Synthesis, Optical and Photocatalytic Properties of ZnSe Microspheres/Nanosheets
The microspheres/nanosheets of the ZnSe were prepared by solvothermal route. The morphological, structural, optical, as well as photocatalytic properties of the ZnSe products were studied. SEM and TEM results showed that morphologies of the products were sensitive to the presence of water or not, an...
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Format: | Article |
Language: | English |
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Tsinghua University Press
2011-06-01
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Series: | Nano Biomedicine and Engineering |
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Online Access: | https://www.sciopen.com/article/10.5101/nbe.v3i2.p107-114 |
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author | Yongqiang Yang Yan Zhang Xuejiao Zhou Xiaochen Wu Sizhe Xu Haixia Wu Shouwu Guo |
author_facet | Yongqiang Yang Yan Zhang Xuejiao Zhou Xiaochen Wu Sizhe Xu Haixia Wu Shouwu Guo |
author_sort | Yongqiang Yang |
collection | DOAJ |
description | The microspheres/nanosheets of the ZnSe were prepared by solvothermal route. The morphological, structural, optical, as well as photocatalytic properties of the ZnSe products were studied. SEM and TEM results showed that morphologies of the products were sensitive to the presence of water or not, and a mechanism was proposed. The products shows a weak blue emission band centered at 476 nm, which is attributed to the near-bandedge emission of the products, and the strong and broad peak at 520 nm is attributed to a defect-related emission. The PL and XRD results indicate that ZnSe microspheres have high crystalline and few defects compared with ZnSe nanosheets, the degradation for Rhodamine 6G shows that the photoactivity of ZnSe nanosheets is nearly twice that of ZnSe microspheres. Therefore, the decrease of defects implies the decrease of photocatalytic activity, and nanosheets is more suitable for the degradation of Rhodamine 6G. |
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spelling | doaj.art-f0ac506de8af437193292aadb5f80d8b2024-10-02T20:26:16ZengTsinghua University PressNano Biomedicine and Engineering2150-55782011-06-013210711410.5101/nbe.v3i2.p107-114Synthesis, Optical and Photocatalytic Properties of ZnSe Microspheres/NanosheetsYongqiang Yang0Yan Zhang1Xuejiao Zhou2Xiaochen Wu3Sizhe Xu4Haixia Wu5Shouwu Guo6National Key Laboratory of Micro/Nano Fabrication Technology, Key Laboratory for Thin Film and Microfabrication of the Ministry of Education, Research Institute of Micro/Nano Science and Technology, Shanghai Jiao Tong University, Shanghai 200240, ChinaNational Key Laboratory of Micro/Nano Fabrication Technology, Key Laboratory for Thin Film and Microfabrication of the Ministry of Education, Research Institute of Micro/Nano Science and Technology, Shanghai Jiao Tong University, Shanghai 200240, ChinaNational Key Laboratory of Micro/Nano Fabrication Technology, Key Laboratory for Thin Film and Microfabrication of the Ministry of Education, Research Institute of Micro/Nano Science and Technology, Shanghai Jiao Tong University, Shanghai 200240, ChinaNational Key Laboratory of Micro/Nano Fabrication Technology, Key Laboratory for Thin Film and Microfabrication of the Ministry of Education, Research Institute of Micro/Nano Science and Technology, Shanghai Jiao Tong University, Shanghai 200240, ChinaNational Key Laboratory of Micro/Nano Fabrication Technology, Key Laboratory for Thin Film and Microfabrication of the Ministry of Education, Research Institute of Micro/Nano Science and Technology, Shanghai Jiao Tong University, Shanghai 200240, ChinaNational Key Laboratory of Micro/Nano Fabrication Technology, Key Laboratory for Thin Film and Microfabrication of the Ministry of Education, Research Institute of Micro/Nano Science and Technology, Shanghai Jiao Tong University, Shanghai 200240, ChinaNational Key Laboratory of Micro/Nano Fabrication Technology, Key Laboratory for Thin Film and Microfabrication of the Ministry of Education, Research Institute of Micro/Nano Science and Technology, Shanghai Jiao Tong University, Shanghai 200240, ChinaThe microspheres/nanosheets of the ZnSe were prepared by solvothermal route. The morphological, structural, optical, as well as photocatalytic properties of the ZnSe products were studied. SEM and TEM results showed that morphologies of the products were sensitive to the presence of water or not, and a mechanism was proposed. The products shows a weak blue emission band centered at 476 nm, which is attributed to the near-bandedge emission of the products, and the strong and broad peak at 520 nm is attributed to a defect-related emission. The PL and XRD results indicate that ZnSe microspheres have high crystalline and few defects compared with ZnSe nanosheets, the degradation for Rhodamine 6G shows that the photoactivity of ZnSe nanosheets is nearly twice that of ZnSe microspheres. Therefore, the decrease of defects implies the decrease of photocatalytic activity, and nanosheets is more suitable for the degradation of Rhodamine 6G.https://www.sciopen.com/article/10.5101/nbe.v3i2.p107-114znsemicrospheresnanosheetsphotoluminescencephotocatalytic |
spellingShingle | Yongqiang Yang Yan Zhang Xuejiao Zhou Xiaochen Wu Sizhe Xu Haixia Wu Shouwu Guo Synthesis, Optical and Photocatalytic Properties of ZnSe Microspheres/Nanosheets Nano Biomedicine and Engineering znse microspheres nanosheets photoluminescence photocatalytic |
title | Synthesis, Optical and Photocatalytic Properties of ZnSe Microspheres/Nanosheets |
title_full | Synthesis, Optical and Photocatalytic Properties of ZnSe Microspheres/Nanosheets |
title_fullStr | Synthesis, Optical and Photocatalytic Properties of ZnSe Microspheres/Nanosheets |
title_full_unstemmed | Synthesis, Optical and Photocatalytic Properties of ZnSe Microspheres/Nanosheets |
title_short | Synthesis, Optical and Photocatalytic Properties of ZnSe Microspheres/Nanosheets |
title_sort | synthesis optical and photocatalytic properties of znse microspheres nanosheets |
topic | znse microspheres nanosheets photoluminescence photocatalytic |
url | https://www.sciopen.com/article/10.5101/nbe.v3i2.p107-114 |
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