Bimetallic Metal-Organic Framework Mediated Synthesis of Ni-Co Catalysts for the Dry Reforming of Methane
Dry reforming of methane (DRM) involves the conversion of CO<sub>2</sub> and CH<sub>4</sub>, the most important greenhouse gases, into syngas, a stoichiometric mixture of H<sub>2</sub> and CO that can be further processed via Fischer–Tropsch chemistry into a wide...
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| Format: | Article |
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MDPI AG
2020-05-01
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| Series: | Catalysts |
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| Online Access: | https://www.mdpi.com/2073-4344/10/5/592 |
| _version_ | 1797567120604659712 |
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| author | Il Son Khan Adrian Ramirez Genrikh Shterk Luis Garzón-Tovar Jorge Gascon |
| author_facet | Il Son Khan Adrian Ramirez Genrikh Shterk Luis Garzón-Tovar Jorge Gascon |
| author_sort | Il Son Khan |
| collection | DOAJ |
| description | Dry reforming of methane (DRM) involves the conversion of CO<sub>2</sub> and CH<sub>4</sub>, the most important greenhouse gases, into syngas, a stoichiometric mixture of H<sub>2</sub> and CO that can be further processed via Fischer–Tropsch chemistry into a wide variety of products. However, the devolvement of the coke resistant catalyst, especially at high pressures, is still hampering commercial applications. One of the relatively new approaches for the synthesis of metal nanoparticle based catalysts comprises the use of metal-organic frameworks (MOFs) as catalyst precursors. In this work we have explored MOF-74/CPO-27 MOFs as precursors for the synthesis of Ni, Co and bimetallic Ni-Co metal nanoparticles. Our results show that the bimetallic system produced through pyrolysis of a Ni-Co@CMOF-74 precursor displays the best activity at moderate pressures, with stable performance during at least 10 h at 700 °C, 5 bar and 33 L·h<sup>−1</sup>·g<sup>−1</sup>. |
| first_indexed | 2024-03-10T19:36:10Z |
| format | Article |
| id | doaj.art-efeac63ba65a4edb83c7a58ecef2acb5 |
| institution | Directory Open Access Journal |
| issn | 2073-4344 |
| language | English |
| last_indexed | 2024-03-10T19:36:10Z |
| publishDate | 2020-05-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Catalysts |
| spelling | doaj.art-efeac63ba65a4edb83c7a58ecef2acb52023-11-20T01:41:20ZengMDPI AGCatalysts2073-43442020-05-0110559210.3390/catal10050592Bimetallic Metal-Organic Framework Mediated Synthesis of Ni-Co Catalysts for the Dry Reforming of MethaneIl Son Khan0Adrian Ramirez1Genrikh Shterk2Luis Garzón-Tovar3Jorge Gascon4Advanced Catalytic Materials, KAUST Catalysis Center (KCC), King Abdullah University of Science and Technology, Thuwal 23955, Saudi ArabiaAdvanced Catalytic Materials, KAUST Catalysis Center (KCC), King Abdullah University of Science and Technology, Thuwal 23955, Saudi ArabiaAdvanced Catalytic Materials, KAUST Catalysis Center (KCC), King Abdullah University of Science and Technology, Thuwal 23955, Saudi ArabiaAdvanced Catalytic Materials, KAUST Catalysis Center (KCC), King Abdullah University of Science and Technology, Thuwal 23955, Saudi ArabiaAdvanced Catalytic Materials, KAUST Catalysis Center (KCC), King Abdullah University of Science and Technology, Thuwal 23955, Saudi ArabiaDry reforming of methane (DRM) involves the conversion of CO<sub>2</sub> and CH<sub>4</sub>, the most important greenhouse gases, into syngas, a stoichiometric mixture of H<sub>2</sub> and CO that can be further processed via Fischer–Tropsch chemistry into a wide variety of products. However, the devolvement of the coke resistant catalyst, especially at high pressures, is still hampering commercial applications. One of the relatively new approaches for the synthesis of metal nanoparticle based catalysts comprises the use of metal-organic frameworks (MOFs) as catalyst precursors. In this work we have explored MOF-74/CPO-27 MOFs as precursors for the synthesis of Ni, Co and bimetallic Ni-Co metal nanoparticles. Our results show that the bimetallic system produced through pyrolysis of a Ni-Co@CMOF-74 precursor displays the best activity at moderate pressures, with stable performance during at least 10 h at 700 °C, 5 bar and 33 L·h<sup>−1</sup>·g<sup>−1</sup>.https://www.mdpi.com/2073-4344/10/5/592metal-organic frameworksMOFdry reformingcatalysis |
| spellingShingle | Il Son Khan Adrian Ramirez Genrikh Shterk Luis Garzón-Tovar Jorge Gascon Bimetallic Metal-Organic Framework Mediated Synthesis of Ni-Co Catalysts for the Dry Reforming of Methane Catalysts metal-organic frameworks MOF dry reforming catalysis |
| title | Bimetallic Metal-Organic Framework Mediated Synthesis of Ni-Co Catalysts for the Dry Reforming of Methane |
| title_full | Bimetallic Metal-Organic Framework Mediated Synthesis of Ni-Co Catalysts for the Dry Reforming of Methane |
| title_fullStr | Bimetallic Metal-Organic Framework Mediated Synthesis of Ni-Co Catalysts for the Dry Reforming of Methane |
| title_full_unstemmed | Bimetallic Metal-Organic Framework Mediated Synthesis of Ni-Co Catalysts for the Dry Reforming of Methane |
| title_short | Bimetallic Metal-Organic Framework Mediated Synthesis of Ni-Co Catalysts for the Dry Reforming of Methane |
| title_sort | bimetallic metal organic framework mediated synthesis of ni co catalysts for the dry reforming of methane |
| topic | metal-organic frameworks MOF dry reforming catalysis |
| url | https://www.mdpi.com/2073-4344/10/5/592 |
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