The Dawn of Lead‐Free Perovskite Solar Cell: Highly Stable Double Perovskite Cs2AgBiBr6 Film

Abstract Recently, lead‐free double perovskites have emerged as a promising environmentally friendly photovoltaic material for their intrinsic thermodynamic stability, appropriate bandgaps, small carrier effective masses, and low exciton binding energies. However, currently no solar cell based on th...

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Main Authors: Cuncun Wu, Qiaohui Zhang, Yang Liu, Wei Luo, Xuan Guo, Ziru Huang, Hungkit Ting, Weihai Sun, Xinrui Zhong, Shiyuan Wei, Shufeng Wang, Zhijian Chen, Lixin Xiao
Format: Article
Language:English
Published: Wiley 2018-03-01
Series:Advanced Science
Subjects:
Online Access:https://doi.org/10.1002/advs.201700759
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author Cuncun Wu
Qiaohui Zhang
Yang Liu
Wei Luo
Xuan Guo
Ziru Huang
Hungkit Ting
Weihai Sun
Xinrui Zhong
Shiyuan Wei
Shufeng Wang
Zhijian Chen
Lixin Xiao
author_facet Cuncun Wu
Qiaohui Zhang
Yang Liu
Wei Luo
Xuan Guo
Ziru Huang
Hungkit Ting
Weihai Sun
Xinrui Zhong
Shiyuan Wei
Shufeng Wang
Zhijian Chen
Lixin Xiao
author_sort Cuncun Wu
collection DOAJ
description Abstract Recently, lead‐free double perovskites have emerged as a promising environmentally friendly photovoltaic material for their intrinsic thermodynamic stability, appropriate bandgaps, small carrier effective masses, and low exciton binding energies. However, currently no solar cell based on these double perovskites has been reported, due to the challenge in film processing. Herein, a first lead‐free double perovskite planar heterojunction solar cell with a high quality Cs2AgBiBr6 film, fabricated by low‐pressure assisted solution processing under ambient conditions, is reported. The device presents a best power conversion efficiency of 1.44%. The preliminary efficiency and the high stability under ambient condition without encapsulation, together with the high film quality with simple processing, demonstrate promise for lead‐free perovskite solar cells.
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spelling doaj.art-f025f8037db841c583515436e60b8d602022-12-21T19:40:32ZengWileyAdvanced Science2198-38442018-03-0153n/an/a10.1002/advs.201700759The Dawn of Lead‐Free Perovskite Solar Cell: Highly Stable Double Perovskite Cs2AgBiBr6 FilmCuncun Wu0Qiaohui Zhang1Yang Liu2Wei Luo3Xuan Guo4Ziru Huang5Hungkit Ting6Weihai Sun7Xinrui Zhong8Shiyuan Wei9Shufeng Wang10Zhijian Chen11Lixin Xiao12Laboratory for Mesoscopic Physics and Department of Physics Peking University Beijing 100871 P. R. ChinaLaboratory for Mesoscopic Physics and Department of Physics Peking University Beijing 100871 P. R. ChinaLaboratory for Mesoscopic Physics and Department of Physics Peking University Beijing 100871 P. R. ChinaLaboratory for Mesoscopic Physics and Department of Physics Peking University Beijing 100871 P. R. ChinaLaboratory for Mesoscopic Physics and Department of Physics Peking University Beijing 100871 P. R. ChinaLaboratory for Mesoscopic Physics and Department of Physics Peking University Beijing 100871 P. R. ChinaLaboratory for Mesoscopic Physics and Department of Physics Peking University Beijing 100871 P. R. ChinaLaboratory for Mesoscopic Physics and Department of Physics Peking University Beijing 100871 P. R. ChinaLaboratory for Mesoscopic Physics and Department of Physics Peking University Beijing 100871 P. R. ChinaLaboratory for Mesoscopic Physics and Department of Physics Peking University Beijing 100871 P. R. ChinaLaboratory for Mesoscopic Physics and Department of Physics Peking University Beijing 100871 P. R. ChinaLaboratory for Mesoscopic Physics and Department of Physics Peking University Beijing 100871 P. R. ChinaLaboratory for Mesoscopic Physics and Department of Physics Peking University Beijing 100871 P. R. ChinaAbstract Recently, lead‐free double perovskites have emerged as a promising environmentally friendly photovoltaic material for their intrinsic thermodynamic stability, appropriate bandgaps, small carrier effective masses, and low exciton binding energies. However, currently no solar cell based on these double perovskites has been reported, due to the challenge in film processing. Herein, a first lead‐free double perovskite planar heterojunction solar cell with a high quality Cs2AgBiBr6 film, fabricated by low‐pressure assisted solution processing under ambient conditions, is reported. The device presents a best power conversion efficiency of 1.44%. The preliminary efficiency and the high stability under ambient condition without encapsulation, together with the high film quality with simple processing, demonstrate promise for lead‐free perovskite solar cells.https://doi.org/10.1002/advs.201700759Cs2AgBiBr6double perovskiteslead‐freeperovskite solar cellplanar heterojunction
spellingShingle Cuncun Wu
Qiaohui Zhang
Yang Liu
Wei Luo
Xuan Guo
Ziru Huang
Hungkit Ting
Weihai Sun
Xinrui Zhong
Shiyuan Wei
Shufeng Wang
Zhijian Chen
Lixin Xiao
The Dawn of Lead‐Free Perovskite Solar Cell: Highly Stable Double Perovskite Cs2AgBiBr6 Film
Advanced Science
Cs2AgBiBr6
double perovskites
lead‐free
perovskite solar cell
planar heterojunction
title The Dawn of Lead‐Free Perovskite Solar Cell: Highly Stable Double Perovskite Cs2AgBiBr6 Film
title_full The Dawn of Lead‐Free Perovskite Solar Cell: Highly Stable Double Perovskite Cs2AgBiBr6 Film
title_fullStr The Dawn of Lead‐Free Perovskite Solar Cell: Highly Stable Double Perovskite Cs2AgBiBr6 Film
title_full_unstemmed The Dawn of Lead‐Free Perovskite Solar Cell: Highly Stable Double Perovskite Cs2AgBiBr6 Film
title_short The Dawn of Lead‐Free Perovskite Solar Cell: Highly Stable Double Perovskite Cs2AgBiBr6 Film
title_sort dawn of lead free perovskite solar cell highly stable double perovskite cs2agbibr6 film
topic Cs2AgBiBr6
double perovskites
lead‐free
perovskite solar cell
planar heterojunction
url https://doi.org/10.1002/advs.201700759
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