Crystal structure of 8-hexyloxy-2-[(Z)-2-(naphthalen-2-yl)ethenyl]quinoline
In the title molecule, C27H27NO, the naphthalene and quinoline groups are both planar and subtend a dihedral angle of 15.47 (7)°. They are nearly coplanar with the cis-vinyl bridge and the hexyloxy chain, which adopts an all-trans conformation, resulting in transannular bifurcated intramolecular C—H...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2022-08-01
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| Series: | Acta Crystallographica Section E: Crystallographic Communications |
| Subjects: | |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S2056989022006740 |
| _version_ | 1811344785868324864 |
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| author | Xiaozhou Liu Lu Wang Ying Feng Deliang Cui Zhi Liu |
| author_facet | Xiaozhou Liu Lu Wang Ying Feng Deliang Cui Zhi Liu |
| author_sort | Xiaozhou Liu |
| collection | DOAJ |
| description | In the title molecule, C27H27NO, the naphthalene and quinoline groups are both planar and subtend a dihedral angle of 15.47 (7)°. They are nearly coplanar with the cis-vinyl bridge and the hexyloxy chain, which adopts an all-trans conformation, resulting in transannular bifurcated intramolecular C—H...N,O contact. The crystal structure features γ-packing of the aromatic moieties, while the parallel packing of alkyl chains resembles that of alkanes. |
| first_indexed | 2024-04-13T19:53:18Z |
| format | Article |
| id | doaj.art-f13c8fe70f79423ba060908c0ab9bb2b |
| institution | Directory Open Access Journal |
| issn | 2056-9890 |
| language | English |
| last_indexed | 2024-04-13T19:53:18Z |
| publishDate | 2022-08-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E: Crystallographic Communications |
| spelling | doaj.art-f13c8fe70f79423ba060908c0ab9bb2b2022-12-22T02:32:27ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902022-08-0178877077310.1107/S2056989022006740zv2017Crystal structure of 8-hexyloxy-2-[(Z)-2-(naphthalen-2-yl)ethenyl]quinolineXiaozhou Liu0Lu Wang1Ying Feng2Deliang Cui3Zhi Liu4State Key Laboratory of Crystal Materials, Shandong University, Jinan 250100, Shandong Province, People's Republic of ChinaState Key Laboratory of Crystal Materials, Shandong University, Jinan 250100, Shandong Province, People's Republic of ChinaState Key Laboratory of Crystal Materials, Shandong University, Jinan 250100, Shandong Province, People's Republic of ChinaState Key Laboratory of Crystal Materials, Shandong University, Jinan 250100, Shandong Province, People's Republic of ChinaState Key Laboratory of Crystal Materials, Shandong University, Jinan 250100, Shandong Province, People's Republic of ChinaIn the title molecule, C27H27NO, the naphthalene and quinoline groups are both planar and subtend a dihedral angle of 15.47 (7)°. They are nearly coplanar with the cis-vinyl bridge and the hexyloxy chain, which adopts an all-trans conformation, resulting in transannular bifurcated intramolecular C—H...N,O contact. The crystal structure features γ-packing of the aromatic moieties, while the parallel packing of alkyl chains resembles that of alkanes.http://scripts.iucr.org/cgi-bin/paper?S2056989022006740π-conjugatednaphthalene derivativequinoline derivativeπ–π interactionsintra-molecular hydrogen bondγ-packingcrystal structure |
| spellingShingle | Xiaozhou Liu Lu Wang Ying Feng Deliang Cui Zhi Liu Crystal structure of 8-hexyloxy-2-[(Z)-2-(naphthalen-2-yl)ethenyl]quinoline Acta Crystallographica Section E: Crystallographic Communications π-conjugated naphthalene derivative quinoline derivative π–π interactions intra-molecular hydrogen bond γ-packing crystal structure |
| title | Crystal structure of 8-hexyloxy-2-[(Z)-2-(naphthalen-2-yl)ethenyl]quinoline |
| title_full | Crystal structure of 8-hexyloxy-2-[(Z)-2-(naphthalen-2-yl)ethenyl]quinoline |
| title_fullStr | Crystal structure of 8-hexyloxy-2-[(Z)-2-(naphthalen-2-yl)ethenyl]quinoline |
| title_full_unstemmed | Crystal structure of 8-hexyloxy-2-[(Z)-2-(naphthalen-2-yl)ethenyl]quinoline |
| title_short | Crystal structure of 8-hexyloxy-2-[(Z)-2-(naphthalen-2-yl)ethenyl]quinoline |
| title_sort | crystal structure of 8 hexyloxy 2 z 2 naphthalen 2 yl ethenyl quinoline |
| topic | π-conjugated naphthalene derivative quinoline derivative π–π interactions intra-molecular hydrogen bond γ-packing crystal structure |
| url | http://scripts.iucr.org/cgi-bin/paper?S2056989022006740 |
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