Methylammonium tetrafluoridoborate 18-crown-6 clathrate
In the title compound, CH3NH3+·BF4−·C12H24O6, the methylammonium cation makes three N—H...O hydrogen bonds to the 18-crown-6 molecule. The –NH3+ and –CH3 groups of the cation adopt a staggered conformation. The F atoms...
| Main Author: | |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2012-01-01
|
| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536811054432 |
| _version_ | 1818998039825612800 |
|---|---|
| author | Yu Jin |
| author_facet | Yu Jin |
| author_sort | Yu Jin |
| collection | DOAJ |
| description | In the title compound, CH3NH3+·BF4−·C12H24O6, the methylammonium cation makes three N—H...O hydrogen bonds to the 18-crown-6 molecule. The –NH3+ and –CH3 groups of the cation adopt a staggered conformation. The F atoms of the tetrafluoridoborate anion are disordered over two sets of sites in a 0.519 (11):0.481 (11) ratio. Weak C—H...F interactions occur in the crystal, which possibly correlate with the anion disorder. |
| first_indexed | 2024-12-20T21:55:12Z |
| format | Article |
| id | doaj.art-f13d6f91e01a4f37b57609b50b867562 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-20T21:55:12Z |
| publishDate | 2012-01-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-f13d6f91e01a4f37b57609b50b8675622022-12-21T19:25:28ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-01-01681o225o22510.1107/S1600536811054432Methylammonium tetrafluoridoborate 18-crown-6 clathrateYu JinIn the title compound, CH3NH3+·BF4−·C12H24O6, the methylammonium cation makes three N—H...O hydrogen bonds to the 18-crown-6 molecule. The –NH3+ and –CH3 groups of the cation adopt a staggered conformation. The F atoms of the tetrafluoridoborate anion are disordered over two sets of sites in a 0.519 (11):0.481 (11) ratio. Weak C—H...F interactions occur in the crystal, which possibly correlate with the anion disorder.http://scripts.iucr.org/cgi-bin/paper?S1600536811054432 |
| spellingShingle | Yu Jin Methylammonium tetrafluoridoborate 18-crown-6 clathrate Acta Crystallographica Section E |
| title | Methylammonium tetrafluoridoborate 18-crown-6 clathrate |
| title_full | Methylammonium tetrafluoridoborate 18-crown-6 clathrate |
| title_fullStr | Methylammonium tetrafluoridoborate 18-crown-6 clathrate |
| title_full_unstemmed | Methylammonium tetrafluoridoborate 18-crown-6 clathrate |
| title_short | Methylammonium tetrafluoridoborate 18-crown-6 clathrate |
| title_sort | methylammonium tetrafluoridoborate 18 crown 6 clathrate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536811054432 |
| work_keys_str_mv | AT yujin methylammoniumtetrafluoridoborate18crown6clathrate |