Interfacial Chemistry and Catalysis of Inorganic Materials

Heterogeneous catalysis is essential to most industrial chemical processes. To achieve a better sustainability of these processes we need highly efficient and highly selective catalysts that are based on earth-abundant materials rather than the more conventional noble metals. Here, we discuss the po...

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Main Authors: Tzu-Chin Chang Chien, Murielle F. Delley
Format: Article
Language:deu
Published: Swiss Chemical Society 2024-02-01
Series:CHIMIA
Subjects:
Online Access:https://www.chimia.ch/chimia/article/view/7170
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author Tzu-Chin Chang Chien
Murielle F. Delley
author_facet Tzu-Chin Chang Chien
Murielle F. Delley
author_sort Tzu-Chin Chang Chien
collection DOAJ
description Heterogeneous catalysis is essential to most industrial chemical processes. To achieve a better sustainability of these processes we need highly efficient and highly selective catalysts that are based on earth-abundant materials rather than the more conventional noble metals. Here, we discuss the potential of inorganic materials as catalysts for chemical transformations focusing in particular on the promising transition metal phosphides and sulfides. We describe our recent and current efforts to understand the interfacial chemistry of these materials that governs catalysis, and to tune catalytic reactivity by controlled chemical modification of the material surfaces and by use of interfacial electric fields.
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spelling doaj.art-f08e9f1ff7af46b2afa8441287a9fc362024-02-28T02:07:51ZdeuSwiss Chemical SocietyCHIMIA0009-42932673-24242024-02-01781/210.2533/chimia.2024.7Interfacial Chemistry and Catalysis of Inorganic MaterialsTzu-Chin Chang Chien0Murielle F. Delley1University of Basel, Department of Chemistry, Mattenstrasse 22, CH-4002 BaselUniversity of Basel, Department of Chemistry, Mattenstrasse 22, CH-4002 BaselHeterogeneous catalysis is essential to most industrial chemical processes. To achieve a better sustainability of these processes we need highly efficient and highly selective catalysts that are based on earth-abundant materials rather than the more conventional noble metals. Here, we discuss the potential of inorganic materials as catalysts for chemical transformations focusing in particular on the promising transition metal phosphides and sulfides. We describe our recent and current efforts to understand the interfacial chemistry of these materials that governs catalysis, and to tune catalytic reactivity by controlled chemical modification of the material surfaces and by use of interfacial electric fields.https://www.chimia.ch/chimia/article/view/7170Chemical surface modificationHeterogeneous catalysisInterfacial electric fieldSurface chemistryTransition metal phosphidesTransition metal sulfides
spellingShingle Tzu-Chin Chang Chien
Murielle F. Delley
Interfacial Chemistry and Catalysis of Inorganic Materials
CHIMIA
Chemical surface modification
Heterogeneous catalysis
Interfacial electric field
Surface chemistry
Transition metal phosphides
Transition metal sulfides
title Interfacial Chemistry and Catalysis of Inorganic Materials
title_full Interfacial Chemistry and Catalysis of Inorganic Materials
title_fullStr Interfacial Chemistry and Catalysis of Inorganic Materials
title_full_unstemmed Interfacial Chemistry and Catalysis of Inorganic Materials
title_short Interfacial Chemistry and Catalysis of Inorganic Materials
title_sort interfacial chemistry and catalysis of inorganic materials
topic Chemical surface modification
Heterogeneous catalysis
Interfacial electric field
Surface chemistry
Transition metal phosphides
Transition metal sulfides
url https://www.chimia.ch/chimia/article/view/7170
work_keys_str_mv AT tzuchinchangchien interfacialchemistryandcatalysisofinorganicmaterials
AT muriellefdelley interfacialchemistryandcatalysisofinorganicmaterials