Characterization of Shallow Groundwater Circulation Based on Chemical Kinetics: A Case Study of Xiong’an New Area, China

Xiong’an New Area, located in the middle of the North China Plain, will have been built as a “city of the future.” Urban planning and construction need to comprehensively consider the constraints of hydrogeological conditions such as aquifer structure and parameters. As the main aquifer in this area...

Full description

Bibliographic Details
Main Authors: Yubo Xia, Haitao Li, Bing Wang, Zhen Ma, Xu Guo, Kai Zhao, Changrong Zhao
Format: Article
Language:English
Published: MDPI AG 2022-06-01
Series:Water
Subjects:
Online Access:https://www.mdpi.com/2073-4441/14/12/1880
_version_ 1797481322238705664
author Yubo Xia
Haitao Li
Bing Wang
Zhen Ma
Xu Guo
Kai Zhao
Changrong Zhao
author_facet Yubo Xia
Haitao Li
Bing Wang
Zhen Ma
Xu Guo
Kai Zhao
Changrong Zhao
author_sort Yubo Xia
collection DOAJ
description Xiong’an New Area, located in the middle of the North China Plain, will have been built as a “city of the future.” Urban planning and construction need to comprehensively consider the constraints of hydrogeological conditions such as aquifer structure and parameters. As the main aquifer in this area, the paleo-channel is heterogeneous and anisotropic, and the two-dimensional hydraulic conductivity in each horizontal direction cannot be obtained from aquifer tests. Therefore, this study adopts a chemical kinetics method to calculate the ionic activity and mineral saturation indices of shallow groundwater, determine the groundwater chemical potential field, and construct a horizontal two-dimensional groundwater chemical kinetics model. This model is used to calculate the hydraulic conductivity, flow rate and retention time of groundwater in areas of different chemical kinetics, as well as evaluate horizontal heterogeneity of the Quaternary paleo-channel aquifer. The results indicate that the groundwater chemical potential field can reflect the characteristics of the groundwater seepage field in each horizontal direction. The paleo-channel is the main channel of groundwater circulation, which shows the statistical difference of its permeability. Alluvial and lacustrine strata affect groundwater circulation due to their different hydrogeological structures and permeability. The groundwater chemical kinetics results of hydraulic conductivity along the paleo-channel are approximately consistent with traditional hydrogeological calculation results derived from aquifer test data. Hydraulic conductivity is higher in the extension direction of the paleo-channel, and lower if the path crosscuts multiple paleo-channels. This feature can be used to build a hydrogeological structure model combined with drilling data. Furthermore, excessive groundwater exploitation will change the actual flow rate and retention time of groundwater, thereby affecting the groundwater circulation conditions. This study of groundwater circulation in Xiong’an New Area by means of chemical kinetics makes up for the deficiency in the study of the unconsolidated sedimentary aquifer anisotropy within the paleo-channel.
first_indexed 2024-03-09T22:12:52Z
format Article
id doaj.art-f1069aecfc55406cbff6de910b32a62f
institution Directory Open Access Journal
issn 2073-4441
language English
last_indexed 2024-03-09T22:12:52Z
publishDate 2022-06-01
publisher MDPI AG
record_format Article
series Water
spelling doaj.art-f1069aecfc55406cbff6de910b32a62f2023-11-23T19:29:00ZengMDPI AGWater2073-44412022-06-011412188010.3390/w14121880Characterization of Shallow Groundwater Circulation Based on Chemical Kinetics: A Case Study of Xiong’an New Area, ChinaYubo Xia0Haitao Li1Bing Wang2Zhen Ma3Xu Guo4Kai Zhao5Changrong Zhao6Tianjin Center China Geological Survey (CGS), Tianjin 300170, ChinaChina Institute of Geo-Environment Monitoring, Beijing 100081, ChinaTianjin Geothermal Exploration and Development-Designing Institute, Tianjin 300250, ChinaTianjin Center China Geological Survey (CGS), Tianjin 300170, ChinaTianjin Center China Geological Survey (CGS), Tianjin 300170, ChinaChina Institute of Geo-Environment Monitoring, Beijing 100081, ChinaTianjin Center China Geological Survey (CGS), Tianjin 300170, ChinaXiong’an New Area, located in the middle of the North China Plain, will have been built as a “city of the future.” Urban planning and construction need to comprehensively consider the constraints of hydrogeological conditions such as aquifer structure and parameters. As the main aquifer in this area, the paleo-channel is heterogeneous and anisotropic, and the two-dimensional hydraulic conductivity in each horizontal direction cannot be obtained from aquifer tests. Therefore, this study adopts a chemical kinetics method to calculate the ionic activity and mineral saturation indices of shallow groundwater, determine the groundwater chemical potential field, and construct a horizontal two-dimensional groundwater chemical kinetics model. This model is used to calculate the hydraulic conductivity, flow rate and retention time of groundwater in areas of different chemical kinetics, as well as evaluate horizontal heterogeneity of the Quaternary paleo-channel aquifer. The results indicate that the groundwater chemical potential field can reflect the characteristics of the groundwater seepage field in each horizontal direction. The paleo-channel is the main channel of groundwater circulation, which shows the statistical difference of its permeability. Alluvial and lacustrine strata affect groundwater circulation due to their different hydrogeological structures and permeability. The groundwater chemical kinetics results of hydraulic conductivity along the paleo-channel are approximately consistent with traditional hydrogeological calculation results derived from aquifer test data. Hydraulic conductivity is higher in the extension direction of the paleo-channel, and lower if the path crosscuts multiple paleo-channels. This feature can be used to build a hydrogeological structure model combined with drilling data. Furthermore, excessive groundwater exploitation will change the actual flow rate and retention time of groundwater, thereby affecting the groundwater circulation conditions. This study of groundwater circulation in Xiong’an New Area by means of chemical kinetics makes up for the deficiency in the study of the unconsolidated sedimentary aquifer anisotropy within the paleo-channel.https://www.mdpi.com/2073-4441/14/12/1880chemical kineticsmineral saturation indexhydraulic conductivityheterogeneityXiong’an New Area
spellingShingle Yubo Xia
Haitao Li
Bing Wang
Zhen Ma
Xu Guo
Kai Zhao
Changrong Zhao
Characterization of Shallow Groundwater Circulation Based on Chemical Kinetics: A Case Study of Xiong’an New Area, China
Water
chemical kinetics
mineral saturation index
hydraulic conductivity
heterogeneity
Xiong’an New Area
title Characterization of Shallow Groundwater Circulation Based on Chemical Kinetics: A Case Study of Xiong’an New Area, China
title_full Characterization of Shallow Groundwater Circulation Based on Chemical Kinetics: A Case Study of Xiong’an New Area, China
title_fullStr Characterization of Shallow Groundwater Circulation Based on Chemical Kinetics: A Case Study of Xiong’an New Area, China
title_full_unstemmed Characterization of Shallow Groundwater Circulation Based on Chemical Kinetics: A Case Study of Xiong’an New Area, China
title_short Characterization of Shallow Groundwater Circulation Based on Chemical Kinetics: A Case Study of Xiong’an New Area, China
title_sort characterization of shallow groundwater circulation based on chemical kinetics a case study of xiong an new area china
topic chemical kinetics
mineral saturation index
hydraulic conductivity
heterogeneity
Xiong’an New Area
url https://www.mdpi.com/2073-4441/14/12/1880
work_keys_str_mv AT yuboxia characterizationofshallowgroundwatercirculationbasedonchemicalkineticsacasestudyofxiongannewareachina
AT haitaoli characterizationofshallowgroundwatercirculationbasedonchemicalkineticsacasestudyofxiongannewareachina
AT bingwang characterizationofshallowgroundwatercirculationbasedonchemicalkineticsacasestudyofxiongannewareachina
AT zhenma characterizationofshallowgroundwatercirculationbasedonchemicalkineticsacasestudyofxiongannewareachina
AT xuguo characterizationofshallowgroundwatercirculationbasedonchemicalkineticsacasestudyofxiongannewareachina
AT kaizhao characterizationofshallowgroundwatercirculationbasedonchemicalkineticsacasestudyofxiongannewareachina
AT changrongzhao characterizationofshallowgroundwatercirculationbasedonchemicalkineticsacasestudyofxiongannewareachina