Influence of the Donor Properties of Silica-immobilized Amines on the Thermodynamic Characteristics of Interfacial Protolytic Reactions
The thermodynamic characteristics of the reaction between amino groups covalently bonded to a silica surface and aqueous solutions of a strong acid were calculated. Data concerning the influence of the surface on the properties of the bonded amino groups and also about the interaction between neighb...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
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SAGE Publications
1999-12-01
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| Series: | Adsorption Science & Technology |
| Online Access: | https://doi.org/10.1177/026361749901701006 |
| _version_ | 1797283270745915392 |
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| author | Viktoria D. Oleynik Vitaly L. Budarin Vladimir N. Zaitsev |
| author_facet | Viktoria D. Oleynik Vitaly L. Budarin Vladimir N. Zaitsev |
| author_sort | Viktoria D. Oleynik |
| collection | DOAJ |
| description | The thermodynamic characteristics of the reaction between amino groups covalently bonded to a silica surface and aqueous solutions of a strong acid were calculated. Data concerning the influence of the surface on the properties of the bonded amino groups and also about the interaction between neighbouring amines were obtained. The characteristics of the protonation process were explained in terms of a bonded layer structure. |
| first_indexed | 2024-03-07T17:29:38Z |
| format | Article |
| id | doaj.art-f1069eced67c4a7599a52ee4e92f246b |
| institution | Directory Open Access Journal |
| issn | 0263-6174 2048-4038 |
| language | English |
| last_indexed | 2024-03-07T17:29:38Z |
| publishDate | 1999-12-01 |
| publisher | SAGE Publications |
| record_format | Article |
| series | Adsorption Science & Technology |
| spelling | doaj.art-f1069eced67c4a7599a52ee4e92f246b2024-03-02T18:31:16ZengSAGE PublicationsAdsorption Science & Technology0263-61742048-40381999-12-011710.1177/026361749901701006Influence of the Donor Properties of Silica-immobilized Amines on the Thermodynamic Characteristics of Interfacial Protolytic ReactionsViktoria D. Oleynik0Vitaly L. Budarin1Vladimir N. Zaitsev2Chemistry Department, t. shevchenko National University. 60 Vladimirskaya Str., 252033 Kiev. Ukraine.Chemistry Department, t. shevchenko National University. 60 Vladimirskaya Str., 252033 Kiev. Ukraine.Chemistry Department, t. shevchenko National University. 60 Vladimirskaya Str., 252033 Kiev. Ukraine.The thermodynamic characteristics of the reaction between amino groups covalently bonded to a silica surface and aqueous solutions of a strong acid were calculated. Data concerning the influence of the surface on the properties of the bonded amino groups and also about the interaction between neighbouring amines were obtained. The characteristics of the protonation process were explained in terms of a bonded layer structure.https://doi.org/10.1177/026361749901701006 |
| spellingShingle | Viktoria D. Oleynik Vitaly L. Budarin Vladimir N. Zaitsev Influence of the Donor Properties of Silica-immobilized Amines on the Thermodynamic Characteristics of Interfacial Protolytic Reactions Adsorption Science & Technology |
| title | Influence of the Donor Properties of Silica-immobilized Amines on the Thermodynamic Characteristics of Interfacial Protolytic Reactions |
| title_full | Influence of the Donor Properties of Silica-immobilized Amines on the Thermodynamic Characteristics of Interfacial Protolytic Reactions |
| title_fullStr | Influence of the Donor Properties of Silica-immobilized Amines on the Thermodynamic Characteristics of Interfacial Protolytic Reactions |
| title_full_unstemmed | Influence of the Donor Properties of Silica-immobilized Amines on the Thermodynamic Characteristics of Interfacial Protolytic Reactions |
| title_short | Influence of the Donor Properties of Silica-immobilized Amines on the Thermodynamic Characteristics of Interfacial Protolytic Reactions |
| title_sort | influence of the donor properties of silica immobilized amines on the thermodynamic characteristics of interfacial protolytic reactions |
| url | https://doi.org/10.1177/026361749901701006 |
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