Zinc Amido-Oxazolinate Catalyzed Ring Opening Copolymerization and Terpolymerization of Maleic Anhydride and Epoxides
Ring opening copolymerization (ROCOP) of epoxides and cyclic anhydrides has become an attractive approach for the synthesis of biodegradable polyesters with various compositions. Encouraged by the efficiency and versatility of a series of amido-oxazolinate zinc complexes, in this study they were sho...
| Main Authors: | , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
MDPI AG
2020-09-01
|
| Series: | Molecules |
| Subjects: | |
| Online Access: | https://www.mdpi.com/1420-3049/25/18/4044 |
| _version_ | 1827706914812723200 |
|---|---|
| author | Muneer Shaik Vamshi K. Chidara Srinivas Abbina Guodong Du |
| author_facet | Muneer Shaik Vamshi K. Chidara Srinivas Abbina Guodong Du |
| author_sort | Muneer Shaik |
| collection | DOAJ |
| description | Ring opening copolymerization (ROCOP) of epoxides and cyclic anhydrides has become an attractive approach for the synthesis of biodegradable polyesters with various compositions. Encouraged by the efficiency and versatility of a series of amido-oxazolinate zinc complexes, in this study they were shown to be active catalysts for the synthesis of unsaturated polyesters via ROCOP of maleic anhydride and various epoxides. The relative activity of epoxides in these reactions was observed to be styrene oxide > cyclohexene oxide > phenyl glycidyl ether, which could be correlated with the electronic and steric features of the substrate. To provide more structural possibilities for the polyesters, the difference in epoxide reactivity was exploited in an attempt to prepare block terpolymers from one anhydride and two epoxides. Terpolymerization was carried out in one or two steps in a single pot. The thermal characterization by thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC) techniques suggested that the resulting materials were mostly random terpolymers. |
| first_indexed | 2024-03-10T16:34:25Z |
| format | Article |
| id | doaj.art-f08d008aa7fa4605b5b308af0f6db624 |
| institution | Directory Open Access Journal |
| issn | 1420-3049 |
| language | English |
| last_indexed | 2024-03-10T16:34:25Z |
| publishDate | 2020-09-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Molecules |
| spelling | doaj.art-f08d008aa7fa4605b5b308af0f6db6242023-11-20T12:35:32ZengMDPI AGMolecules1420-30492020-09-012518404410.3390/molecules25184044Zinc Amido-Oxazolinate Catalyzed Ring Opening Copolymerization and Terpolymerization of Maleic Anhydride and EpoxidesMuneer Shaik0Vamshi K. Chidara1Srinivas Abbina2Guodong Du3Department of Chemistry, University of North Dakota, 151 Cornell Street Stop 9024, Grand Forks, ND 58202, USADepartment of Chemistry, University of North Dakota, 151 Cornell Street Stop 9024, Grand Forks, ND 58202, USADepartment of Chemistry, University of North Dakota, 151 Cornell Street Stop 9024, Grand Forks, ND 58202, USADepartment of Chemistry, University of North Dakota, 151 Cornell Street Stop 9024, Grand Forks, ND 58202, USARing opening copolymerization (ROCOP) of epoxides and cyclic anhydrides has become an attractive approach for the synthesis of biodegradable polyesters with various compositions. Encouraged by the efficiency and versatility of a series of amido-oxazolinate zinc complexes, in this study they were shown to be active catalysts for the synthesis of unsaturated polyesters via ROCOP of maleic anhydride and various epoxides. The relative activity of epoxides in these reactions was observed to be styrene oxide > cyclohexene oxide > phenyl glycidyl ether, which could be correlated with the electronic and steric features of the substrate. To provide more structural possibilities for the polyesters, the difference in epoxide reactivity was exploited in an attempt to prepare block terpolymers from one anhydride and two epoxides. Terpolymerization was carried out in one or two steps in a single pot. The thermal characterization by thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC) techniques suggested that the resulting materials were mostly random terpolymers.https://www.mdpi.com/1420-3049/25/18/4044polyesterzinc catalysisring opening copolymerizationterpolymerizationmaleic anhydride |
| spellingShingle | Muneer Shaik Vamshi K. Chidara Srinivas Abbina Guodong Du Zinc Amido-Oxazolinate Catalyzed Ring Opening Copolymerization and Terpolymerization of Maleic Anhydride and Epoxides Molecules polyester zinc catalysis ring opening copolymerization terpolymerization maleic anhydride |
| title | Zinc Amido-Oxazolinate Catalyzed Ring Opening Copolymerization and Terpolymerization of Maleic Anhydride and Epoxides |
| title_full | Zinc Amido-Oxazolinate Catalyzed Ring Opening Copolymerization and Terpolymerization of Maleic Anhydride and Epoxides |
| title_fullStr | Zinc Amido-Oxazolinate Catalyzed Ring Opening Copolymerization and Terpolymerization of Maleic Anhydride and Epoxides |
| title_full_unstemmed | Zinc Amido-Oxazolinate Catalyzed Ring Opening Copolymerization and Terpolymerization of Maleic Anhydride and Epoxides |
| title_short | Zinc Amido-Oxazolinate Catalyzed Ring Opening Copolymerization and Terpolymerization of Maleic Anhydride and Epoxides |
| title_sort | zinc amido oxazolinate catalyzed ring opening copolymerization and terpolymerization of maleic anhydride and epoxides |
| topic | polyester zinc catalysis ring opening copolymerization terpolymerization maleic anhydride |
| url | https://www.mdpi.com/1420-3049/25/18/4044 |
| work_keys_str_mv | AT muneershaik zincamidooxazolinatecatalyzedringopeningcopolymerizationandterpolymerizationofmaleicanhydrideandepoxides AT vamshikchidara zincamidooxazolinatecatalyzedringopeningcopolymerizationandterpolymerizationofmaleicanhydrideandepoxides AT srinivasabbina zincamidooxazolinatecatalyzedringopeningcopolymerizationandterpolymerizationofmaleicanhydrideandepoxides AT guodongdu zincamidooxazolinatecatalyzedringopeningcopolymerizationandterpolymerizationofmaleicanhydrideandepoxides |