Ultra‐High Performance Amorphous Ga2O3 Photodetector Arrays for Solar‐Blind Imaging

Abstract The growing demand for scalable solar‐blind image sensors with remarkable photosensitive properties has stimulated the research on more advanced solar‐blind photodetector (SBPD) arrays. In this work, the authors demonstrate ultrahigh‐performance metal‐semiconductor‐metal (MSM) SBPDs based o...

Full description

Bibliographic Details
Main Authors: Yuan Qin, Li‐Heng Li, Zhaoan Yu, Feihong Wu, Danian Dong, Wei Guo, Zhongfang Zhang, Jun‐Hui Yuan, Kan‐Hao Xue, Xiangshui Miao, Shibing Long
Format: Article
Language:English
Published: Wiley 2021-10-01
Series:Advanced Science
Subjects:
Online Access:https://doi.org/10.1002/advs.202101106
_version_ 1818835255305437184
author Yuan Qin
Li‐Heng Li
Zhaoan Yu
Feihong Wu
Danian Dong
Wei Guo
Zhongfang Zhang
Jun‐Hui Yuan
Kan‐Hao Xue
Xiangshui Miao
Shibing Long
author_facet Yuan Qin
Li‐Heng Li
Zhaoan Yu
Feihong Wu
Danian Dong
Wei Guo
Zhongfang Zhang
Jun‐Hui Yuan
Kan‐Hao Xue
Xiangshui Miao
Shibing Long
author_sort Yuan Qin
collection DOAJ
description Abstract The growing demand for scalable solar‐blind image sensors with remarkable photosensitive properties has stimulated the research on more advanced solar‐blind photodetector (SBPD) arrays. In this work, the authors demonstrate ultrahigh‐performance metal‐semiconductor‐metal (MSM) SBPDs based on amorphous (a‐) Ga2O3 via a post‐annealing process. The post‐annealed MSM a‐Ga2O3 SBPDs exhibit superhigh sensitivity of 733 A/W and high response speed of 18 ms, giving a high gain‐bandwidth product over 104 at 5 V. The SBPDs also show ultrahigh photo‐to‐dark current ratio of 3.9 × 107. Additionally, the PDs demonstrate super‐high specific detectivity of 3.9 × 1016 Jones owing to the extremely low noise down to 3.5 fW Hz−1/2, suggesting high signal‐to‐noise ratio. Underlying mechanism for such superior photoelectric properties is revealed by Kelvin probe force microscopy and first principles calculation. Furthermore, for the first time, a large‐scale, high‐uniformity 32 × 32 image sensor array based on the post‐annealed a‐Ga2O3 SBPDs is fabricated. Clear image of target object with high contrast can be obtained thanks to the high sensitivity and uniformity of the array. These results demonstrate the feasibility and practicality of the Ga2O3 PDs for applications in solar‐blind imaging, environmental monitoring, artificial intelligence and machine vision.
first_indexed 2024-12-19T02:47:48Z
format Article
id doaj.art-f1204b88532c40e8a0f6c25cf1918c31
institution Directory Open Access Journal
issn 2198-3844
language English
last_indexed 2024-12-19T02:47:48Z
publishDate 2021-10-01
publisher Wiley
record_format Article
series Advanced Science
spelling doaj.art-f1204b88532c40e8a0f6c25cf1918c312022-12-21T20:38:47ZengWileyAdvanced Science2198-38442021-10-01820n/an/a10.1002/advs.202101106Ultra‐High Performance Amorphous Ga2O3 Photodetector Arrays for Solar‐Blind ImagingYuan Qin0Li‐Heng Li1Zhaoan Yu2Feihong Wu3Danian Dong4Wei Guo5Zhongfang Zhang6Jun‐Hui Yuan7Kan‐Hao Xue8Xiangshui Miao9Shibing Long10Key Laboratory of Microelectronics Devices & Integration Technology Institute of Microelectronics of Chinese Academy of Sciences Beijing 100029 ChinaWuhan National Laboratory for Optoelectronics School of Optical and Electronic Information Huazhong University of Science and Technology Wuhan 430074 ChinaKey Laboratory of Microelectronics Devices & Integration Technology Institute of Microelectronics of Chinese Academy of Sciences Beijing 100029 ChinaSchool of Microelectronics University of Science and Technology of China Hefei Anhui 230026 ChinaKey Laboratory of Microelectronics Devices & Integration Technology Institute of Microelectronics of Chinese Academy of Sciences Beijing 100029 ChinaSchool of Microelectronics University of Science and Technology of China Hefei Anhui 230026 ChinaSchool of Microelectronics University of Science and Technology of China Hefei Anhui 230026 ChinaWuhan National Laboratory for Optoelectronics School of Optical and Electronic Information Huazhong University of Science and Technology Wuhan 430074 ChinaWuhan National Laboratory for Optoelectronics School of Optical and Electronic Information Huazhong University of Science and Technology Wuhan 430074 ChinaWuhan National Laboratory for Optoelectronics School of Optical and Electronic Information Huazhong University of Science and Technology Wuhan 430074 ChinaSchool of Microelectronics University of Science and Technology of China Hefei Anhui 230026 ChinaAbstract The growing demand for scalable solar‐blind image sensors with remarkable photosensitive properties has stimulated the research on more advanced solar‐blind photodetector (SBPD) arrays. In this work, the authors demonstrate ultrahigh‐performance metal‐semiconductor‐metal (MSM) SBPDs based on amorphous (a‐) Ga2O3 via a post‐annealing process. The post‐annealed MSM a‐Ga2O3 SBPDs exhibit superhigh sensitivity of 733 A/W and high response speed of 18 ms, giving a high gain‐bandwidth product over 104 at 5 V. The SBPDs also show ultrahigh photo‐to‐dark current ratio of 3.9 × 107. Additionally, the PDs demonstrate super‐high specific detectivity of 3.9 × 1016 Jones owing to the extremely low noise down to 3.5 fW Hz−1/2, suggesting high signal‐to‐noise ratio. Underlying mechanism for such superior photoelectric properties is revealed by Kelvin probe force microscopy and first principles calculation. Furthermore, for the first time, a large‐scale, high‐uniformity 32 × 32 image sensor array based on the post‐annealed a‐Ga2O3 SBPDs is fabricated. Clear image of target object with high contrast can be obtained thanks to the high sensitivity and uniformity of the array. These results demonstrate the feasibility and practicality of the Ga2O3 PDs for applications in solar‐blind imaging, environmental monitoring, artificial intelligence and machine vision.https://doi.org/10.1002/advs.202101106Ga2O3high detectivityimage sensorsphotodetector arrayssolar‐blind imaginguniformity
spellingShingle Yuan Qin
Li‐Heng Li
Zhaoan Yu
Feihong Wu
Danian Dong
Wei Guo
Zhongfang Zhang
Jun‐Hui Yuan
Kan‐Hao Xue
Xiangshui Miao
Shibing Long
Ultra‐High Performance Amorphous Ga2O3 Photodetector Arrays for Solar‐Blind Imaging
Advanced Science
Ga2O3
high detectivity
image sensors
photodetector arrays
solar‐blind imaging
uniformity
title Ultra‐High Performance Amorphous Ga2O3 Photodetector Arrays for Solar‐Blind Imaging
title_full Ultra‐High Performance Amorphous Ga2O3 Photodetector Arrays for Solar‐Blind Imaging
title_fullStr Ultra‐High Performance Amorphous Ga2O3 Photodetector Arrays for Solar‐Blind Imaging
title_full_unstemmed Ultra‐High Performance Amorphous Ga2O3 Photodetector Arrays for Solar‐Blind Imaging
title_short Ultra‐High Performance Amorphous Ga2O3 Photodetector Arrays for Solar‐Blind Imaging
title_sort ultra high performance amorphous ga2o3 photodetector arrays for solar blind imaging
topic Ga2O3
high detectivity
image sensors
photodetector arrays
solar‐blind imaging
uniformity
url https://doi.org/10.1002/advs.202101106
work_keys_str_mv AT yuanqin ultrahighperformanceamorphousga2o3photodetectorarraysforsolarblindimaging
AT lihengli ultrahighperformanceamorphousga2o3photodetectorarraysforsolarblindimaging
AT zhaoanyu ultrahighperformanceamorphousga2o3photodetectorarraysforsolarblindimaging
AT feihongwu ultrahighperformanceamorphousga2o3photodetectorarraysforsolarblindimaging
AT daniandong ultrahighperformanceamorphousga2o3photodetectorarraysforsolarblindimaging
AT weiguo ultrahighperformanceamorphousga2o3photodetectorarraysforsolarblindimaging
AT zhongfangzhang ultrahighperformanceamorphousga2o3photodetectorarraysforsolarblindimaging
AT junhuiyuan ultrahighperformanceamorphousga2o3photodetectorarraysforsolarblindimaging
AT kanhaoxue ultrahighperformanceamorphousga2o3photodetectorarraysforsolarblindimaging
AT xiangshuimiao ultrahighperformanceamorphousga2o3photodetectorarraysforsolarblindimaging
AT shibinglong ultrahighperformanceamorphousga2o3photodetectorarraysforsolarblindimaging