Solvothermal synthesis and thermoelectric properties of indium telluride nanostring-cluster hierarchical structures

<p>Abstract</p> <p>A simple solvothermal approach has been developed to successfully synthesize n-type &#945;-In<sub>2</sub>Te<sub>3 </sub>thermoelectric nanomaterials. The nanostring-cluster hierarchical structures were prepared using In(NO<sub>3&...

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Main Authors: Zhang Haiqian, Tai Guo&apos;an, Miao Chunyang, Wang Yubo, Bai Yunrui, Guo Wanlin
Format: Article
Language:English
Published: SpringerOpen 2011-01-01
Series:Nanoscale Research Letters
Online Access:http://www.nanoscalereslett.com/content/6/1/329
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author Zhang Haiqian
Tai Guo&apos;an
Miao Chunyang
Wang Yubo
Bai Yunrui
Guo Wanlin
author_facet Zhang Haiqian
Tai Guo&apos;an
Miao Chunyang
Wang Yubo
Bai Yunrui
Guo Wanlin
author_sort Zhang Haiqian
collection DOAJ
description <p>Abstract</p> <p>A simple solvothermal approach has been developed to successfully synthesize n-type &#945;-In<sub>2</sub>Te<sub>3 </sub>thermoelectric nanomaterials. The nanostring-cluster hierarchical structures were prepared using In(NO<sub>3</sub>)<sub>3 </sub>and Na<sub>2</sub>TeO<sub>3 </sub>as the reactants in a mixed solvent of ethylenediamine and ethylene glycol at 200&#176;C for 24 h. A diffusion-limited reaction mechanism was proposed to explain the formation of the hierarchical structures. The Seebeck coefficient of the bulk pellet pressed by the obtained samples exhibits 43% enhancement over that of the corresponding thin film at room temperature. The electrical conductivity of the bulk pellet is one to four orders of magnitude higher than that of the corresponding thin film or p-type bulk sample. The synthetic route can be applied to obtain other low-dimensional semiconducting telluride nanostructures.</p> <p>PACS: 65.80.-g, 68.35.bg, 68.35.bt</p>
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spelling doaj.art-f0ddba71ed464b3da2d09867ebee0fa82023-08-02T04:46:42ZengSpringerOpenNanoscale Research Letters1931-75731556-276X2011-01-0161329Solvothermal synthesis and thermoelectric properties of indium telluride nanostring-cluster hierarchical structuresZhang HaiqianTai Guo&apos;anMiao ChunyangWang YuboBai YunruiGuo Wanlin<p>Abstract</p> <p>A simple solvothermal approach has been developed to successfully synthesize n-type &#945;-In<sub>2</sub>Te<sub>3 </sub>thermoelectric nanomaterials. The nanostring-cluster hierarchical structures were prepared using In(NO<sub>3</sub>)<sub>3 </sub>and Na<sub>2</sub>TeO<sub>3 </sub>as the reactants in a mixed solvent of ethylenediamine and ethylene glycol at 200&#176;C for 24 h. A diffusion-limited reaction mechanism was proposed to explain the formation of the hierarchical structures. The Seebeck coefficient of the bulk pellet pressed by the obtained samples exhibits 43% enhancement over that of the corresponding thin film at room temperature. The electrical conductivity of the bulk pellet is one to four orders of magnitude higher than that of the corresponding thin film or p-type bulk sample. The synthetic route can be applied to obtain other low-dimensional semiconducting telluride nanostructures.</p> <p>PACS: 65.80.-g, 68.35.bg, 68.35.bt</p>http://www.nanoscalereslett.com/content/6/1/329
spellingShingle Zhang Haiqian
Tai Guo&apos;an
Miao Chunyang
Wang Yubo
Bai Yunrui
Guo Wanlin
Solvothermal synthesis and thermoelectric properties of indium telluride nanostring-cluster hierarchical structures
Nanoscale Research Letters
title Solvothermal synthesis and thermoelectric properties of indium telluride nanostring-cluster hierarchical structures
title_full Solvothermal synthesis and thermoelectric properties of indium telluride nanostring-cluster hierarchical structures
title_fullStr Solvothermal synthesis and thermoelectric properties of indium telluride nanostring-cluster hierarchical structures
title_full_unstemmed Solvothermal synthesis and thermoelectric properties of indium telluride nanostring-cluster hierarchical structures
title_short Solvothermal synthesis and thermoelectric properties of indium telluride nanostring-cluster hierarchical structures
title_sort solvothermal synthesis and thermoelectric properties of indium telluride nanostring cluster hierarchical structures
url http://www.nanoscalereslett.com/content/6/1/329
work_keys_str_mv AT zhanghaiqian solvothermalsynthesisandthermoelectricpropertiesofindiumtelluridenanostringclusterhierarchicalstructures
AT taiguoaposan solvothermalsynthesisandthermoelectricpropertiesofindiumtelluridenanostringclusterhierarchicalstructures
AT miaochunyang solvothermalsynthesisandthermoelectricpropertiesofindiumtelluridenanostringclusterhierarchicalstructures
AT wangyubo solvothermalsynthesisandthermoelectricpropertiesofindiumtelluridenanostringclusterhierarchicalstructures
AT baiyunrui solvothermalsynthesisandthermoelectricpropertiesofindiumtelluridenanostringclusterhierarchicalstructures
AT guowanlin solvothermalsynthesisandthermoelectricpropertiesofindiumtelluridenanostringclusterhierarchicalstructures