Reversible Diels–Alder Addition to Fullerenes: A Study of Dimethylanthracene with H<sub>2</sub>@C<sub>60</sub>
The study of isolated atoms or molecules inside a fullerene cavity provides a unique environment. It is likely to control the outer carbon cage and study the isolated species when molecules or atoms are trapped inside a fullerene. We report the Diels–Alder addition reaction of 9,10-dimethyl anthrace...
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MDPI AG
2022-05-01
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| Series: | Nanomaterials |
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| Online Access: | https://www.mdpi.com/2079-4991/12/10/1667 |
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| author | Mahboob Subhani Jinrong Zhou Yuguang Sui Huijing Zou Michael Frunzi James Cross Martin Saunders Cijun Shuai Wenjie Liang Hai Xu |
| author_facet | Mahboob Subhani Jinrong Zhou Yuguang Sui Huijing Zou Michael Frunzi James Cross Martin Saunders Cijun Shuai Wenjie Liang Hai Xu |
| author_sort | Mahboob Subhani |
| collection | DOAJ |
| description | The study of isolated atoms or molecules inside a fullerene cavity provides a unique environment. It is likely to control the outer carbon cage and study the isolated species when molecules or atoms are trapped inside a fullerene. We report the Diels–Alder addition reaction of 9,10-dimethyl anthracene (DMA) to H<sub>2</sub>@C<sub>60</sub> while <sup>1</sup>H NMR spectroscopy is utilized to characterize the Diels–Alder reaction of the DMA with the fullerene. Through <sup>1</sup>H NMR spectroscopy, a series of isomeric adducts are identified. The obtained peaks are sharp, precise, and straightforward. Moreover, in this paper, H<sub>2</sub>@C<sub>60</sub> and its isomers are described for the first time. |
| first_indexed | 2024-03-10T03:17:18Z |
| format | Article |
| id | doaj.art-f06bc408a905475a8369f7d6ffb8a792 |
| institution | Directory Open Access Journal |
| issn | 2079-4991 |
| language | English |
| last_indexed | 2024-03-10T03:17:18Z |
| publishDate | 2022-05-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Nanomaterials |
| spelling | doaj.art-f06bc408a905475a8369f7d6ffb8a7922023-11-23T12:26:21ZengMDPI AGNanomaterials2079-49912022-05-011210166710.3390/nano12101667Reversible Diels–Alder Addition to Fullerenes: A Study of Dimethylanthracene with H<sub>2</sub>@C<sub>60</sub>Mahboob Subhani0Jinrong Zhou1Yuguang Sui2Huijing Zou3Michael Frunzi4James Cross5Martin Saunders6Cijun Shuai7Wenjie Liang8Hai Xu9College of Chemistry and Chemical Engineering, Central South University, South Lushan Road, Changsha 410083, ChinaCollege of Chemistry and Chemical Engineering, Central South University, South Lushan Road, Changsha 410083, ChinaCollege of Chemistry and Chemical Engineering, Central South University, South Lushan Road, Changsha 410083, ChinaDepartment of Biology, College of Arts and Science, New York University, New York, NY 10012, USADepartment of Chemistry, Yale University, New Haven, CT 06520, USADepartment of Chemistry, Yale University, New Haven, CT 06520, USADepartment of Chemistry, Yale University, New Haven, CT 06520, USACollege of Mechanical and Electrical Engineering, Central South University, South Lushan Road, Changsha 410083, ChinaCollege of Chemistry and Chemical Engineering, Central South University, South Lushan Road, Changsha 410083, ChinaCollege of Chemistry and Chemical Engineering, Central South University, South Lushan Road, Changsha 410083, ChinaThe study of isolated atoms or molecules inside a fullerene cavity provides a unique environment. It is likely to control the outer carbon cage and study the isolated species when molecules or atoms are trapped inside a fullerene. We report the Diels–Alder addition reaction of 9,10-dimethyl anthracene (DMA) to H<sub>2</sub>@C<sub>60</sub> while <sup>1</sup>H NMR spectroscopy is utilized to characterize the Diels–Alder reaction of the DMA with the fullerene. Through <sup>1</sup>H NMR spectroscopy, a series of isomeric adducts are identified. The obtained peaks are sharp, precise, and straightforward. Moreover, in this paper, H<sub>2</sub>@C<sub>60</sub> and its isomers are described for the first time.https://www.mdpi.com/2079-4991/12/10/1667<sup>1</sup>H NMR spectroscopyDiels–Alder reaction9,10-dimethylanthracenefullereneH<sub>2</sub>@C<sub>60</sub> |
| spellingShingle | Mahboob Subhani Jinrong Zhou Yuguang Sui Huijing Zou Michael Frunzi James Cross Martin Saunders Cijun Shuai Wenjie Liang Hai Xu Reversible Diels–Alder Addition to Fullerenes: A Study of Dimethylanthracene with H<sub>2</sub>@C<sub>60</sub> Nanomaterials <sup>1</sup>H NMR spectroscopy Diels–Alder reaction 9,10-dimethylanthracene fullerene H<sub>2</sub>@C<sub>60</sub> |
| title | Reversible Diels–Alder Addition to Fullerenes: A Study of Dimethylanthracene with H<sub>2</sub>@C<sub>60</sub> |
| title_full | Reversible Diels–Alder Addition to Fullerenes: A Study of Dimethylanthracene with H<sub>2</sub>@C<sub>60</sub> |
| title_fullStr | Reversible Diels–Alder Addition to Fullerenes: A Study of Dimethylanthracene with H<sub>2</sub>@C<sub>60</sub> |
| title_full_unstemmed | Reversible Diels–Alder Addition to Fullerenes: A Study of Dimethylanthracene with H<sub>2</sub>@C<sub>60</sub> |
| title_short | Reversible Diels–Alder Addition to Fullerenes: A Study of Dimethylanthracene with H<sub>2</sub>@C<sub>60</sub> |
| title_sort | reversible diels alder addition to fullerenes a study of dimethylanthracene with h sub 2 sub c sub 60 sub |
| topic | <sup>1</sup>H NMR spectroscopy Diels–Alder reaction 9,10-dimethylanthracene fullerene H<sub>2</sub>@C<sub>60</sub> |
| url | https://www.mdpi.com/2079-4991/12/10/1667 |
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