Crystal structure of (E)-1(anthracen-9-ylmethylidene)[2-(morpholin-4-yl)ethyl]amine
The title compound, C21H22N2O, crystallizes with two independent molecules in the asymmetric unit. In both molecules, the anthracene ring systems are almost planar, with maximum deviations of 0.071 (8) and 0.028 (7) Å, and make dihedral angles of 73.4 (2) and 73.3 (2)° with the least-squares planes...
| Main Authors: | , , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2014-09-01
|
| Series: | Acta Crystallographica Section E |
| Subjects: | |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536814018807 |
| _version_ | 1828425029082152960 |
|---|---|
| author | Zeliha Atioğlu Mehmet Akkurt Aliasghar Jarrahpour Mehdi Mohammadi Chermahini Orhan Büyükgüngör |
| author_facet | Zeliha Atioğlu Mehmet Akkurt Aliasghar Jarrahpour Mehdi Mohammadi Chermahini Orhan Büyükgüngör |
| author_sort | Zeliha Atioğlu |
| collection | DOAJ |
| description | The title compound, C21H22N2O, crystallizes with two independent molecules in the asymmetric unit. In both molecules, the anthracene ring systems are almost planar, with maximum deviations of 0.071 (8) and 0.028 (7) Å, and make dihedral angles of 73.4 (2) and 73.3 (2)° with the least-squares planes formed by the four C atoms of the morpholine rings, which adopt a chair conformation. An intramolecular C—H...π interaction occurs. In the crystal, the packing is stabilized by weak C—H...O hydrogen bonds, which connect pairs of molecules into parallel to the c axis, and C—H...π interactions. |
| first_indexed | 2024-12-10T16:25:24Z |
| format | Article |
| id | doaj.art-f0b1ab9035cc44a2968e4d88b4db4511 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-10T16:25:24Z |
| publishDate | 2014-09-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-f0b1ab9035cc44a2968e4d88b4db45112022-12-22T01:41:41ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682014-09-01709o1045o104610.1107/S1600536814018807xu5815Crystal structure of (E)-1(anthracen-9-ylmethylidene)[2-(morpholin-4-yl)ethyl]amineZeliha Atioğlu0Mehmet Akkurt1Aliasghar Jarrahpour2Mehdi Mohammadi Chermahini3Orhan Büyükgüngör4İlke Education and Health Foundation, Cappadocia Vocational College, The Medical Imaging Techniques Program, 50420 Mustafapaşa, Ürgüp, Nevşehir, TurkeyDepartment of Physics, Faculty of Sciences, Erciyes University, 38039 Kayseri, TurkeyDepartment of Chemistry, College of Sciences, Shiraz University, 71454 Shiraz, IranDepartment of Chemistry, College of Sciences, Shiraz University, 71454 Shiraz, IranDepartment of Physics, Faculty of Arts and Sciences, Ondokuz Mayıs University, 55139 Samsun, TurkeyThe title compound, C21H22N2O, crystallizes with two independent molecules in the asymmetric unit. In both molecules, the anthracene ring systems are almost planar, with maximum deviations of 0.071 (8) and 0.028 (7) Å, and make dihedral angles of 73.4 (2) and 73.3 (2)° with the least-squares planes formed by the four C atoms of the morpholine rings, which adopt a chair conformation. An intramolecular C—H...π interaction occurs. In the crystal, the packing is stabilized by weak C—H...O hydrogen bonds, which connect pairs of molecules into parallel to the c axis, and C—H...π interactions.http://scripts.iucr.org/cgi-bin/paper?S1600536814018807crystal structureC—H...π interactionsSchiff basesanthracenemorpholinemethanimine |
| spellingShingle | Zeliha Atioğlu Mehmet Akkurt Aliasghar Jarrahpour Mehdi Mohammadi Chermahini Orhan Büyükgüngör Crystal structure of (E)-1(anthracen-9-ylmethylidene)[2-(morpholin-4-yl)ethyl]amine Acta Crystallographica Section E crystal structure C—H...π interactions Schiff bases anthracene morpholine methanimine |
| title | Crystal structure of (E)-1(anthracen-9-ylmethylidene)[2-(morpholin-4-yl)ethyl]amine |
| title_full | Crystal structure of (E)-1(anthracen-9-ylmethylidene)[2-(morpholin-4-yl)ethyl]amine |
| title_fullStr | Crystal structure of (E)-1(anthracen-9-ylmethylidene)[2-(morpholin-4-yl)ethyl]amine |
| title_full_unstemmed | Crystal structure of (E)-1(anthracen-9-ylmethylidene)[2-(morpholin-4-yl)ethyl]amine |
| title_short | Crystal structure of (E)-1(anthracen-9-ylmethylidene)[2-(morpholin-4-yl)ethyl]amine |
| title_sort | crystal structure of e 1 anthracen 9 ylmethylidene 2 morpholin 4 yl ethyl amine |
| topic | crystal structure C—H...π interactions Schiff bases anthracene morpholine methanimine |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536814018807 |
| work_keys_str_mv | AT zelihaatioglu crystalstructureofe1anthracen9ylmethylidene2morpholin4ylethylamine AT mehmetakkurt crystalstructureofe1anthracen9ylmethylidene2morpholin4ylethylamine AT aliasgharjarrahpour crystalstructureofe1anthracen9ylmethylidene2morpholin4ylethylamine AT mehdimohammadichermahini crystalstructureofe1anthracen9ylmethylidene2morpholin4ylethylamine AT orhanbuyukgungor crystalstructureofe1anthracen9ylmethylidene2morpholin4ylethylamine |