In situ growth of NiO nanostructures supported on nickel foam as an efficient electrocatalyst for oxygen evolution reaction

Recently, the concerns about depletion of fossil fuels and also the environmental pollution arisen from burning of them have driven scientists to quest for clean and sustainable energy resources. Some advantages of hydrogen have made it as an alternative energy resource to fossil fuels. Electrochemi...

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Main Authors: Ahmad Ahmadi Daryakenari, Somayeh Sepehri, Behrooz Mosallanejad, Mahshid Ershadi, Mohammad Ahmadi Daryakenari
Format: Article
Language:English
Published: Iranian Chemical Society 2021-06-01
Series:Nanochemistry Research
Subjects:
Online Access:http://www.nanochemres.org/article_138037_a4fc2db6d9def978e8cc1e21da738e55.pdf
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author Ahmad Ahmadi Daryakenari
Somayeh Sepehri
Behrooz Mosallanejad
Mahshid Ershadi
Mohammad Ahmadi Daryakenari
author_facet Ahmad Ahmadi Daryakenari
Somayeh Sepehri
Behrooz Mosallanejad
Mahshid Ershadi
Mohammad Ahmadi Daryakenari
author_sort Ahmad Ahmadi Daryakenari
collection DOAJ
description Recently, the concerns about depletion of fossil fuels and also the environmental pollution arisen from burning of them have driven scientists to quest for clean and sustainable energy resources. Some advantages of hydrogen have made it as an alternative energy resource to fossil fuels. Electrochemically splitting of water is considered as one of the main techniques to produce high-purity hydrogen. Fabrication of cost-effective electrocatalysts for oxygen evolution reaction (OER) in a water splitting process is vital for large-scale practical applications. Herein, we present an affordable and straightforward method for synthesis of NiO nanoparticles supported on Ni foam for oxygen evolution reaction (OER). A single-step annealing process is carried out at the different temperatures to achieve an optimal temperature, at which an electrocatalyst with a tailored morphology and high electrocatalytic activity is obtainable. The best electrocatalytic activity is showed by the electrode fabricated at 400 °C, which delivers current density of 10 mA/cm2 at 1.59 mV potential versus reversible hydrogen electrode (RHE) under alkaline condition. Various material characterization tests accompanied by electrochemical measurements are employed to clarify the cause of the excellent electrocatalytic activity of the electrode fabricated at 400 °C.
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spelling doaj.art-f0878884f53948559b63a7360ac6e6cd2023-02-05T07:27:31ZengIranian Chemical SocietyNanochemistry Research2538-42792423-818X2021-06-0161727810.22036/ncr.2021.01.007138037In situ growth of NiO nanostructures supported on nickel foam as an efficient electrocatalyst for oxygen evolution reactionAhmad Ahmadi Daryakenari0Somayeh Sepehri1Behrooz Mosallanejad2Mahshid Ershadi3Mohammad Ahmadi Daryakenari4Department of Nanotechnology, Faculty of Engineering, University of Guilan, Rasht, Guilan, IranDepartment of Nanotechnology, Faculty of Engineering, University of Guilan, Rasht, Guilan, IranFaculty of Chemistry, Amirkabir University of Technology (Tehran Polytechnic), Tehran, IranFaculty of Chemistry, Amirkabir University of Technology (Tehran Polytechnic), Tehran, IranFaculty of Chemical and Materials Engineering, Shahrood University of Technology, Shahrood, IranRecently, the concerns about depletion of fossil fuels and also the environmental pollution arisen from burning of them have driven scientists to quest for clean and sustainable energy resources. Some advantages of hydrogen have made it as an alternative energy resource to fossil fuels. Electrochemically splitting of water is considered as one of the main techniques to produce high-purity hydrogen. Fabrication of cost-effective electrocatalysts for oxygen evolution reaction (OER) in a water splitting process is vital for large-scale practical applications. Herein, we present an affordable and straightforward method for synthesis of NiO nanoparticles supported on Ni foam for oxygen evolution reaction (OER). A single-step annealing process is carried out at the different temperatures to achieve an optimal temperature, at which an electrocatalyst with a tailored morphology and high electrocatalytic activity is obtainable. The best electrocatalytic activity is showed by the electrode fabricated at 400 °C, which delivers current density of 10 mA/cm2 at 1.59 mV potential versus reversible hydrogen electrode (RHE) under alkaline condition. Various material characterization tests accompanied by electrochemical measurements are employed to clarify the cause of the excellent electrocatalytic activity of the electrode fabricated at 400 °C.http://www.nanochemres.org/article_138037_a4fc2db6d9def978e8cc1e21da738e55.pdfnio nanostructuresoxygen evolution reactionthermal annealingnickel foam
spellingShingle Ahmad Ahmadi Daryakenari
Somayeh Sepehri
Behrooz Mosallanejad
Mahshid Ershadi
Mohammad Ahmadi Daryakenari
In situ growth of NiO nanostructures supported on nickel foam as an efficient electrocatalyst for oxygen evolution reaction
Nanochemistry Research
nio nanostructures
oxygen evolution reaction
thermal annealing
nickel foam
title In situ growth of NiO nanostructures supported on nickel foam as an efficient electrocatalyst for oxygen evolution reaction
title_full In situ growth of NiO nanostructures supported on nickel foam as an efficient electrocatalyst for oxygen evolution reaction
title_fullStr In situ growth of NiO nanostructures supported on nickel foam as an efficient electrocatalyst for oxygen evolution reaction
title_full_unstemmed In situ growth of NiO nanostructures supported on nickel foam as an efficient electrocatalyst for oxygen evolution reaction
title_short In situ growth of NiO nanostructures supported on nickel foam as an efficient electrocatalyst for oxygen evolution reaction
title_sort in situ growth of nio nanostructures supported on nickel foam as an efficient electrocatalyst for oxygen evolution reaction
topic nio nanostructures
oxygen evolution reaction
thermal annealing
nickel foam
url http://www.nanochemres.org/article_138037_a4fc2db6d9def978e8cc1e21da738e55.pdf
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