Recent advances of 2D metal-organic frameworks for electrochemical carbon dioxide reduction
The electrochemical carbon dioxide reduction (ECR) to profoundly diminished chemical entities offers a compelling avenue for transforming sporadic energy resources into enduring fuels while forging an enclosed anthropogenic carbon cycle. Metal-organic frameworks (MOFs) has been extensively investiga...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
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Elsevier
2024-03-01
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| Series: | Materials Today Catalysis |
| Subjects: | |
| Online Access: | http://www.sciencedirect.com/science/article/pii/S2949754X2400005X |
| _version_ | 1797237860853612544 |
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| author | Xingcheng Ma Meiling Xiao Changpeng Liu Wei Xing |
| author_facet | Xingcheng Ma Meiling Xiao Changpeng Liu Wei Xing |
| author_sort | Xingcheng Ma |
| collection | DOAJ |
| description | The electrochemical carbon dioxide reduction (ECR) to profoundly diminished chemical entities offers a compelling avenue for transforming sporadic energy resources into enduring fuels while forging an enclosed anthropogenic carbon cycle. Metal-organic frameworks (MOFs) has been extensively investigated as a promising multifunctional material for ECR. Notably, two-dimensional (2D) MOFs attract particular research attention due to their specific chemical and structural properties, i.e., enhanced electrical conductivity, increased open sites, improved mass transport and tunable interfacial environments. In this review, the recent progress of 2D MOFs for ECR is summarized. We begin with the introduction of the synthetic strategies of 2D MOFs. Then, we mainly focus on the advanced 2D MOF electrocatalysts for ECR in recent years, which are clarified by the products. The mechanism underlying the conversion of carbon dioxide (CO2) into carbon products, the factors influencing product formation and a summary of selected 2D MOF catalysts and their synthetic methods are presented. By consolidating the potential factors contributing to the products, we anticipate that the review will offer fresh opportunities for further advancements in CO2 reduction with 2D MOF catalysts. |
| first_indexed | 2024-04-24T17:26:28Z |
| format | Article |
| id | doaj.art-efe3237ffc994ab4b08a0cc44b4218b9 |
| institution | Directory Open Access Journal |
| issn | 2949-754X |
| language | English |
| last_indexed | 2024-04-24T17:26:28Z |
| publishDate | 2024-03-01 |
| publisher | Elsevier |
| record_format | Article |
| series | Materials Today Catalysis |
| spelling | doaj.art-efe3237ffc994ab4b08a0cc44b4218b92024-03-28T06:40:37ZengElsevierMaterials Today Catalysis2949-754X2024-03-014100043Recent advances of 2D metal-organic frameworks for electrochemical carbon dioxide reductionXingcheng Ma0Meiling Xiao1Changpeng Liu2Wei Xing3State Key Laboratory of Electroanalytical Chemistry, Laboratory of Advanced Power Sources, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, ChinaState Key Laboratory of Electroanalytical Chemistry, Laboratory of Advanced Power Sources, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China; School of Applied Chemistry and Engineering, University of Science and Technology of China, Hefei 230026, China; Corresponding authors at: State Key Laboratory of Electroanalytical Chemistry, Laboratory of Advanced Power Sources, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, ChinaState Key Laboratory of Electroanalytical Chemistry, Laboratory of Advanced Power Sources, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China; School of Applied Chemistry and Engineering, University of Science and Technology of China, Hefei 230026, China; Corresponding authors at: State Key Laboratory of Electroanalytical Chemistry, Laboratory of Advanced Power Sources, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, ChinaState Key Laboratory of Electroanalytical Chemistry, Laboratory of Advanced Power Sources, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China; School of Applied Chemistry and Engineering, University of Science and Technology of China, Hefei 230026, China; Corresponding authors at: State Key Laboratory of Electroanalytical Chemistry, Laboratory of Advanced Power Sources, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, ChinaThe electrochemical carbon dioxide reduction (ECR) to profoundly diminished chemical entities offers a compelling avenue for transforming sporadic energy resources into enduring fuels while forging an enclosed anthropogenic carbon cycle. Metal-organic frameworks (MOFs) has been extensively investigated as a promising multifunctional material for ECR. Notably, two-dimensional (2D) MOFs attract particular research attention due to their specific chemical and structural properties, i.e., enhanced electrical conductivity, increased open sites, improved mass transport and tunable interfacial environments. In this review, the recent progress of 2D MOFs for ECR is summarized. We begin with the introduction of the synthetic strategies of 2D MOFs. Then, we mainly focus on the advanced 2D MOF electrocatalysts for ECR in recent years, which are clarified by the products. The mechanism underlying the conversion of carbon dioxide (CO2) into carbon products, the factors influencing product formation and a summary of selected 2D MOF catalysts and their synthetic methods are presented. By consolidating the potential factors contributing to the products, we anticipate that the review will offer fresh opportunities for further advancements in CO2 reduction with 2D MOF catalysts.http://www.sciencedirect.com/science/article/pii/S2949754X2400005XCarbon dioxide reductionElectrocatalystsMetal-organic frameworksTwo-dimensional |
| spellingShingle | Xingcheng Ma Meiling Xiao Changpeng Liu Wei Xing Recent advances of 2D metal-organic frameworks for electrochemical carbon dioxide reduction Materials Today Catalysis Carbon dioxide reduction Electrocatalysts Metal-organic frameworks Two-dimensional |
| title | Recent advances of 2D metal-organic frameworks for electrochemical carbon dioxide reduction |
| title_full | Recent advances of 2D metal-organic frameworks for electrochemical carbon dioxide reduction |
| title_fullStr | Recent advances of 2D metal-organic frameworks for electrochemical carbon dioxide reduction |
| title_full_unstemmed | Recent advances of 2D metal-organic frameworks for electrochemical carbon dioxide reduction |
| title_short | Recent advances of 2D metal-organic frameworks for electrochemical carbon dioxide reduction |
| title_sort | recent advances of 2d metal organic frameworks for electrochemical carbon dioxide reduction |
| topic | Carbon dioxide reduction Electrocatalysts Metal-organic frameworks Two-dimensional |
| url | http://www.sciencedirect.com/science/article/pii/S2949754X2400005X |
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