Crystal structure of (E)-1-(1-hydroxynaphthalen-2-yl)-3-(2,3,4-trimethoxyphenyl)prop-2-en-1-one
The title compound, C22H20O5, is composed of a hydroxynaphthyl ring and a trimethoxyphenyl ring [the planes of which are inclined to one another by 21.61 (10)°] bridged by an unsaturated prop-2-en-1-one group. The mean plane of the prop-2-en-1-one group [–C(=O)—C=C–] is inclined to that of the napht...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2015-08-01
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| Series: | Acta Crystallographica Section E: Crystallographic Communications |
| Subjects: | |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S2056989015013870 |
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| author | J. Srividya D. Reuben Jonathan B. K. Revathi G. Anbalagan |
| author_facet | J. Srividya D. Reuben Jonathan B. K. Revathi G. Anbalagan |
| author_sort | J. Srividya |
| collection | DOAJ |
| description | The title compound, C22H20O5, is composed of a hydroxynaphthyl ring and a trimethoxyphenyl ring [the planes of which are inclined to one another by 21.61 (10)°] bridged by an unsaturated prop-2-en-1-one group. The mean plane of the prop-2-en-1-one group [–C(=O)—C=C–] is inclined to that of the naphthyl system and benzene rings by 3.77 (14) and 18.01 (16)°, respectively. There is an intramolecular O—H...O hydrogen bond present forming an S(6) ring motif. In the crystal, inversion-related molecules are linked by a slipped-parallel π–π interaction [intercentroid distance = 3.8942 (13) Å, interplanar distance = 3.478 (9) Å and slippage = 1.751 Å], and stack along the [101] direction. There are no other significant intermolecular interactions present. |
| first_indexed | 2024-12-24T04:22:28Z |
| format | Article |
| id | doaj.art-f09f5d099b2e437bbed9edce6f41ae11 |
| institution | Directory Open Access Journal |
| issn | 2056-9890 |
| language | English |
| last_indexed | 2024-12-24T04:22:28Z |
| publishDate | 2015-08-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E: Crystallographic Communications |
| spelling | doaj.art-f09f5d099b2e437bbed9edce6f41ae112022-12-21T17:15:47ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902015-08-01718o610o61110.1107/S2056989015013870su5174Crystal structure of (E)-1-(1-hydroxynaphthalen-2-yl)-3-(2,3,4-trimethoxyphenyl)prop-2-en-1-oneJ. Srividya0D. Reuben Jonathan1B. K. Revathi2G. Anbalagan3PG and Research Department of Physics, Queen Mary's College, Chennai 600 004, IndiaDepartment of Chemistry, Madras Christian College, Chennai-59, IndiaPG and Research Department of Physics, Queen Mary's College, Chennai 600 004, IndiaPG and Research Department of Physics, Presidency College, University of Madras, Chennai 600 005, IndiaThe title compound, C22H20O5, is composed of a hydroxynaphthyl ring and a trimethoxyphenyl ring [the planes of which are inclined to one another by 21.61 (10)°] bridged by an unsaturated prop-2-en-1-one group. The mean plane of the prop-2-en-1-one group [–C(=O)—C=C–] is inclined to that of the naphthyl system and benzene rings by 3.77 (14) and 18.01 (16)°, respectively. There is an intramolecular O—H...O hydrogen bond present forming an S(6) ring motif. In the crystal, inversion-related molecules are linked by a slipped-parallel π–π interaction [intercentroid distance = 3.8942 (13) Å, interplanar distance = 3.478 (9) Å and slippage = 1.751 Å], and stack along the [101] direction. There are no other significant intermolecular interactions present.http://scripts.iucr.org/cgi-bin/paper?S2056989015013870crystal structurechalconeshydroxynaphthaleneO—H...O hydrogen bondS(6) ring motifπ–π slipped parallel interaction |
| spellingShingle | J. Srividya D. Reuben Jonathan B. K. Revathi G. Anbalagan Crystal structure of (E)-1-(1-hydroxynaphthalen-2-yl)-3-(2,3,4-trimethoxyphenyl)prop-2-en-1-one Acta Crystallographica Section E: Crystallographic Communications crystal structure chalcones hydroxynaphthalene O—H...O hydrogen bond S(6) ring motif π–π slipped parallel interaction |
| title | Crystal structure of (E)-1-(1-hydroxynaphthalen-2-yl)-3-(2,3,4-trimethoxyphenyl)prop-2-en-1-one |
| title_full | Crystal structure of (E)-1-(1-hydroxynaphthalen-2-yl)-3-(2,3,4-trimethoxyphenyl)prop-2-en-1-one |
| title_fullStr | Crystal structure of (E)-1-(1-hydroxynaphthalen-2-yl)-3-(2,3,4-trimethoxyphenyl)prop-2-en-1-one |
| title_full_unstemmed | Crystal structure of (E)-1-(1-hydroxynaphthalen-2-yl)-3-(2,3,4-trimethoxyphenyl)prop-2-en-1-one |
| title_short | Crystal structure of (E)-1-(1-hydroxynaphthalen-2-yl)-3-(2,3,4-trimethoxyphenyl)prop-2-en-1-one |
| title_sort | crystal structure of e 1 1 hydroxynaphthalen 2 yl 3 2 3 4 trimethoxyphenyl prop 2 en 1 one |
| topic | crystal structure chalcones hydroxynaphthalene O—H...O hydrogen bond S(6) ring motif π–π slipped parallel interaction |
| url | http://scripts.iucr.org/cgi-bin/paper?S2056989015013870 |
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