive to instrumental artifacts during the wildfire-smoke-affected period. Hence, as an alternative to traditional UV and IR (<span class="inline-formula"><i>λ</i></span> <span class="inline-formula">=</span> 880 nm)-based BC source apportionment methods, in this work, we tested the blue (<span class="inline-formula"><i>λ</i></span> <span class="inline-formula">=</span> 470 nm) and IR wavelengths for BC source apportionment calculation. When the blue–IR-based source apportionment technique is adopted instead of the UV–IR, there is a 10 % (on average) decrease in the percentage difference of the apportioned components from the reference monitor.</p> |
| first_indexed | 2024-04-09T14:17:59Z |
| format | Article |
| id | doaj.art-efd7d118ce48436dab84de4f71e6115a |
| institution | Directory Open Access Journal |
| issn | 1867-1381 1867-8548 |
| language | English |
| last_indexed | 2024-04-09T14:17:59Z |
| publishDate | 2023-05-01 |
| publisher | Copernicus Publications |
| record_format | Article |
| series | Atmospheric Measurement Techniques |
| spelling | doaj.art-efd7d118ce48436dab84de4f71e6115a2023-05-05T06:11:10ZengCopernicus PublicationsAtmospheric Measurement Techniques1867-13811867-85482023-05-01162333235210.5194/amt-16-2333-2023Performance evaluation of portable dual-spot micro-aethalometers for source identification of black carbon aerosols: application to wildfire smoke and traffic emissions in the Pacific NorthwestM. Chakraborty0A. Giang1A. Giang2N. Zimmerman3Department of Mechanical Engineering, University of British Columbia, Vancouver, V6T 1Z4, CanadaDepartment of Mechanical Engineering, University of British Columbia, Vancouver, V6T 1Z4, CanadaInstitute for Resources, Environment and Sustainability, University of British Columbia, Vancouver, V6T 1Z4, CanadaDepartment of Mechanical Engineering, University of British Columbia, Vancouver, V6T 1Z4, Canada<p>Black carbon (BC) is a component of particulate matter, emitted from the incomplete combustion of carbonaceous fuels. The presence of BC in the atmosphere can disrupt the atmospheric radiation budget, and exposure to BC can adversely affect human health. Multi-wavelength light-absorption-based dual-spot aethalometers can be used to quantify the source and characteristics of BC from traffic or biomass-burning-based sources. However, aethalometer measurements are affected by artifacts such as aerosol loading and light scattering; hence, they often need correction to reduce measurement uncertainty. This work assesses the performance of the recently developed portable aethalometer (MA300, AethLabs). Due to their portability and ease of usage, MA300s can be suitable for mobile and personal exposure monitoring. Here, we evaluate BC concentration and source apportionment accuracy of three MA300 units relative to a widely used aethalometer, the AE33 (Magee Scientific). Synchronous field measurements were performed at a major traffic intersection during regular and wildfire-smoke-affected days in Vancouver, Canada. We find that MA300-reported BC mass concentrations were strongly correlated (Slope range between 0.73 and 1.01, with <span class="inline-formula"><i>R</i><sup>2</sup></span> <span class="inline-formula">=</span> 0.9) compared to the reference instrument, yet there is visible instrumental variability in the normalized concentrations (5 %) across three units. The mean absolute error of MA300-reported BC concentrations ranged between 0.44–0.98 <span class="inline-formula">µ</span>g m<span class="inline-formula"><sup>−3</sup></span>, with the highest deviations observed in wildfire-smoke-affected polluted days. From the aerosol light absorption measurement perspective, MA300s tend to underestimate the absorption coefficients (<span class="inline-formula"><i>b</i><sub>abs</sub></span>) across the five wavelengths. UV channel light absorption results were subjected to the highest amount of noise and were found to be consistently underestimating in all the MA300 units, leading to systematic bias in source apportionment analysis. Absorption Ångström exponent values from the MA300 units were able to capture the variability of aerosol sources within a day, with a mean value of 1.15 during clean days and 1.46 during wildfire-smoke-affected days. We investigated the application of the latest non-linear aethalometer correction protocols in the MA300 and found that flow fluctuations enhanced noise across all channels, compared to onboard instrument correction. We also identify that the UV (<span class="inline-formula"><i>λ</i></span> <span class="inline-formula">=</span> 370 nm) channel absorption measurements are most sensitive to instrumental artifacts during the wildfire-smoke-affected period. Hence, as an alternative to traditional UV and IR (<span class="inline-formula"><i>λ</i></span> <span class="inline-formula">=</span> 880 nm)-based BC source apportionment methods, in this work, we tested the blue (<span class="inline-formula"><i>λ</i></span> <span class="inline-formula">=</span> 470 nm) and IR wavelengths for BC source apportionment calculation. When the blue–IR-based source apportionment technique is adopted instead of the UV–IR, there is a 10 % (on average) decrease in the percentage difference of the apportioned components from the reference monitor.</p>https://amt.copernicus.org/articles/16/2333/2023/amt-16-2333-2023.pdf |
| spellingShingle | M. Chakraborty A. Giang A. Giang N. Zimmerman Performance evaluation of portable dual-spot micro-aethalometers for source identification of black carbon aerosols: application to wildfire smoke and traffic emissions in the Pacific Northwest Atmospheric Measurement Techniques |
| title | Performance evaluation of portable dual-spot micro-aethalometers for source identification of black carbon aerosols: application to wildfire smoke and traffic emissions in the Pacific Northwest |
| title_full | Performance evaluation of portable dual-spot micro-aethalometers for source identification of black carbon aerosols: application to wildfire smoke and traffic emissions in the Pacific Northwest |
| title_fullStr | Performance evaluation of portable dual-spot micro-aethalometers for source identification of black carbon aerosols: application to wildfire smoke and traffic emissions in the Pacific Northwest |
| title_full_unstemmed | Performance evaluation of portable dual-spot micro-aethalometers for source identification of black carbon aerosols: application to wildfire smoke and traffic emissions in the Pacific Northwest |
| title_short | Performance evaluation of portable dual-spot micro-aethalometers for source identification of black carbon aerosols: application to wildfire smoke and traffic emissions in the Pacific Northwest |
| title_sort | performance evaluation of portable dual spot micro aethalometers for source identification of black carbon aerosols application to wildfire smoke and traffic emissions in the pacific northwest |
| url | https://amt.copernicus.org/articles/16/2333/2023/amt-16-2333-2023.pdf |
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