Multi-Technique Characterization of a Fine Fraction of CDW and Assessment of Reactivity in a CDW/Lime System

This study analysed the fine particle (<5 mm) waste generated during siliceous or calcareous (depending on the composition of the original aggregate) concrete waste crushing. In the absence of industrial applications, such waste is amassed in open-air stockpiles on construction and demolition was...

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Main Authors: Moisés Frías, Raquel Vigil de la Villa, Sagrario Martínez-Ramírez, Lucía Fernández-Carrasco, Ernesto Villar-Cociña, Rosario García-Giménez
Format: Article
Language:English
Published: MDPI AG 2020-06-01
Series:Minerals
Subjects:
Online Access:https://www.mdpi.com/2075-163X/10/7/590
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author Moisés Frías
Raquel Vigil de la Villa
Sagrario Martínez-Ramírez
Lucía Fernández-Carrasco
Ernesto Villar-Cociña
Rosario García-Giménez
author_facet Moisés Frías
Raquel Vigil de la Villa
Sagrario Martínez-Ramírez
Lucía Fernández-Carrasco
Ernesto Villar-Cociña
Rosario García-Giménez
author_sort Moisés Frías
collection DOAJ
description This study analysed the fine particle (<5 mm) waste generated during siliceous or calcareous (depending on the composition of the original aggregate) concrete waste crushing. In the absence of industrial applications, such waste is amassed in open-air stockpiles on construction and demolition wastes (CDW) management plant grounds. The aim pursued was to find an outlet for that material in the cement industry. The starting waste, sourced from six Spanish management facilities, was characterised for its chemical and mineralogical composition, physical properties and pozzolanicity. The mineralogical phases in the CDW/lime system and their variations during the pozzolanic reaction were likewise identified. The findings showed that the fine waste consisted primarily in quartz, calcite, micas and feldspars, with smaller fractions of kaolinite and cement anhydrous phases. No portland cement hydration phases were identified. All six types analysed exhibited medium to low pozzolanicity, with the highest values recorded for the siliceous waste. Ettringite, C–S–H gels and calcium aluminate hydrates (C<sub>4</sub>AH<sub>13,</sub> C<sub>4</sub>AcH<sub>12</sub>) were identified during the pozzolanic reaction in CDW/lime system. Therefore, this type of waste can be reused as supplementary cementitious material with low-medium pozzolanic activity.
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spelling doaj.art-f00b2ad5a1fd4c44ba09d22d1d4a77632023-11-20T05:22:59ZengMDPI AGMinerals2075-163X2020-06-0110759010.3390/min10070590Multi-Technique Characterization of a Fine Fraction of CDW and Assessment of Reactivity in a CDW/Lime SystemMoisés Frías0Raquel Vigil de la Villa1Sagrario Martínez-Ramírez2Lucía Fernández-Carrasco3Ernesto Villar-Cociña4Rosario García-Giménez5Eduardo Torroja Institute for Construction Science (IETcc-CSIC), 28033 Madrid, SpainDepartamento de Geología y Geoquímica, Geomateriales Unidad Asociada CSIC-UAM, Universidad Autónoma de Madrid, 28049 Madrid, SpainInstitute for the Structure of Matter (IEM-CSIC), 28006 Madrid, SpainDepartment of Civil and Environmental Engineering, Barcelona TECH, Universitat Politècnica de Catalunya, 08034 Barcelona, SpainDepartment of Physics, Central University of Las Villas, Santa Clara 54830, Villa Clara, CubaDepartamento de Geología y Geoquímica, Geomateriales Unidad Asociada CSIC-UAM, Universidad Autónoma de Madrid, 28049 Madrid, SpainThis study analysed the fine particle (<5 mm) waste generated during siliceous or calcareous (depending on the composition of the original aggregate) concrete waste crushing. In the absence of industrial applications, such waste is amassed in open-air stockpiles on construction and demolition wastes (CDW) management plant grounds. The aim pursued was to find an outlet for that material in the cement industry. The starting waste, sourced from six Spanish management facilities, was characterised for its chemical and mineralogical composition, physical properties and pozzolanicity. The mineralogical phases in the CDW/lime system and their variations during the pozzolanic reaction were likewise identified. The findings showed that the fine waste consisted primarily in quartz, calcite, micas and feldspars, with smaller fractions of kaolinite and cement anhydrous phases. No portland cement hydration phases were identified. All six types analysed exhibited medium to low pozzolanicity, with the highest values recorded for the siliceous waste. Ettringite, C–S–H gels and calcium aluminate hydrates (C<sub>4</sub>AH<sub>13,</sub> C<sub>4</sub>AcH<sub>12</sub>) were identified during the pozzolanic reaction in CDW/lime system. Therefore, this type of waste can be reused as supplementary cementitious material with low-medium pozzolanic activity.https://www.mdpi.com/2075-163X/10/7/590fine particle wasteconcrete-based CDWmineralogypozzolanicityhydrated phases
spellingShingle Moisés Frías
Raquel Vigil de la Villa
Sagrario Martínez-Ramírez
Lucía Fernández-Carrasco
Ernesto Villar-Cociña
Rosario García-Giménez
Multi-Technique Characterization of a Fine Fraction of CDW and Assessment of Reactivity in a CDW/Lime System
Minerals
fine particle waste
concrete-based CDW
mineralogy
pozzolanicity
hydrated phases
title Multi-Technique Characterization of a Fine Fraction of CDW and Assessment of Reactivity in a CDW/Lime System
title_full Multi-Technique Characterization of a Fine Fraction of CDW and Assessment of Reactivity in a CDW/Lime System
title_fullStr Multi-Technique Characterization of a Fine Fraction of CDW and Assessment of Reactivity in a CDW/Lime System
title_full_unstemmed Multi-Technique Characterization of a Fine Fraction of CDW and Assessment of Reactivity in a CDW/Lime System
title_short Multi-Technique Characterization of a Fine Fraction of CDW and Assessment of Reactivity in a CDW/Lime System
title_sort multi technique characterization of a fine fraction of cdw and assessment of reactivity in a cdw lime system
topic fine particle waste
concrete-based CDW
mineralogy
pozzolanicity
hydrated phases
url https://www.mdpi.com/2075-163X/10/7/590
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