ORBITALS IN GENERAL CHEMISTRY, PART III: CONSEQUENCES FOR TEACHING

In Part III of this series, we undertake a critique of the nature of application of orbitals to describe or to explain the structure and the binding within molecules and materials. Teaching orbitals in introductory chemistry presents five dilemmas that cannot be easily resolved. We thus conclude, ba...

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Main Authors: Guy Lamoureux, John F. Ogilvie
Format: Article
Language:English
Published: Sociedade Brasileira de Química 2021-05-01
Series:Química Nova
Subjects:
Online Access:http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422021000300355&tlng=en
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author Guy Lamoureux
John F. Ogilvie
author_facet Guy Lamoureux
John F. Ogilvie
author_sort Guy Lamoureux
collection DOAJ
description In Part III of this series, we undertake a critique of the nature of application of orbitals to describe or to explain the structure and the binding within molecules and materials. Teaching orbitals in introductory chemistry presents five dilemmas that cannot be easily resolved. We thus conclude, based on mathematical realties, that orbitals are not essential until advanced courses. Even in advanced courses, we question the traditional choice of presenting an inadequate set of orbitals. When one recognizes, in a context of general chemistry, the irrelevance of orbitals as algebraic formulae to the observable properties and reactions of chemical substances, one can readily proceed to teach appropriate content effectively without invoking orbitals or analogous entities, based on our actual experience in teaching general chemistry over the years.
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spelling doaj.art-f126e5681b3045288f6a666b5b5955d32022-12-21T21:23:30ZengSociedade Brasileira de QuímicaQuímica Nova1678-70642021-05-0144335536010.21577/0100-4042.20170660ORBITALS IN GENERAL CHEMISTRY, PART III: CONSEQUENCES FOR TEACHINGGuy Lamoureuxhttps://orcid.org/0000-0002-2717-7506John F. OgilvieIn Part III of this series, we undertake a critique of the nature of application of orbitals to describe or to explain the structure and the binding within molecules and materials. Teaching orbitals in introductory chemistry presents five dilemmas that cannot be easily resolved. We thus conclude, based on mathematical realties, that orbitals are not essential until advanced courses. Even in advanced courses, we question the traditional choice of presenting an inadequate set of orbitals. When one recognizes, in a context of general chemistry, the irrelevance of orbitals as algebraic formulae to the observable properties and reactions of chemical substances, one can readily proceed to teach appropriate content effectively without invoking orbitals or analogous entities, based on our actual experience in teaching general chemistry over the years.http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422021000300355&tlng=enteaching general chemistryorbitalsquantum mechanicsmolecular structure
spellingShingle Guy Lamoureux
John F. Ogilvie
ORBITALS IN GENERAL CHEMISTRY, PART III: CONSEQUENCES FOR TEACHING
Química Nova
teaching general chemistry
orbitals
quantum mechanics
molecular structure
title ORBITALS IN GENERAL CHEMISTRY, PART III: CONSEQUENCES FOR TEACHING
title_full ORBITALS IN GENERAL CHEMISTRY, PART III: CONSEQUENCES FOR TEACHING
title_fullStr ORBITALS IN GENERAL CHEMISTRY, PART III: CONSEQUENCES FOR TEACHING
title_full_unstemmed ORBITALS IN GENERAL CHEMISTRY, PART III: CONSEQUENCES FOR TEACHING
title_short ORBITALS IN GENERAL CHEMISTRY, PART III: CONSEQUENCES FOR TEACHING
title_sort orbitals in general chemistry part iii consequences for teaching
topic teaching general chemistry
orbitals
quantum mechanics
molecular structure
url http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422021000300355&tlng=en
work_keys_str_mv AT guylamoureux orbitalsingeneralchemistrypartiiiconsequencesforteaching
AT johnfogilvie orbitalsingeneralchemistrypartiiiconsequencesforteaching