Synthesis and Characterization of Biochar-Based Geopolymer Materials

The aim of this research is to evaluate the possibility to realize alkali-activated materials exploiting biochar, a secondary raw material coming from pyrolysis/gasification processes, for environmental benefits, such as improvement of soil fertility and reduction of CO<sub>2</sub> emiss...

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Main Authors: Federica Piccolo, Fernanda Andreola, Luisa Barbieri, Isabella Lancellotti
Format: Article
Language:English
Published: MDPI AG 2021-11-01
Series:Applied Sciences
Subjects:
Online Access:https://www.mdpi.com/2076-3417/11/22/10945
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author Federica Piccolo
Fernanda Andreola
Luisa Barbieri
Isabella Lancellotti
author_facet Federica Piccolo
Fernanda Andreola
Luisa Barbieri
Isabella Lancellotti
author_sort Federica Piccolo
collection DOAJ
description The aim of this research is to evaluate the possibility to realize alkali-activated materials exploiting biochar, a secondary raw material coming from pyrolysis/gasification processes, for environmental benefits, such as improvement of soil fertility and reduction of CO<sub>2</sub> emissions into the atmosphere thanks to the carbon sink process where carbon dioxide is subtracted from the cycle of carbon. For the matrix of the geopolymers, a waste material derived from incinerator bottom ash was used and compared to pure metakaolin matrix. The materials obtained are lightweight and porous, with high water absorption capacity and moisture adsorption/desorption. BET analysis shows an increase in specific surface by increasing the biochar content and the biochar acts as a filler in the pores. From porosimetry analysis it is possible to follow the evolution of the curing process of the geopolymer prepared: specimens containing 70 wt% biochar after 28 and 90 days showed an increase in total Hg intrusion volume, pore area and total porosity but a decrease in the dimensions of pores. Due to the technical properties of materials containing biochar, they can be used in the future for a cleaner design of products in the field of sustainable construction for insulating panels or lightweight materials for houses and gardens in terraces and balconies.
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spelling doaj.art-f15e1357ef034802a4645d0aa81f00572023-11-22T22:21:17ZengMDPI AGApplied Sciences2076-34172021-11-0111221094510.3390/app112210945Synthesis and Characterization of Biochar-Based Geopolymer MaterialsFederica Piccolo0Fernanda Andreola1Luisa Barbieri2Isabella Lancellotti3Department of Engineering “Enzo Ferrari”, University of Modena and Reggio Emilia, 41126 Modena, ItalyDepartment of Engineering “Enzo Ferrari”, University of Modena and Reggio Emilia, 41126 Modena, ItalyDepartment of Engineering “Enzo Ferrari”, University of Modena and Reggio Emilia, 41126 Modena, ItalyDepartment of Engineering “Enzo Ferrari”, University of Modena and Reggio Emilia, 41126 Modena, ItalyThe aim of this research is to evaluate the possibility to realize alkali-activated materials exploiting biochar, a secondary raw material coming from pyrolysis/gasification processes, for environmental benefits, such as improvement of soil fertility and reduction of CO<sub>2</sub> emissions into the atmosphere thanks to the carbon sink process where carbon dioxide is subtracted from the cycle of carbon. For the matrix of the geopolymers, a waste material derived from incinerator bottom ash was used and compared to pure metakaolin matrix. The materials obtained are lightweight and porous, with high water absorption capacity and moisture adsorption/desorption. BET analysis shows an increase in specific surface by increasing the biochar content and the biochar acts as a filler in the pores. From porosimetry analysis it is possible to follow the evolution of the curing process of the geopolymer prepared: specimens containing 70 wt% biochar after 28 and 90 days showed an increase in total Hg intrusion volume, pore area and total porosity but a decrease in the dimensions of pores. Due to the technical properties of materials containing biochar, they can be used in the future for a cleaner design of products in the field of sustainable construction for insulating panels or lightweight materials for houses and gardens in terraces and balconies.https://www.mdpi.com/2076-3417/11/22/10945geopolymerbiocharbottom ashlightweight material
spellingShingle Federica Piccolo
Fernanda Andreola
Luisa Barbieri
Isabella Lancellotti
Synthesis and Characterization of Biochar-Based Geopolymer Materials
Applied Sciences
geopolymer
biochar
bottom ash
lightweight material
title Synthesis and Characterization of Biochar-Based Geopolymer Materials
title_full Synthesis and Characterization of Biochar-Based Geopolymer Materials
title_fullStr Synthesis and Characterization of Biochar-Based Geopolymer Materials
title_full_unstemmed Synthesis and Characterization of Biochar-Based Geopolymer Materials
title_short Synthesis and Characterization of Biochar-Based Geopolymer Materials
title_sort synthesis and characterization of biochar based geopolymer materials
topic geopolymer
biochar
bottom ash
lightweight material
url https://www.mdpi.com/2076-3417/11/22/10945
work_keys_str_mv AT federicapiccolo synthesisandcharacterizationofbiocharbasedgeopolymermaterials
AT fernandaandreola synthesisandcharacterizationofbiocharbasedgeopolymermaterials
AT luisabarbieri synthesisandcharacterizationofbiocharbasedgeopolymermaterials
AT isabellalancellotti synthesisandcharacterizationofbiocharbasedgeopolymermaterials