The kinetics and mechanism of an aqueous phase isoprene reaction with hydroxyl radical

The kinetics and mechanism of an aqueous phase isoprene reaction with hydroxyl radical

Aqueous phase chemical processes of organic compounds in the atmosphere have received increasing attention, partly due to their potential contribution to the formation of secondary organic aerosol (SOA). Here, we analyzed the aqueous OH-initiated oxidation of isoprene and its reaction products inclu...

Full description

Bibliographic Details
Main Authors:	D. Huang, X. Zhang, Z. M. Chen, Y. Zhao, X. L. Shen
Format:	Article
Language:	English
Published:	Copernicus Publications 2011-08-01
Series:	Atmospheric Chemistry and Physics
Online Access:	http://www.atmos-chem-phys.net/11/7399/2011/acp-11-7399-2011.pdf

Similar Items

<i>Corrigendum to</i> "The kinetics and mechanism of an aqueous phase isoprene reaction with hydroxyl radical" published in Atmos. Chem. Phys., 11, 7399–7415, 2011
by: X. L. Shen, et al.
Published: (2011-12-01)

Understanding the aqueous phase ozonolysis of isoprene: distinct product distribution and mechanism from the gas phase reaction
by: H. L. Wang, et al.
Published: (2012-08-01)

Theoretical Calculation on the Reaction Mechanisms, Kinetics and Toxicity of Acetaminophen Degradation Initiated by Hydroxyl and Sulfate Radicals in the Aqueous Phase
by: Mengmeng Xu, et al.
Published: (2021-09-01)

Temperature-dependent rate coefficients for the reactions of the hydroxyl radical with the atmospheric biogenics isoprene, alpha-pinene and delta-3-carene
by: T. J. Dillon, et al.
Published: (2017-12-01)

Towards a chemical mechanism of the oxidation of aqueous sulfur dioxide via isoprene hydroxyl hydroperoxides (ISOPOOH)
by: E. Dovrou, et al.
Published: (2021-06-01)

Penetration of hydroxyl radicals in the aqueous phase surrounding a cavitation bubble
by: Kewen Peng, et al.
Published: (2022-12-01)

Kinetics of the reactions of isoprene-derived hydroxynitrates: gas phase epoxide formation and solution phase hydrolysis
by: M. I. Jacobs, et al.
Published: (2014-09-01)

Chemical characterization of SOA formed from aqueous-phase reactions of phenols with the triplet excited state of carbonyl and hydroxyl radical
by: L. Yu, et al.
Published: (2014-12-01)

Role of (H2O)n (n = 1–2) in the Gas-Phase Reaction of Ethanol with Hydroxyl Radical: Mechanism, Kinetics, and Products
by: Li Xu, et al.
Published: (2019-03-01)

Kinetics of the Gas-Phase Reaction of Hydroxyl Radicals with Dimethyl Methylphosphonate (DMMP) over an Extended Temperature Range (273–837 K)
by: Xiaokai Zhang, et al.
Published: (2022-04-01)

Atmospheric reaction of hydrazine plus hydroxyl radical
by: Hamed Douroudgari, et al.
Published: (2021-06-01)

Rate constant and secondary organic aerosol formation from the gas-phase reaction of eugenol with hydroxyl radicals
by: C. Liu, et al.
Published: (2019-02-01)

Photodegradation kinetics of organophosphorous with hydroxyl radicals: Experimental and theoretical study
by: Aydogdu Seyda, et al.
Published: (2021-01-01)

Constraining condensed-phase formation kinetics of secondary organic aerosol components from isoprene epoxydiols
by: T. P. Riedel, et al.
Published: (2016-02-01)

Theoretical Kinetics studies of isoprene peroxy radical chemistry: The fate of Z-δ-(4-OH, 1-OO)-ISOPOO radical
by: Yan Li, et al.
Published: (2023-11-01)

Supplementary data for the mechanism research for depolymerization of cellulose induced by hydroxyl radical using GC–MS, reaction kinetics simulation and quantum chemistry computation
by: Chunfu Shao, et al.
Published: (2020-04-01)

Secondary organic aerosol (SOA) formation from reaction of isoprene with nitrate radicals (NO3)
by: R. C. Flagan, et al.
Published: (2008-08-01)

Reactions of isoprene and sulphoxy radical-anions – a possible source of atmospheric organosulphites and organosulphates
by: K. J. Rudziński, et al.
Published: (2009-03-01)

Dextran Methacrylate Reactions with Hydroxyl Radicals and Hydrated Electrons in Water: A Kinetic Study Using Pulse Radiolysis
by: Kamila J. Szafulera, et al.
Published: (2023-05-01)

Aqueous chemical bleaching of 4-nitrophenol brown carbon by hydroxyl radicals; products, mechanism, and light absorption
by: B. Witkowski, et al.
Published: (2022-04-01)

AMORE-Isoprene v1.0: a new reduced mechanism for gas-phase isoprene oxidation
by: F. Wiser, et al.
Published: (2023-03-01)

The reaction of hydroxyl and methylperoxy radicals is not a major source of atmospheric methanol
by: Rebecca L. Caravan, et al.
Published: (2018-10-01)

Hydroxyl radical production via the photo-Fenton reaction in natural waters
by: Southworth, Barbara A. (Barbara Anne), 1973-
Published: (2005)

Hydroxyl Radical Scavenging of Indole-3-Carbinol: A Mechanistic and Kinetic Study
by: Quan V. Vo, et al.
Published: (2019-11-01)

Heterogeneous oxidation of saturated organic aerosols by hydroxyl radicals: uptake kinetics, condensed-phase products, and particle size change
by: I. J. George, et al.
Published: (2007-08-01)

N‑Heterocyclic Carbene-Catalyzed Radical Reactions for Highly Enantioselective β‑Hydroxylation of Enals
by: Zhang, Yuexia, et al.
Published: (2016)

The Detection Methods of Hydroxyl Radical: A Review
by: Huang Chenkun, et al.
Published: (2023-01-01)

The Colorimetric Detection of the Hydroxyl Radical
by: Yandong Ran, et al.
Published: (2023-02-01)

Kinetics of the gas-phase reactions of OH radicals with alkanes and cycloalkanes
by: R. Atkinson
Published: (2003-01-01)

Multi-level Quantum Mechanics and Molecular Mechanics Study of Ring Opening Process of Guanine Damage by Hydroxyl Radical in Aqueous Solution
by: Peng Liu, et al.
Published: (2017-08-01)

Theoretical Study of Radical–Molecule Reactions with Negative Activation Energies in Combustion: Hydroxyl Radical Addition to Alkenes
by: FengXia Xiao, et al.
Published: (2020-05-01)

Importance of isomerization reactions for OH radical regeneration from the photo-oxidation of isoprene investigated in the atmospheric simulation chamber SAPHIR
by: A. Novelli, et al.
Published: (2020-03-01)

The reaction of methyl peroxy and hydroxyl radicals as a major source of atmospheric methanol
by: Jean-François Müller, et al.
Published: (2016-10-01)

Computer Simulation of Opposing Reaction Kinetics
by: X.Z. Huang, et al.
Published: (2015-12-01)

Kinetics of dimethyl sulfide (DMS) reactions with isoprene-derived Criegee intermediates studied with direct UV absorption
by: M.-T. Kuo, et al.
Published: (2020-11-01)

Hydroxyl radical reactivity at the air-ice interface
by: T. F. Kahan, et al.
Published: (2010-01-01)

Phenolic compounds induce ferroptosis-like death by promoting hydroxyl radical generation in the Fenton reaction
by: Xinyue Sui, et al.
Published: (2024-02-01)

Kinetics of the Toluene Reaction with OH Radical
by: Rui Ming Zhang, et al.
Published: (2019-01-01)

A self-consistent, multivariate method for the determination of gas-phase rate coefficients, applied to reactions of atmospheric VOCs and the hydroxyl radical
by: J. T. Shaw, et al.
Published: (2018-03-01)

Influences of hydroxyl radicals (OH) on top-down estimates of the global and regional methane budgets
by: Y. Zhao, et al.
Published: (2020-08-01)