Synthesis, Optical and Photocatalytic Properties of ZnSe Microspheres/Nanosheets

The microspheres/nanosheets of the ZnSe were prepared by solvothermal route. The morphological, structural, optical, as well as photocatalytic properties of the ZnSe products were studied. SEM and TEM results showed that morphologies of the products were sensitive to the presence of water or not, an...

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Main Authors: Yongqiang Yang, Yan Zhang, Xuejiao Zhou, Xiaochen Wu, Sizhe Xu, Haixia Wu, Shouwu Guo
Format: Article
Language:English
Published: Tsinghua University Press 2011-06-01
Series:Nano Biomedicine and Engineering
Subjects:
Online Access:https://www.sciopen.com/article/10.5101/nbe.v3i2.p107-114
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author Yongqiang Yang
Yan Zhang
Xuejiao Zhou
Xiaochen Wu
Sizhe Xu
Haixia Wu
Shouwu Guo
author_facet Yongqiang Yang
Yan Zhang
Xuejiao Zhou
Xiaochen Wu
Sizhe Xu
Haixia Wu
Shouwu Guo
author_sort Yongqiang Yang
collection DOAJ
description The microspheres/nanosheets of the ZnSe were prepared by solvothermal route. The morphological, structural, optical, as well as photocatalytic properties of the ZnSe products were studied. SEM and TEM results showed that morphologies of the products were sensitive to the presence of water or not, and a mechanism was proposed. The products shows a weak blue emission band centered at 476 nm, which is attributed to the near-bandedge emission of the products, and the strong and broad peak at 520 nm is attributed to a defect-related emission. The PL and XRD results indicate that ZnSe microspheres have high crystalline and few defects compared with ZnSe nanosheets, the degradation for Rhodamine 6G shows that the photoactivity of ZnSe nanosheets is nearly twice that of ZnSe microspheres. Therefore, the decrease of defects implies the decrease of photocatalytic activity, and nanosheets is more suitable for the degradation of Rhodamine 6G.
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spelling doaj.art-f0ac506de8af437193292aadb5f80d8b2024-10-02T20:26:16ZengTsinghua University PressNano Biomedicine and Engineering2150-55782011-06-013210711410.5101/nbe.v3i2.p107-114Synthesis, Optical and Photocatalytic Properties of ZnSe Microspheres/NanosheetsYongqiang Yang0Yan Zhang1Xuejiao Zhou2Xiaochen Wu3Sizhe Xu4Haixia Wu5Shouwu Guo6National Key Laboratory of Micro/Nano Fabrication Technology, Key Laboratory for Thin Film and Microfabrication of the Ministry of Education, Research Institute of Micro/Nano Science and Technology, Shanghai Jiao Tong University, Shanghai 200240, ChinaNational Key Laboratory of Micro/Nano Fabrication Technology, Key Laboratory for Thin Film and Microfabrication of the Ministry of Education, Research Institute of Micro/Nano Science and Technology, Shanghai Jiao Tong University, Shanghai 200240, ChinaNational Key Laboratory of Micro/Nano Fabrication Technology, Key Laboratory for Thin Film and Microfabrication of the Ministry of Education, Research Institute of Micro/Nano Science and Technology, Shanghai Jiao Tong University, Shanghai 200240, ChinaNational Key Laboratory of Micro/Nano Fabrication Technology, Key Laboratory for Thin Film and Microfabrication of the Ministry of Education, Research Institute of Micro/Nano Science and Technology, Shanghai Jiao Tong University, Shanghai 200240, ChinaNational Key Laboratory of Micro/Nano Fabrication Technology, Key Laboratory for Thin Film and Microfabrication of the Ministry of Education, Research Institute of Micro/Nano Science and Technology, Shanghai Jiao Tong University, Shanghai 200240, ChinaNational Key Laboratory of Micro/Nano Fabrication Technology, Key Laboratory for Thin Film and Microfabrication of the Ministry of Education, Research Institute of Micro/Nano Science and Technology, Shanghai Jiao Tong University, Shanghai 200240, ChinaNational Key Laboratory of Micro/Nano Fabrication Technology, Key Laboratory for Thin Film and Microfabrication of the Ministry of Education, Research Institute of Micro/Nano Science and Technology, Shanghai Jiao Tong University, Shanghai 200240, ChinaThe microspheres/nanosheets of the ZnSe were prepared by solvothermal route. The morphological, structural, optical, as well as photocatalytic properties of the ZnSe products were studied. SEM and TEM results showed that morphologies of the products were sensitive to the presence of water or not, and a mechanism was proposed. The products shows a weak blue emission band centered at 476 nm, which is attributed to the near-bandedge emission of the products, and the strong and broad peak at 520 nm is attributed to a defect-related emission. The PL and XRD results indicate that ZnSe microspheres have high crystalline and few defects compared with ZnSe nanosheets, the degradation for Rhodamine 6G shows that the photoactivity of ZnSe nanosheets is nearly twice that of ZnSe microspheres. Therefore, the decrease of defects implies the decrease of photocatalytic activity, and nanosheets is more suitable for the degradation of Rhodamine 6G.https://www.sciopen.com/article/10.5101/nbe.v3i2.p107-114znsemicrospheresnanosheetsphotoluminescencephotocatalytic
spellingShingle Yongqiang Yang
Yan Zhang
Xuejiao Zhou
Xiaochen Wu
Sizhe Xu
Haixia Wu
Shouwu Guo
Synthesis, Optical and Photocatalytic Properties of ZnSe Microspheres/Nanosheets
Nano Biomedicine and Engineering
znse
microspheres
nanosheets
photoluminescence
photocatalytic
title Synthesis, Optical and Photocatalytic Properties of ZnSe Microspheres/Nanosheets
title_full Synthesis, Optical and Photocatalytic Properties of ZnSe Microspheres/Nanosheets
title_fullStr Synthesis, Optical and Photocatalytic Properties of ZnSe Microspheres/Nanosheets
title_full_unstemmed Synthesis, Optical and Photocatalytic Properties of ZnSe Microspheres/Nanosheets
title_short Synthesis, Optical and Photocatalytic Properties of ZnSe Microspheres/Nanosheets
title_sort synthesis optical and photocatalytic properties of znse microspheres nanosheets
topic znse
microspheres
nanosheets
photoluminescence
photocatalytic
url https://www.sciopen.com/article/10.5101/nbe.v3i2.p107-114
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